Role of coagulation/flocculation as a pretreatment option to reduce colloidal/bio-colloidal fouling in tertiary filtration of textile wastewater: A review and future outlooks

Textile industry wastewater has become a growing concern in recent years due to it has been characterized by a high load of organic dyes, suspended and dissolved solids, alkaline pH, and low biodegradability. As a result, environmental authorities necessitate textile industries to treat effluents before discharge into the environment. Tertiary filters, particularly membrane filtrations, are the most preferable process to recover good-quality water at the tertiary treatment phase, which feeds from secondary effluents, in wastewater treatment processes. However, fouling is still a challenge due to a higher load of suspended solids, colloids, organic matter, and a high level of bio-colloids (mostly from secondary effluents) in the textile wastewater treatment process. Bio-colloids are any colloidal entities of organic matter including microorganisms and their exudates. Hence, a coagulation/flocculation unit process, as a pretreatment option, is critical both at the primary treatment stage and after secondary (biological) effluents to prevent fouling problems at the tertiary filters. We reviewed identifying major foulants causing tertiary filter damage and the available pretreatment option for the removal of these foulants. We focus on and suggest the coagulation/flocculation process as a good pretreatment alternative to prevent filter fouling as it provides a reliable process to treat high water turbidity that arises from a high load of solids and colloids. Amongst different types of foulants, we focus on and present the colloidal solids and bio-colloidal foulants that could be major causes of fouling. These foulants are less understood and expected to be dominant in the textile industry wastewater, and established pretreatment alternatives are not well developed for the bio-foulants fed from the secondary effluent. Thus, these foulants need to be critically identified in the textile wastewater treatment plants to integrate suitable pretreatment options to prevent fouling potentiality. We proposed a coagulation/flocculation unit process as a pretreatment option to reduce colloidal and bio-colloidal fouling before the tertiary treatment stage, next to the secondary effluent, is critical

Bioremediation of petroleum hydrocarbon contaminated soil: a review on principles, degradation mechanisms, and advancements

Petroleum hydrocarbons (PHCs) are key energy sources for several industries and daily life. Soil contamination from oily PHC spills is commonly detected in cities and industrial facilities where crude oil is used. The release of PHC pollutants into the environment, whether accidentally from petroleum industries or human activities, has become a leading source of soil pollution. Consequently, the mineralization of PHC-polluted sites has become a central issue worldwide. Although bioremediation is imperative for environmental safety and management, several approaches have been developed for PHC bioremediation. However, much remains to be explored in this regard. This review explores bioremediation of PHC-contaminated soil and provides a comprehensive examination of the principles, degradation mechanisms, and recent advancements in the field. Several microbial species have been used to study the bioremediation of PHCs, emphasizing the pivotal roles of diverse microbial communities. Aspergillus spp., Proteobacteria, and Firmicutes groups of microorganisms were the most efficient in remediating PHC-contaminated soil. The fundamental concepts behind the bioremediation of PHC and the complex mechanisms that govern degradation were elucidated. Limiting factors in the bioremediation process and recent innovations propelling the field were also discussed. Therefore, understanding the degradation pathway, ensuring complete degradation of contaminants, and flexible legislation for the proper use of genetically engineered microbes can make bioremediation more sustainable and cost-effective

Recycling electro-coagulated sludge from textile wastewater treatment plants as an adsorbent for the adsorptions of fluoride in an aqueous solution

This research investigated the high content of iron-based materials from recycled electro-coagulated (EC) sludge for the adsorptive removal of fluoride, and the properties of the material were characterized. The thermal activation of EC sludge in which the unwanted impurity was removed by beneficiation and thermally activated at 500 °C, and was used for fluoride removal. Basic operating parameters (mixing time, adsorbent dosage, adsorbate concentration, solution pH, and temperature) were examined to evaluate the optimum de-fluoridation capacity (DC). The functional groups, the crystalline structure, and surface morphology of thermally treated and raw EC sludge were analyzed using FTIR, XRD, and SEM, respectively, and demonstrates that thermally activated EC sludge contains significant content of magnetite and hematite. The optimum DC was recorded as 5.12 mg of F−/gm with experimental conditions: mixing time = 20 min, adsorbent dosage = 0.3 gm/100 ml, initial fluoride concentration = 1 mg/L, and pH = 5 at the temperature of 353 K. The Langmuir isotherm model was fitted, and the capacity is calculated as 6.43 mg/g. The adsorption process follows the Pseudo-Second-order kinetic models. It can be concluded that the prepared adsorbents have excellent fluoride removal capacity, and EC sludge can be used as an alternative adsorbent for de-fluoridation

Utilization of treated coffee husk as low-cost bio-sorbent for adsorption of methylene blue

Dyes and pigments have been used in many industries for colorization purpose but they pose hazards to the environment and end users of water. Therefore, it is important to remove this pollutant from waste water before their final disposal. This study aimed to investigate the removal of methylene blue by cost effective, ecofriendly, high-efficiency bio-sorbent from activated coffee husk. The process was carried out using chemical activation (H 3 PO 4 ) process. Fourier transform infrared spectroscopy and surface analyzer (Brunauer-Emmett-Teller) were used to characterize the adsorbent. The specific surface area adsorbent was obtained as 28.54 m 2 /g. The maximum removal efficiency was obtained as 96.9% at pH of 5, initial dye concentration of 20 mg/L, adsorbent dosage of 0.8 g/50 mL, for contact time of 50 min and 30°C temperature on the activation surface of coffee husk. Langmuir model was found to fit the equilibrium data for methylene blue adsorption with 6.82 mg/g at 30°C. The adsorption process follows the pseudo-second-order model. Thermodynamics analysis showed that the adsorption of methylene blue on to the activated coffee husk was a spontaneous and endothermic process. The experimental data obtained in the present study proved that coffee husk is a suitable bio-sorbent in removal of cationic dyes

Plastic and paint debris in marine protected areas of Peru

Contamination with anthropogenic debris, such as plastic and paint particles, has been widely investigated in the global marine environment. However, there is a lack of information regarding their presence in marine protected areas (MPAs). In the present study, the abundance, distribution, and chemical characteristics of microplastics (MPs; <5 mm), mesoplastics (MePs; 5–25 mm), and paint particles were investigated in multiple environmental compartments of two MPAs from Peru. The characteristics of MPs across surface water, bottom sediments, and fish guts were similar, primarily dominated by blue fibers. On the other hand, MePs and large MPs (1–5 mm) were similar across sandy beaches. Several particles were composite materials consisting of multiple layers confirmed as alkyd resins by Fourier-transformed infrared spectroscopy, which were typical indicators of marine coatings. The microstructure of paint particles showed differentiated topography across layers, as well as different elemental compositions. Some layers displayed amorphous structures with Ba-, Cr-, and Ti-based additives. However, the leaching and impact of potentially toxic additives in paint particles require further investigation. The accumulation of multiple types of plastic and paint debris in MPAs could pose a threat to conservation goals. The current study contributed to the knowledge regarding anthropogenic debris contamination in MPAs and further elucidated the physical and chemical properties of paint particles in marine environments. While paint particles may look similar to MPs and MePs, more attention should be given to these contaminants in places where intense maritime activity takes place.Fil: De la Torre, Gabriel Enrique. Universidad San Ignacio de Loyola; PerúFil: Dioses Salinas, Diana Carolina. Universidad San Ignacio de Loyola; PerúFil: Pizarro Ortega, Carlos Ivan. Universidad San Ignacio de Loyola; PerúFil: Forero Lopez, Ana Deisy. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto Argentino de Oceanografía. Universidad Nacional del Sur. Instituto Argentino de Oceanografía; ArgentinaFil: Fernandez Severini, Melisa Daiana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto Argentino de Oceanografía. Universidad Nacional del Sur. Instituto Argentino de Oceanografía; ArgentinaFil: Rimondino, Guido Noé. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Malanca, Fabio Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Dobaradaran, Sina. Bushehr University of Medical Sciences; Irán. Universitat Essen; AlemaniaFil: Aragaw, Tadele Assefa. Bahir Dar University; EtiopíaFil: Mghili, Bilal. Abdelmalek Essaadi University; MarruecosFil: Ayala, Félix. Universidad Peruana Cayetano Heredia; Per

Binational survey of personal protective equipment (PPE) pollution driven by the COVID-19 pandemic in coastal environments: Abundance, distribution, and analytical characterization

In the present contribution, two nationwide surveys of personal protective equipment (PPE) pollution were conducted in Peru and Argentina aiming to provide valuable information regarding the abundance and distribution of PPE in coastal sites. Additionally, PPE items were recovered from the environment and analyzed by Fourier transformed infrared (FTIR) spectroscopy, Scanning electron microscopy (SEM) with Energy dispersive X-ray (EDX), and X-ray diffraction (XRD), and compared to brand-new PPE in order to investigate the chemical and structural degradation of PPE in the environment. PPE density (PPE m− 2 ) found in both countries were comparable to previous studies. FTIR analysis revealed multiple polymer types comprising common PPE, mainly polypropylene, polyamide, polyethylene terephthalate, and polyester. SEM micrographs showed clear weathering signs, such as cracks, cavities, and rough surfaces in face masks and gloves. EDX elemental mapping revealed the presence of elemental additives, such as Ca in gloves and face masks and AgNPs as an antimicrobial agent. Other metals found on the surface of PPE were Mo, P, Ti, and Zn. XRD patterns displayed a notorious decrease in the crystallinity of polypropylene face masks, which could alter its interaction with external contaminants and stability. The next steps in this line of research were discussed.Campus Lima Centr

Primary plastic polymers: Urgently needed upstream reduction

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