Insights into deposition of Lower Cretaceous black shales from meager accumulation of organic matter in Albian sediments from ODP site 763, Exmouth Plateau, Northwest Australia

The amount and type of organic matter present in an exceptionally complete upper Aptian to lower Cenomanian sequence of sediments from ODP site 763 on the Exmouth Plateau has been determined. Organic carbon concentrations average 0.2%. Organic matter is marine in origin, and its production and preservation was low over the ca. 20-million-year interval recorded by this sequence. Because this section was tectonically isolated from mainland Australia in the early Aptian, it better represents global oceanic conditions than the many basin-edge locations in which Albian-age black shales have been found. Formation of the basin-edge black shales evidently resulted from rapid, turbiditic burial of organic matter rather than from enhanced oceanic production or from basin-wide anoxia during the Albian.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/47134/1/367_2005_Article_BF02202605.pd

Proxy evidence for state-dependence of climate sensitivity in the Eocene greenhouse

Despite recent advances, the link between the evolution of atmospheric CO2 and climate during the Eocene greenhouse remains uncertain. In particular, modelling studies suggest that in order to achieve the global warmth that characterised the early Eocene, warmer climates must be more sensitive to CO2 forcing than colder climates. Here, we test this assertion in the geological record by combining a new high-resolution boron isotope-based CO2 record with novel estimates of Global Mean Temperature. We find that Equilibrium Climate Sensitivity (ECS) was indeed higher during the warmest intervals of the Eocene, agreeing well with recent model simulations, and declined through the Eocene as global climate cooled. These observations indicate that the canonical IPCC range of ECS (1.5 to 4.5 °C per doubling) is unlikely to be appropriate for high-CO2 warm climates of the past, and the state dependency of ECS may play an increasingly important role in determining the state of future climate as the Earth continues to warm

Sudden spreading of corrosive bottom water during the Palaeocene-Eocene Thermal Maximum

The Palaeocene-Eocene Thermal Maximum, approximately 55 million years ago, was a period of rapid warming linked to a massive release of carbon to the ocean-atmosphere system. Thiswarming eventwas alsomarked by widespread dissolution of carbonates at the sea floor2. The acidification of deepwaters was generally more extensive and severe in the Atlantic and Caribbean, with more modest changes in the Southern and Pacific oceans3,5. Here we use the UVic ESCM global climate model to show that corrosive deep water spreading from the North Atlantic can explain the spatial variations in carbonate dissolution during the Palaeocene-Eocene Thermal Maximum. In our simulations, highly corrosive waters accumulate in the deep North Atlantic at the onset of the event. Several thousand years after an imposed atmospheric carbon release, warming of the deep ocean destabilizes the North Atlantic water column and triggers deep-water formation. This deep convection causes the corrosive bottom water to spill over an equatorial sill into the South Atlantic. The bottom water then spreads throughthe SouthernandPacific oceans, progressively gaining alkalinity. We conclude that the pattern of sediment dissolution simulated along the path taken by the corrosive water is consistent with most dissolution estimates from the sediment record

The dynamics of global change at the Paleocene-Eocene thermal maximum: A data-model comparison

We integrate published stable isotopic, chemical, mineralogical, and biotic data from the onset of the Paleocene-Eocene thermal maximum (PETM) at Site 690, Maud Rise in the Southern Ocean. The integrated data set documents a sequence of environmental steps including warming of the ocean from the surface downward, and modification of its thermal and nutrient structure, acidification of the deep ocean, and the onset of continental weathering. The age of the events with respect to the onset of the PETM is calibrated with three different age models. The relative and absolute timing of the steps are compared with simulated temperature, salinity, calcite saturation, and dissolved PO4 and O2, at different depths in the ocean, generated with the UVic Earth System Climate Model of intermediate complexity. The simulation supports the top to bottom transfer of heat and carbon, and generally agrees with age models in terms of the durations of leads and lags in temperature, C-isotope, and biotic responses. Moreover, the simulation shows that stratification increased and the nutricline strengthened at the onset of the PETM. These environmental changes explain the abundance of deep-dwelling nannoplankton and foraminifera during the early part of the event. The modeled calcite saturation is consistent with a harsh deep-sea habitat at the time of the benthic foraminiferal extinction

Organic matter from the Chicxulub crater exacerbated the K-Pg impact winter.

An asteroid impact in the Yucatán Peninsula set off a sequence of events that led to the Cretaceous-Paleogene (K-Pg) mass extinction of 76% species, including the nonavian dinosaurs. The impact hit a carbonate platform and released sulfate aerosols and dust into Earth's upper atmosphere, which cooled and darkened the planet-a scenario known as an impact winter. Organic burn markers are observed in K-Pg boundary records globally, but their source is debated. If some were derived from sedimentary carbon, and not solely wildfires, it implies soot from the target rock also contributed to the impact winter. Characteristics of polycyclic aromatic hydrocarbons (PAHs) in the Chicxulub crater sediments and at two deep ocean sites indicate a fossil carbon source that experienced rapid heating, consistent with organic matter ejected during the formation of the crater. Furthermore, PAH size distributions proximal and distal to the crater indicate the ejected carbon was dispersed globally by atmospheric processes. Molecular and charcoal evidence indicates wildfires were also present but more delayed and protracted and likely played a less acute role in biotic extinctions than previously suggested. Based on stratigraphy near the crater, between 7.5 × 1014 and 2.5 × 1015 g of black carbon was released from the target and ejected into the atmosphere, where it circulated the globe within a few hours. This carbon, together with sulfate aerosols and dust, initiated an impact winter and global darkening that curtailed photosynthesis and is widely considered to have caused the K-Pg mass extinction

Globally distributed iridium layer preserved within the Chicxulub impact structure.

The Cretaceous-Paleogene (K-Pg) mass extinction is marked globally by elevated concentrations of iridium, emplaced by a hypervelocity impact event 66 million years ago. Here, we report new data from four independent laboratories that reveal a positive iridium anomaly within the peak-ring sequence of the Chicxulub impact structure, in drill core recovered by IODP-ICDP Expedition 364. The highest concentration of ultrafine meteoritic matter occurs in the post-impact sediments that cover the crater peak ring, just below the lowermost Danian pelagic limestone. Within years to decades after the impact event, this part of the Chicxulub impact basin returned to a relatively low-energy depositional environment, recording in unprecedented detail the recovery of life during the succeeding millennia. The iridium layer provides a key temporal horizon precisely linking Chicxulub to K-Pg boundary sections worldwide