Iron phthalocyanine and MnOx composite catalysts for microbial fuel cell applications

AbstractA low cost iron phthalocyanine (FePc)-MnOx composite catalyst was prepared for the oxygen reduction reaction (ORR) in the cathode of microbial fuel cells (MFCs).The catalysts were characterised using rotating ring disc electrode technique. The n number of electrons transferred, and H2O2 production from ORR was investigated. The FePc–MnOx composite catalyst showed higher ORR reduction current than FePc and Pt in low overpotential region. MFC with composite catalysts on the cathode was tested and compared to Pt and FePc cathodes. The cell performance was evaluated in buffered primary clarifier influent from wastewater treatment plant. The membrane-less single chamber MFC generated more power with composite FePcMnOx/MON air cathodes (143mWm−2) than commercial platinum catalyst (140mWm−2) and unmodified FePc/MON (90mWm−2), which is consistent with the RRDE study.The improvement was due to two mechanisms which abate H2O2 release from the composite. H2O2 is the reactant in two processes: (i) chemical regeneration of MnOx after electro-reduction to Mn2+, and (ii) peroxide undergoing chemical disproportionation to O2 and H2O on an electrochemically aged manganese surface retained in the film. Process (i) has the potential to sustain electrochemical reduction of MnOx at cathode potentials as high as 1.0VRHE

Active thermal mass enhancement using phase change materials

Buildings account for around 40% of energy consumption in the UK. For over twenty years active thermal mass systems have been a feature in low-energy buildings in northern Europe. By passing ventilation air, and utilising night ventilation, through the hollow core structures efficient heating and cooling has been achieved. Despite the success, such systems suffer from space overheating and efficiency losses during extended hot periods. Control strategies have largely mitigated this effect however low cost retrofit solutions that enhance the system are of interest. This research therefore investigates the benefit of using innovative phase change material (PCM) solutions to enhance thermal comfort and reduced energy usage of traditional active thermal mass systems. A prototype PCM enhancement was constructed, with energy saving and comfort benefits investigated under controlled laboratory conditions. In absolute terms the PCM solution offered an additional 12.5% energy storage capacity and a 29% increase in active surface area, coupled with the existing sensible thermal mass. Under laboratory conditions the PCM addition saved an additional 0.1 kWh per day, delayed AC onset by 1.2 h and offered an average 1.0 °C reduction in room temperature during 8 h of fixed internal heat gain, contrasted against the original active thermal mass system