514 research outputs found
Effects of Nitrogen Photoabsorption Cross Section Resolution on Minor Species Vertical Profiles in Titan's Upper Atmosphere
The significant variations in both measured and modeled densities of minor species in Titan's atmosphere call for the evaluation of possible influencing factors in photochemical modeling. The effect of nitrogen photoabsorption cross section selection on the modeled vertical profiles of minor species is analyzed here, with particular focus on C2H6 and HCN. Our results show a clear impact of cross sections used on all neutral and ion species studied. Affected species include neutrals and ions that are not primary photochemical products, including species that do not even contain nitrogen. The results indicate that photochemical models that employ low-resolution cross sections may significantly miscalculate the vertical profiles of minor species. Such differences are expected to have important implications for Titan's overall atmospheric structure and chemistry.NASA Outer Planet Research program NNH12ZDA001NInstitute for Computational Engineering and Sciences (ICES
Hdo And SO2 Thermal Mapping On Venus: Evidence For Strong SO2 Variability
We have been using the TEXES high-resolution imaging spectrometer at the NASA Infrared Telescope Facility to map sulfur dioxide and deuterated water over the disk of Venus. Observations took place on January 10-12, 2012. The diameter of Venus was 13 arcsec, with an illumination factor of 80%. Data were recorded in the 1344-1370 cm(-1) range (around 7.35 mu m) with a spectral resolving power of 80 000 and a spatial resolution of about 1.5 arcsec. In this spectral range, the emission of Venus comes from above the cloud top (z = 60-80 km). Four HDO lines and tens of SO2 lines have been identified in our spectra. Mixing ratios have been estimated from HDO/CO2 and SO2/CO2 line depth ratios, using weak neighboring transitions of comparable depths. The HDO maps, recorded on Jan. 10 and Jan. 12, are globally uniform with no significant variation between the two dates. A slight enhancement of the HDO mixing ratio toward the limb might be interpreted as a possible increase of the D/H ratio with height above the cloud level. The mean H2O mixing ratio is found to be 1.5 +/-0.75 ppm, assuming a D/H ratio of 0.0312 (i.e. 200 times the terrestrial value) over the cloud deck. The SO2 maps, recorded each night from Jan. 10 to Jan. 12, show strong variations over the disk of Venus, by a factor as high as 5 to 10. In addition, the position of the maximum SO2 mixing ratio strongly varies on a timescale of 24 h. The maximum SO2 mixing ratio ranges between 75 +/-25 ppb and 125 +/-50 ppb between Jan. 10 and Jan. 12. The high variability of sulfur dioxide is probably a consequence of its very short photochemical lifetime.NASA NNX-08AE38A, NNX08AW33G S03NSF AST-0607312, AST-0708074Astronom
Characterization of Antimicrobial Methylated Tryptophan Retro Lactoferricin Peptides by Solid State NMR and Fluorescence Spectroscopy
Ne II Observations of Gas Motions in Compact and Ultracompact H II Regions
We present high spatial and spectral resolution observations of 16 Galactic compact and ultracompact H II regions in the [Ne II] 12.8 mu m fine-structure line. The small thermal width of the neon line and the high dynamic range of the maps provide an unprecedented view of the kinematics of compact and ultracompact H II regions. These observations solidify an emerging picture of the structure of ultracompact H II regions suggested in our earlier studies of G29.96-0.02 and Mon R2 IRS 1; systematic surface flows, rather than turbulence or bulk expansion, dominate the gas motions in the H II regions. The observations show that almost all of the sources have significant (5-20 km s(-1)) velocity gradients and that most of the sources are limb-brightened. In many cases, the velocity pattern implies tangential flow along a dense shell of ionized gas. None of the observed sources clearly fits into the categories of filled expanding spheres, expanding shells, filled blister flows, or cometary H II regions formed by rapidly moving stars. Instead, the kinematics and morphologies of most of the sources lead to a picture of H II regions confined to the edges of cavities created by stellar wind ram pressure and flowing along the cavity surfaces. In sources where the radio continuum and [Ne II] morphologies agree, the majority of the ionic emission is blueshifted relative to nearby molecular gas. This is consistent with sources lying on the near side of their natal clouds being less affected by extinction and with gas motions being predominantly outward, as is expected for pressure-driven flows.NSF AST-0607312, NSF-0708074SOFIA USRA8500-98-008NYSTAR Faculty Development ProgramNASA NNG 04-GG92G, CAN-NCC5-679Lunar and Planetary InstituteAstronom
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HDO And SO2 Thermal Mapping On Venus II. The So2 Spatial Distribution Above And Within The Clouds
Sulfur dioxide and water vapor, two key species of Venus photochemistry, are known to exhibit significant spatial and temporal variations above the cloud top. In particular, ground-based thermal imaging spectroscopy at high spectral resolution, achieved on Venus in January 2012, has shown evidence for strong SO2 variations on timescales shorter than a day. We have continued our observing campaign using the TEXES high-resolution imaging spectrometer at the NASA InfraRed Telescope Facility to map sulfur dioxide over the disk of Venus at two different wavelengths, 7 mu m (already used in the previous study) and 19 mu m. The 7 mu m radiation probes the top of the H2SO4 cloud, while the 19 mu m radiation probes a few kilometers below within the cloud. Observations took place on October 4 and 5, 2012. Both HDO and SO2 lines are identified in our 7-mu m spectra and SO2 is also easily identified at 19 mu m. The CO2 lines at 7 and 19 mu m are used to infer the thermal structure. An isothermal/inversion layer is present at high latitudes (above 60 N and S) in the polar collars, which was not detected in October 2012. The enhancement of the polar collar in October 2012 is probably due to the fact that the morning terminator is observed, while the January data probed the evening terminator. As observed in our previous run, the HDO map is relatively uniform over the disk of Venus, with a mean mixing ratio of about 1 ppm. In contrast, the SO2 maps at 19 mu m show intensity variations by a factor of about 2 over the disk within the cloud, less patchy than observed at the cloud top at 7 mu m. In addition, the SO2 maps seem to indicate significant temporal changes within an hour. There is evidence for a cutoff in the SO2 vertical distribution above the cloud top, also previously observed by SPICAV/SOIR aboard Venus Express and predicted by photochemical models.NASA NNX-08AE38AIRTF AST-0607312, AST-0708074Astronom
Performance characteristics of several divergent-shroud aircraft ejectors
Performance characteristics of several divergent- shroud aircraft ejector
TEXES Observations of M Supergiants: Dynamics and Thermodynamics of Wind Acceleration
We have detected [Fe II] 17.94 um and 24.52 um emission from a sample of M
supergiants using TEXES on the IRTF. These low opacity emission lines are
resolved at R = 50, 000 and provide new diagnostics of the dynamics and
thermodynamics of the stellar wind acceleration zone. The [Fe II] lines, from
the first excited term, are sensitive to the warm plasma where energy is
deposited into the extended atmosphere to form the chromosphere and wind
outflow. These diagnostics complement previous KAO and ISO observations which
were sensitive to the cooler and more extended circumstellar envelopes. The
turbulent velocities, Vturb is about 12 to 13 km/s, observed in the [Fe II]
forbidden lines are found to be a common property of our sample, and are less
than that derived from the hotter chromospheric C II] 2325 Angstrom lines
observed in alpha Ori, where Vturb is about 17 to 19 km/s. For the first time,
we have dynamically resolved the motions of the dominant cool atmospheric
component discovered in alpha Ori from multi-wavelength radio interferometry by
Lim et al. (1998). Surprisingly, the emission centroids are quite Gaussian and
at rest with respect to the M supergiants. These constraints combined with
model calculations of the infrared emission line fluxes for alpha Ori imply
that the warm material has a low outflow velocity and is located close to the
star. We have also detected narrow [Fe I] 24.04 um emission that confirms that
Fe II is the dominant ionization state in alpha Ori's extended atmosphere.Comment: 79 pages including 10 figures and 2 appendices. Accepted by Ap
TEXES Observations of Pure Rotational H_2 Emission from AB Aurigae
We present observations of pure rotational molecular hydrogen emission from the Herbig Ae star, AB Aur. Our observations were made using the Texas Echelon Cross Echelle Spectrograph (TEXES) at the NASA Infrared Telescope Facility and the Gemini North Observatory. We searched for H_2 emission in the S(1), S(2), and S(4) lines at high spectral resolution and detected all three. By fitting a simple model for the emission in the three transitions, we derive T = 670 ± 40 K and M = 0.52 ± 0.15 M_⊙ for the emitting gas. On the basis of the 8.5 km s^(-1) FWHM of the S(2) line, assuming the emission comes from the circumstellar disk, and with an inclination estimate of the AB Aur system taken from the literature, we place the location for the emission near 18 AU. Comparison of our derived temperature to a disk structure model suggests that UV and X-ray heating are important in heating the disk atmosphere
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