Titanium phosphate for Fuel Cell Proton Conduction Membranes

Environmental issues due to increases in emissions of air pollutants and greenhouse gases are driving the development of clean energy delivery technologies such as fuel cells. Low temperature Proton Exchange Membrane Fuel Cells (PEMFC) use hydrogen as a fuel and their only emission is water. While significant advances have been made in recent years, a major limitation of the current technology is the cost and materials limitations of the proton conduction membrane. The proton exchange membrane performs three critical functions in the PEMFC membrane electrode assembly (MEA): (i) conduction of protons with minimal resistance from the anode (where they are generated from hydrogen) to the cathode (where they combine with oxygen and electrons, from the external circuit or load), (ii) providing electrical insulation between the anode and cathode to prevent shorting, and (iii) providing a gas impermeable barrier to prevent mixing of the fuel (hydrogen) and oxidant. The PFSA (perfluorosulphonic acid) family of membranes is currently the best developed proton conduction membrane commercially available, but these materials are limited to operation below 100oC (typically 80oC, or lower) due to the thermochemical limitations of this polymer. For both mobile and stationary applications, fuel cell companies require more durable, cost effective membrane technologies capable of delivering enhanced performance at higher temperatures (typically 120oC, or higher. This is driving research into a wide range of novel organic and inorganic materials with the potential to be good proton conductors and form coherent membranes. There are several research efforts recently reported in the literature employing inorganic nanomaterials. These include functionalised silica phosphates [1,2], fullerene [3] titania phosphates [4], zirconium pyrophosphate [5]. This work addresses the functionalisation of titania particles with phosphoric acid. Proton conductivity measurements are given together with structural properties

Disentangling the near infrared continuum spectral components of the inner 500 pc of Mrk 573: two-dimensional maps

We present a near infrared study of the spectral components of the continuum in the inner 500$\times$500 pc$^2$ of the nearby Seyfert galaxy Mrk573 using adaptive optics near-infrared integral field spectroscopy with the instrument NIFS of the Gemini North Telescope at a spatial resolution of $\sim$50 pc. We performed spectral synthesis using the {\sc starlight} code and constructed maps for the contributions of different age components of the stellar population: young ($age\leq100$ Myr), young-intermediate ($100<age\leq700$ Myr), intermediate-old ($700$ Myr $2$ Gyr) to the near-IR K-band continuum, as well as their contribution to the total stellar mass. We found that the old stellar population is dominant within the inner 250 pc, while the intermediate age components dominate the continuum at larger distances. A young stellar component contributes up to $\sim$20% within the inner $\sim$70 pc, while hot dust emission and featureless continuum components are also necessary to fit the nuclear spectrum, contributing up to 20% of the K-band flux there. The radial distribution of the different age components in the inner kiloparsec of Mrk573 is similar to those obtained by our group for the Seyfert galaxies Mrk1066, Mrk1157 and NGC1068 in previous works using a similar methodology. Young stellar populations ($\leq$100 Myr) are seen in the inner 200-300 pc for all galaxies contributing with $\ge$20% of the K-band flux, while the near-IR continuum is dominated by the contribution of intermediate-age stars ($t=$100 Myr-2 Gyr) at larger distances. Older stellar populations dominate in the inner 250 pc

Electron spin resonance detected by a superconducting qubit

A new method for detecting the magnetic resonance of electronic spins at low temperature is demonstrated. It consists in measuring the signal emitted by the spins with a superconducting qubit that acts as a single-microwave-photon detector, resulting in an enhanced sensitivity. We implement this new type of electron-spin resonance spectroscopy using a hybrid quantum circuit in which a transmon qubit is coupled to a spin ensemble consisting of NV centers in diamond. With this setup we measure the NV center absorption spectrum at 30mK at an excitation level of \thicksim15\,\mu_{B} out of an ensemble of 10^{11} spins.Comment: 6 pages, 4 figures, submitted to PR

A subida do nível do mar durante o Holocénico no Golfo de Cadiz – tendência regional e diferenças locais

In Guadiana River Estuary, the Holocene sequence is underlain by pebbly delta fan formed in two stages, prior to 5E and 3 highstands. The Holocene sedimentary sequence was lain either directly on gravels or on top of fluvial sands deposited between 11000 and 10000 yr. BP. An accelerated phase of infilling of the estuary by clayey sediments, containing marsh foraminifer Trochammina, began at ca. 9800 yr. BP when the sea level was about 39 m below the present.At ca. 7000 BP the central part of the estuary started to accommodate coarser sediments, partially introduced from the shelf. The first phase of the Holocene sea level rise at a rate of 0.85 m/century terminated at ca 6500yr. BP. Since then, the lagoonal bodies in the vicinity of estuary started to enclose behind sand spits and predominantly sandy sedimentation initiated within the estuary. After the second phase of a slower rise at the rate of 0.3 m/century, which lasted until ca. 5000 yr.BP, the sea approached the present level. Data from Guadalete Estuary published in Spain set the beginning of Holocene transgression at shallower level (ca 10m)than in Guadiana Estuary.This discrepancy may be explained by isostatic uplift of Betic Cordillera or slumping of Guadiana terrace on which the Holocene sediments are lain. Since 7500 yr. BP the data from Odiel-Tinto, Guadalete and Guadiana are in a relatively good agreement.INTERREG I

Alterações microbianas e químicas de um gleissolo sob macaubeiras nativas em função da variação sazonal e espacial.

RESUMO: A macaúba (Acrocomia aculeata) é uma alternativa para a produção de biodiesel e, consorciada com pastagem, pode auxiliar na recuperação de áreas degradadas. O objetivo deste trabalho foi estudar as alterações nos atributos microbiológicos, na matéria orgânica e no N total do solo, em função da variação sazonal e espacial em um Gleissolo sob maciço de macaubeiras nativas, no Cerrado. O estudo observacional foi realizado na região de Planaltina de Goiás, na Fazenda Agropecuária Santa Fé. Foram selecionadas dez árvores em uma mata com macaubeiras nativas no bioma cerrado. A coleta de solo foi realizada na camada de 0 a 10 centímetros de profundidade, sob uma linha horizontal, imaginária, traçada a partir da base do caule das macaubeiras. As amostras de solo foram coletadas a 50, 150 e 250 centímetros de distância do caule da palmeira, durante o verão chuvoso (março de 2010) e inverno seco (julho 2010). Para a avaliação estatística das variáveis observadas, utilizou-se um modelo misto. As médias das variáveis observadas foram submetidas a testes para verificar se seguiam a distribuição normal, e a homogeneidade de variâncias. Em seguida, os dados foram submetidos ao teste F e as médias foram comparadas pelo teste t. Os atributos carbono microbiano (Cmic), respiração basal (RB), quociente metabólico (qCO2), a matéria orgânica do solo (MOS) e a relação C/N do solo são sensíveis à variação sazonal e espacial em mata de macaubeiras no Cerrado. O nitrogênio total (NT) foi sensível à variação espacial. A microbiota presente no solo sob macaubal se manteve mais equilibrada durante o período seco, apresentando maiores teores de carbono microbiano e quociente microbiano e menor quociente metabólico e relação C/N do solo