Petrology and Geochemistry of Mafic-Ultramafic Fragments from the Aguablanca Ni-Cu Ore Breccia, Southwest Spain

Aguablanca (southwest Spain) is the first economic Ni-Cu-(PGE) deposit found in southern Europe. Two features make it an unusual example of magmatic sulfide ore: it is related to the development of an Andeantype continental magmatic arc, and it is hosted by a subvertical magmatic breccia. The structural style and the geodynamic context of the deposit contrast with most plutonic Ni-Cu-PGE deposits elsewhere, which occur at specific levels of layered mafic intrusions in rift environments. The Ni-Cu deposit is hosted by the Aguablanca intrusion, a mafic body composed of gabbronorite and minor quartz-diorite, gabbro, and norite. Sulfides are concentrated in a gabbronorite matrix along a subvertical (dipof 70º–80º N), funnel-like magmatic breccia that contains barren or slightly mineralized ultramafic-mafic cumulate fragments. Modal compositions of the fragments reflect a wide variety of rock types, including peridotite (hornblende-rich werhlite, dunite, and hornblende-rich harzburgite), pyroxenite (ortho- and clinopyroxenite), gabbro (gabbro, gabbronorite, and hornblende gabbro), and anorthosite. The primary silicate assemblage includes olivine (Fo91–Fo79), orthopyroxene (Mg no. 0.85–0.73), clinopyroxene (Mg no. 0.93–0.62), plagioclase (An99–An38), amphibole (Mg no. 0.87–0.68) and phlogopite (Mg no. 0.89–0.64). The wide range of rock types and the Fe-enrichment trends in the primary ferromagnesian silicates suggest magmatic differentiation processes from the parent melts, with the fragments representing different stages of cumulate formation. The ore-bearing breccia contains both semimassive and disseminated sulfides in the gabbronorite matrix. Textures vary between meso- and orthocumulate, and the rock-forming magmatic silicates are orthopyroxene (Mg no. 0.83–0.74), clinopyroxene (Mg no. 0.89–0.78), plagioclase (An50-An77), and intercumulus amphibole (Mg no. 0.86–0.70), phlogopite (0.84–0.69) and minor quartz. The gabbronorite in the matrix of the breccia is petrographically and chemically very similar to that of the unmineralized parts of the main Aguablanca intrusion and exhibits a similar differentiation trend, suggesting that the matrix of the ore-bearing breccia and the unmineralized rocks belong to a same magmatic suite. The local presence of mafic-ultramafic fragments in the barren Aguablanca intrusion supports this suggestion. The presence of highly Ni depleted olivine, whole-rock Cu/Zr ratios below 1, and the local occurrence of disseminations of magmatic sulfides in the peridotite fragments point to sulfide segregation before and/or during the formation of the peridotite cumulates. Mantle-normalized incompatible trace element patterns of the fragments along with published sulfur isotope data are consistent with crustal contamination, suggesting that addition of crustal sulfur from pyrite-bearing black slates led to sulfide saturation. These results support a model in which sulfides segregated and settled during the differentiation of an unexposed mafic-ultramafic complex, now sampled as fragments in the breccia, whereas the overlying silicate magma, most probably fed by successive fresh magma injections, underwent fractional crystallization, giving rise to this cumulate sequence. The emplacement of the ore breccia took place at temperatures above the (monosulfide solid solution (mss) solidus but below the olivine and pyroxene solidus, likely owing to the explosive injection of a new pulse of magma into the chamber, which mingled with the sulfide liquid and disrupted the overlying cumulate sequence. As a consequence, fragments reached their current position in the breccia, injected along with the sulfide and the silicate melts, which subsequently formed the sulfide-rich gabbronorite

Uralitization – An example from Kuusamo, Finland

The course of events as well as the chemical changes associated with the alteration of clinopyroxenes to uralite have been studied from diabases in Kuusamo, Finland. The uralitization takes place in several phases starting from the intercumulus spaces, where late-magmatic fluids cause an increase in iron and titanium in the pyroxene as a first phase of alteration. During the second phase the pyroxene is altered to actinolitic amphibole which appears as isolated flakes within the pyroxene, later the entire pyroxene crystal becomes filled with colourless amphibole. At this stage Fe, Ti, Al and K and Na are introduced internally from the rock-mass itself into the altering mineral. Some Ca is removed simultaneously. Finally, the amphibole changes into a green hornblende with additional introduction of the above elements. During the last phase the crystal boundaries of the original pyroxene are exceeded and the amphibole overflows from the pyroxene crystal spaces at the expense of the adjoining plagioclase that participates in the reaction. The density of the uralitized rock is somewhat lower than that of an unaltered counterpart. It is postulated that some silica is removed during the process to account for the drop in the density

Energy dispersive X-ray microanalysis of laminated sediments from Lake Valkiajärvi, Finland

Energy dispersive X-ray spectrometry is applied to the study of thinly laminated organic sediments of the iron-meromictic Lake Valkiajärvi, Finland. Si, Fe, Ca, K, S, (and Cl as an artefact) are present in detectable quantities. It is concluded that the main reason for the occurrence of such annual laminations (i.e. varves) in this lake is the seasonal variation in the deposition of mineral matter. Iron remains low throughout the year and does not play any important role in varve formation

The marginal border group of the Porttivaara layered intrusion and related sulphide mineralization

Basic magma intruded between the Archean gneisses and the discordantly overlying volcanics in the Early-Proterozoic era, and, following Fenner's series of differentiation crystallized into a layered sequence of the Porttivaara massif. A relatively complicated border group developed between the layered sequence and the Archean gneisses consisting of the following units, from the bottom upwards: albite-quartz rock, contact gabbro and ultramafitolites. The border zone contains sulphide dissemination which consists mainly of chalcopyrite, pentlandite and pyrrhotite. The sulphide dissemination formed during the intrusion of the magma, as contamination lowered the solubility of sulphides in the magma

Origen de los fragmentos máficos-ultramáficos de la brecha mineralizada del yacimiento de Ni-Cu-EGP de Aguablanca (Badajoz)

Depto. de Mineralogía y PetrologíaFac. de Ciencias GeológicasTRUEpu