420 research outputs found

    Alkyd-acrylic composite emulsions : polymerization and morphology

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    CO2FIX V2.0 : manual of a modeling framework for quantifying carbon sequestration in forest ecosystems and wood products

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    This reports presents a manual of the CO2FIX V 2.0 model. CO2FIX V 2.0 is a simple bookkeeping model that converts volumetric net annual increment data (and additional parameters) to annual carbon stocks and fluxes of the forest ecosystem-soil-wood products chain. It calculates on the hectare scale with time steps of one year. This Version 2.0 is a hectare scale model which was improved on the ability to simulate multi-species and uneven aged stands in multiple cohorts (e.g. selective tropical selective logging systems, and agroforestry systems); the ability to parametrize the growth also by stand density; the ability to deal with inter cohort competition; harvesting, allocation, processing lines, and end-of-life disposal of harvested wood; soil dynamics; the ability to deal with a wider variety of forest types including agro-forestry systems, selective logging systems, and post harvesting mortality; output viewing charts

    Trees as carbon sinks and sources in the European Union

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    http://www.elsevier.com/locate/issn/14629011The carbon (C) sinks and sources of trees that may be accounted for under Article 3.3 of the Kyoto Protocol during the first commitment period from 2008 to 2012 were estimated for the countries of the European Union (EU) based on existing forest inventory data. Two sets of definitions for the accounted activities, afforestation, reforestation and deforestation, were applied. Applying the definitions by the Food and Agricultural Organization of the United Nations (FAO), the trees were estimated to be a C source in eight and a C sink in seven countries, and in the whole EU a C source of 5.4 Tg year-1. Applying the definitions by the Intergovernmental Panel of Climate Change (IPCC), the trees were estimated to be a C source in three and a C sink in 12 countries, and in the whole EU a C sink of 0.1 Tg year-1. These estimates are small compared with the C sink of trees in all EU forests, 63 Tg year-1, the anthropogenic CO2 emissions of the EU, 880 Tg C year-1, and the reduction target of the CO2 emissions, 8%. In individual countries, the estimated C sink of the trees accounted for under Article 3.3 was at largest 8% and the C source 12% compared with the CO2 emissions. 7 2000 Elsevier Science Ltd. All rights reserved

    Arts handbook

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    1998 handbook for the faculty of Art

    Non-native hydrophobic interactions detected in unfolded apoflavodoxin by paramagnetic relaxation enhancement

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    Transient structures in unfolded proteins are important in elucidating the molecular details of initiation of protein folding. Recently, native and non-native secondary structure have been discovered in unfolded A. vinelandii flavodoxin. These structured elements transiently interact and subsequently form the ordered core of an off-pathway folding intermediate, which is extensively formed during folding of this α–β parallel protein. Here, site-directed spin-labelling and paramagnetic relaxation enhancement are used to investigate long-range interactions in unfolded apoflavodoxin. For this purpose, glutamine-48, which resides in a non-native α-helix of unfolded apoflavodoxin, is replaced by cysteine. This replacement enables covalent attachment of nitroxide spin-labels MTSL and CMTSL. Substitution of Gln-48 by Cys-48 destabilises native apoflavodoxin and reduces flexibility of the ordered regions in unfolded apoflavodoxin in 3.4 M GuHCl, because of increased hydrophobic interactions in the unfolded protein. Here, we report that in the study of the conformational and dynamic properties of unfolded proteins interpretation of spin-label data can be complicated. The covalently attached spin-label to Cys-48 (or Cys-69 of wild-type apoflavodoxin) perturbs the unfolded protein, because hydrophobic interactions occur between the label and hydrophobic patches of unfolded apoflavodoxin. Concomitant hydrophobic free energy changes of the unfolded protein (and possibly of the off-pathway intermediate) reduce the stability of native spin-labelled protein against unfolding. In addition, attachment of MTSL or CMTSL to Cys-48 induces the presence of distinct states in unfolded apoflavodoxin. Despite these difficulties, the spin-label data obtained here show that non-native contacts exist between transiently ordered structured elements in unfolded apoflavodoxin

    The incentive gap: LULUCF and the Kyoto mechanism before and after Durban

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    To-date, forest resource-based carbon accounting in land use, land use change and forestry (LULUCF) under the United Nations Framework Convention on Climate Change (UNFCCC), Kyoto Protocol (KP), European Union (EU) and national level emission reduction schemes considers only a fraction of its potential and fails to adequately mobilize the LULUCF sector for the successful stabilization of atmospheric greenhouse gas (GHG) concentrations. Recent modifications at the 2011 COP17 meetings in Durban have partially addressed this basic problem, but leave room for improvement. The presence of an Incentive Gap (IG) continues to justify reform of the LULUCF carbon accounting framework. Frequently neglected in the climate change mitigation and adaptation literature, carbon accounting practices ultimately define the nuts and bolts of what counts and which resources (forest, forest-based or other) are favored and utilized. For Annex I countries in the Kyoto Mechanism, the Incentive Gap under forest management (FM) is significantly large: some 75% or more of potential forestry-based carbon sequestration is not effectively incentivized or mobilized for climate change mitigation and adaptation (Ellison etal. 2011a). In this paper, we expand our analysis of the Incentive Gap to incorporate the changes agreed in Durban and encompass both a wider set of countries and a larger set of omitted carbon pools. For Annex I countries, based on the first 2years of experience in the first Commitment Period (CP1) we estimate the IG in FM at approximately 88%. Though significantly reduced in CP2, the IG remains a problem. Thus our measure of missed opportunities under the Kyoto and UNFCCC framework - despite the changes in Durban - remains important. With the exception perhaps of increased energy efficiency, few sinks or sources of reduced emissions can be mobilized as effectively and efficiently as forests. Thus, we wonder at the sheer magnitude of this underutilized resource

    Assessment of Forest Biomass and Carbon Stocks at Stand Level Using Site-Specific Primary Data to Support Forest Management

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    To quantify and map woody biomass (WB) and forest carbon (C) stocks, several models were developed. They differ in terms of scale of application, details related to the input data required and outputs provided. Local Authorities, such as Mountain Communities, can be supported in sustainable forest planning and management by providing specific models in which the reference unit is the same as the one reported in the Forest Management Plans (FMP), i.e. the forest stand. In the Lombardy Region (Northern Italy), a few studies were performed to assess WB and forest C stocks, and they were generally based on data coming from regional\u2014or national\u2014forest inventories and remote sensing, without taking into account data collected in the FMPs. For this study, the first version of the stand-level model \u201cWOody biomass and Carbon ASsessment\u201d (WOCAS) for WB and C stocks calculation was improved into a second version (WOCAS v2) and preliminary results about its first application to 2019 forest stands of Valle Camonica District (Lombardy Region) are presented. Since the model WOCAS uses the growing stock as the main driver for the calculation, it can be applied in any other forest area where the same input data are available
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