Reactivity of pi-complexes of Ti, V, and Nb towards dithioacetic acid: Synthesis and structure of novel metal sulfur-containing complexes

In order to use sulfur-containing resources economically and with minimal environmental damage, it is important to understand the desulfurization processes. Hydrodesulfurization, for example, is carried out on the surface of a heterogeneous metal sulfide catalyst. Studies of simple, soluble inorganic systems provide information regarding the structure and reactivity of sulfur-containing compounds with metal complexes. Further, consistent with recent trends in materials chemistry, many model compounds warrant further study as catalyst precursors. The reactivity of low-valent organometallic sandwich pi-complexes toward dithiocarboxylic acids is described. For example, treatment of bisbenzene vanadium with CH3CSSH affords a divanadium tetrakis(dithioacetate) complex. The crystallographically determined V-V bond distance, 2.800(2), is nearly the same as the V-V bond distance in a V(mu-nu squared-S2)2V' unit in the mineral patonite (VS4)n. The stability of the V2S4 core in the dimer is demonstrated by evidence of V2S4(+) in the mass spectrum (70 eV, solid probe) of the vanadium dimer. Several other systems relevant to HDS catalysis are also discussed

Learning from each other: A handbook for language teacher associations

The publication is aimed at those involved in the running of language teacher associations at international, national, regional and local levels. This may include paid employees or, more frequently, volunteers. It provides guidance on the effective running and networking of associations. It encourages language teacher associations to collaborate in order to support teachers more effectively, and to contribute to improvements in the quality of language teaching. It enables language teachers across the world to share their own ideas, to be involved in research, and to learn about the cutting-edge work of the ECML and its European project

Voneinander Lernen: Ein Handbuch für Sprachlehrerverbände

The publication is aimed at those involved in the running of language teacher associations at international, national, regional and local levels. This may include paid employees or, more frequently, volunteers. It provides guidance on the effective running and networking of associations. It encourages language teacher associations to collaborate in order to support teachers more effectively, and to contribute to improvements in the quality of language teaching. It enables language teachers across the world to share their own ideas, to be involved in research, and to learn about the cutting-edge work of the ECML and its European projects

Apprendre les uns des autres: Manuel pour les associations de professeurs de langues

The publication is aimed at those involved in the running of language teacher associations at international, national, regional and local levels. This may include paid employees or, more frequently, volunteers. It provides guidance on the effective running and networking of associations. It encourages language teacher associations to collaborate in order to support teachers more effectively, and to contribute to improvements in the quality of language teaching. It enables language teachers across the world to share their own ideas, to be involved in research, and to learn about the cutting-edge work of the ECML and its European project

Supersymmetric Yang-Mills-Chern-Simons theory

We prove that three-dimensional N=1 supersymmetric Yang-Mills-Chern-Simons theory is finite to all loops. This leaves open the possibility that different regularization methods give different finite effective actions. We show that for this model dimensional regularization and regularization by dimensional reduction yield the same effective action.Comment: 6 pages, 1 figure, latex, espcrc2. Contribution to the Proceedings of the 30th Ahrenshoop Symposium on the Theory of Elementary Particles, edited by D. Lust, H.-J. Otto and G. Weigt, to appear in Nuclear Physics B, Proceedings Supplemen

Integration-by-parts identities in FDR

Four-dimensional renormalized (FDR) integrals play an increasingly important role in perturbative loop calculations. Thanks to them, loop computations can be performed directly in four dimensions and with no ultraviolet (UV) counterterms. In this paper I prove that integration-by-parts (IBP) identities can be used to find relations among multi-loop FDR integrals. Since algorithms based on IBP are widely applied beyond one loop, this result represents a decisive step forward towards the use of FDR in multi-loop calculations.Comment: 13 page

Continuity of the four-point function of massive ϕ44\phi_4^4-theory above threshold

In this paper we prove that the four-point function of massive \vp_4^4-theory is continuous as a function of its independent external momenta when posing the renormalization condition for the (physical) mass on-shell. The proof is based on integral representations derived inductively from the perturbative flow equations of the renormalization group. It closes a longstanding loophole in rigorous renormalization theory in so far as it shows the feasibility of a physical definition of the renormalized coupling.Comment: 23 pages; to appear in Rev. Math. Physics few corrections, two explanatory paragraphs adde

Systematic Implementation of Implicit Regularization for Multi-Loop Feynman Diagrams

Implicit Regularization (IReg) is a candidate to become an invariant framework in momentum space to perform Feynman diagram calculations to arbitrary loop order. In this work we present a systematic implementation of our method that automatically displays the terms to be subtracted by Bogoliubov's recursion formula. Therefore, we achieve a twofold objective: we show that the IReg program respects unitarity, locality and Lorentz invariance and we show that our method is consistent since we are able to display the divergent content of a multi-loop amplitude in a well defined set of basic divergent integrals in one loop momentum only which is the essence of IReg. Moreover, we conjecture that momentum routing invariance in the loops, which has been shown to be connected with gauge symmetry, is a fundamental symmetry of any Feynman diagram in a renormalizable quantum field theory

Chern-Simons Theory as the Large Mass Limit of Topologically Massive Yang-Mills Theory

We study quantum Chern-Simons theory as the large mass limit of the limit $D\to 3$ of dimensionally regularized topologically massive Yang-Mills theory. This approach can also be interpreted as a BRS-invariant hybrid regularization of Chern-Simons theory, consisting of a higher-covariant derivative Yang-Mills term plus dimensional regularization. Working in the Landau gauge, we compute radiative corrections up to second order in perturbation theory and show that there is no two-loop correction to the one-loop shift $k\rightarrow k+ c_{\scriptscriptstyle V},\,\,k$ being the bare Chern-Simons parameter. In passing we also prove by explicit computation that topologically massive Yang-Mills theory is UV finite.Comment: 64 pages without figures (10 figures), DAMTP 91-34, LPTHE 91-61, NBI-HE 91-55, UGMS 91-2

Wedge-Local Quantum Fields and Noncommutative Minkowski Space

Within the setting of a recently proposed model of quantum fields on noncommutative Minkowski spacetime, the consequences of the consistent application of the proper, untwisted Poincare group as the symmetry group are investigated. The emergent model contains an infinite family of fields which are labelled by different noncommutativity parameters, and related to each other by Lorentz transformations. The relative localization properties of these fields are investigated, and it is shown that to each field one can assign a wedge-shaped localization region of Minkowski space. This assignment is consistent with the principles of covariance and locality, i.e. fields localized in spacelike separated wedges commute. Regarding the model as a non-local, but wedge-local, quantum field theory on ordinary (commutative) Minkowski spacetime, it is possible to determine two-particle S-matrix elements, which turn out to be non-trivial. Some partial negative results concerning the existence of observables with sharper localization properties are also obtained.Comment: Version to appear in JHEP, 27 page