478 research outputs found
Migration and public finances in the EU
We provide novel and comprehensive evidence on the net fiscal contributions of natives and migrants to the governmental budgets of EU countries. We account for income taxes and cash benefits, along with indirect taxes and in-kind benefits, which are often missing in standard datasets. We find that on average, migrants were net contributors to public finances over the period of 2014–2018 in the EU and, moreover, that they contribute approximately €1.5 thousand more per capita each year than natives. We also show that this difference is partly due to the selection on characteristics that make migrants net fiscal contributors, such as demographic factors and employment probability
Kinetic and Spectroscopic Characterisation of Highly Reactive Methanesulfonates. Leaving Group Effects for Solvolyses and Comments on Geminal Electronic Effects Influencing S1 Reactivity
Highly reactive methanesulfonates (mesylates, ROMs) have been prepared from 1-phenylethanol. cyclohex-2-en-1-ol, diphenylmethanol and p-methoxybenzyl alcohol by treatment with methanesulfonyl chloride and triethylamine in dichloro- or trichloro-methane at - 20 to 0 °C. The mesylates. characterised in solution by H and C NMR at -20 °C, were obtained in satisfactory purity (ca. 95%) in cold solutions but they decomposed by reaction with chloride, triethylamine or the parent alcohol. Rate constants for solvolyses in aqueous acetone and aqueous ethanol have been determined by a fast response conductimetric method. Product selectivities for solvolyses of pmethoxybenzyl mesylate in aqueous ethanol and methanol at 0 °C have been determined by HPLC. From additional new or Iiterature kinetic data for solvolyses of corresponding bromides. chlorides and p-nitrobenzoates (OPNB). Br/CI. OMs/Br and OMs/OPNB rate ratios were calculated; the results are consistent with electronic effects stabilising the carbocationic transition states and increasing OMs/Br rate ratios for these SN 1 solvolyses; none of the evidence supports a geminal electronic effect on Br/CI rate ratios (e.g. caused by stabilisation of the initial state in pmethoxybenzyl chloride). Steric effects on ester /halide rate ratios for solvolyses of tertiary substrates are confirmed. Relative rates over a 10 range for ester and halide leaving groups are evaluated for solvolyses of 1-phenylethyl substrates in 80% ethanol-water. updating previous work by Noyce et al. (1972)
Upturn observed in heavy nuclei to iron ratios by the ATIC-2 experiment
The ratios of fluxes of heavy nuclei from sulfur (Z=16) to chromium (Z=24) to
the flux of iron were measured by the ATIC-2 experiment. The ratios are
decreasing functions of energy from 5 GeV/n to approximately 80 GeV/n, as
expected. However, an unexpected sharp upturn in the ratios are observed for
energies above 100 GeV/n for all elements from Z=16 to Z=24. Similar upturn but
with lower amplitude was also discovered in the ATIC-2 data for the ratio of
fluxes of abundant even nuclei (C, O, Ne, Mg, Si) to the flux of iron.
Therefore the spectrum of iron is significantly different from the spectra of
other abundant even nuclei.Comment: 4 pages, LaTeX2e, a paper for 23rd European Cosmic Ray Symposium
(2012
Possible structure in the cosmic ray electron spectrum measured by the ATIC-2 and ATIC-4 experiments
A strong excess in a form of a wide peak in the energy range of 300-800 GeV
was discovered in the first measurements of the electron spectrum in the energy
range from 20 GeV to 3 TeV by the balloon-borne experiment ATIC (J. Chang et
al. Nature, 2008). The experimental data processing and analysis of the
electron spectrum with different criteria for selection of electrons,
completely independent of the results reported in (J. Chang et al. Nature,
2008) is employed in the present paper. The new independent analysis generally
confirms the results of (J. Chang et al. Nature, 2008), but shows that the
spectrum in the region of the excess is represented by a number of narrow
peaks. The measured spectrum is compared to the spectrum of (J. Chang et al.
Nature, 2008) and to the spectrum of the Fermi/LAT experiment.Comment: LaTeX2e, 10 pages, 4 figures, a paper for ECRS 2010 (Turku, Finland);
http://www.astrophys-space-sci-trans.net/7/119/2011
Relative abundances of cosmic ray nuclei B-C-N-O in the energy region from 10 GeV/n to 300 GeV/n. Results from ATIC-2 (the science flight of ATIC)
The ATIC balloon-borne experiment measures the energy spectra of elements
from H to Fe in primary cosmic rays from about 100 GeV to 100 TeV. ATIC is
comprised of a fully active bismuth germanate calorimeter, a carbon target with
embedded scintillator hodoscopes, and a silicon matrix that is used as the main
charge detector. The silicon matrix produces good charge resolution for protons
and helium but only partial resolution for heavier nuclei. In the present
paper, the charge resolution of ATIC was improved and backgrounds were reduced
in the region from Be to Si by using the upper layer of the scintillator
hodoscope as an additional charge detector. The flux ratios of nuclei B/C, C/O,
N/O in the energy region from about 10 GeV/nucleon to 300 GeV/nucleon obtained
from this high-resolution, high-quality charge spectra are presented, and
compared with existing theoretical predictions.Comment: 4 pages,2 figures, a paper for 30-th International Cosmic Rays
Conferenc
FiberGLAST: a scintillating fiber approach to the GLAST mission
FiberGLAST is a scintillating fiber gamma-ray detector designed for the GLAST mission. The system described below provides superior effective area and field of view for modest cost and risk. An overview of the FiberGLAST instrument is presented, as well as a more detailed description of the principle elements of the primary detector volume. The triggering and readout electronics are described, and Monte Carlo Simulations of the instrument performance are presented
Energy dependence of Ti/Fe ratio in the Galactic cosmic rays measured by the ATIC-2 experiment
Titanium is a rare, secondary nucleus among Galactic cosmic rays. Using the
Silicon matrix in the ATIC experiment, Titanium has been separated. The energy
dependence of the Ti to Fe flux ratio in the energy region from 5 GeV per
nucleon to about 500 GeV per nucleon is presented.Comment: 8 pages, 4 figures, accepted for publication in Astronomy Letter
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