243 research outputs found
Fast relaxation in a fragile liquid under pressure
The incoherent dynamic structure factor of ortho-terphenyl has been measured
by neutron time-of-flight and backscattering technique in the pressure range
from 0.1 MPa to 240 MPa for temperatures between 301 K and 335 K.
Tagged-particle correlations in the compressed liquid decay in two steps. The
alpha-relaxation lineshape is independent of pressure, and the relaxation time
proportional to viscosity. A kink in the amplitude f_Q(P) reveals the onset of
beta relaxation. The beta-relaxation regime can be described by the
mode-coupling scaling function; amplitudes and time scales allow a consistent
determination of the critical pressure P_c(T). alpha and beta relaxation depend
in the same way on the thermodynamic state; close to the mode-coupling
cross-over, this dependence can be parametrised by an effective coupling Gamma
~ n*T**{-1/4}.Comment: 4 Pages of RevTeX, 4 figures (submitted to Physical Review Letters
Flow equations for cold Bose gases
Wederive flow equations for cold atomic gases with one macroscopically populated energy level. The
generator is chosen such that the ground state decouples from all other states in the system as the
renormalization group flow progresses.Wepropose a self-consistent truncation scheme for the flow
equations at the level of three-body operators and show how they can be used to calculate the ground
state energy of a generalN-body system. Moreover, we provide a general method to estimate the
truncation error in the calculated energies. Finally, we test our scheme by benchmarking to the exactly
solvable LiebâLiniger model and find good agreement for weak and moderate interaction strengths
On the correlation between fragility and stretching in glassforming liquids
We study the pressure and temperature dependences of the dielectric
relaxation of two molecular glassforming liquids, dibutyl phtalate and
m-toluidine. We focus on two characteristics of the slowing down of relaxation,
the fragility associated with the temperature dependence and the stretching
characterizing the relaxation function. We combine our data with data from the
literature to revisit the proposed correlation between these two quantities. We
do this in light of constraints that we suggest to put on the search for
empirical correlations among properties of glassformers. In particular, argue
that a meaningful correlation is to be looked for between stretching and
isochoric fragility, as both seem to be constant under isochronic conditions
and thereby reflect the intrinsic effect of temperature
Assessing the risk of central post-stroke pain of thalamic origin by lesion mapping
Central post-stroke pain of thalamic origin is an extremely distressing and often refractory disorder. There are no well-established predictors for pain development after thalamic stroke, and the role of different thalamic nuclei is unclear. Here, we used structural magnetic resonance imaging to identify the thalamic nuclei, specifically implicated in the generation of central post-stroke pain of thalamic origin. Lesions of 10 patients with central post-stroke pain of thalamic origin and 10 control patients with thalamic strokes without pain were identified as volumes of interest on magnetic resonance imaging data. Non-linear deformations were estimated to match each image with a high-resolution template and were applied to each volume of interest. By using a digital atlas of the thalamus, we elucidated the involvement of different nuclei with respect to each lesion. Patient and control volumes of interest were summed separately to identify unique areas of involvement. Voxelwise odds ratio maps were calculated to localize the anatomical site where lesions put patients at risk of developing central post-stroke pain of thalamic origin. In the patients with pain, mainly lateral and posterior thalamic nuclei were affected, whereas a more anterior-medial lesion pattern was evident in the controls. The lesions of 9 of 10 pain patients overlapped at the border of the ventral posterior nucleus and the pulvinar, coinciding with the ventrocaudalis portae nucleus. The lesions of this area showed an odds ratio of 81 in favour of developing thalamic pain. The high odds ratio at the ventral posterior nucleus-pulvinar border zone indicates that this area is crucial in the pathogenesis of thalamic pain and demonstrates the feasibility of identifying patients at risk of developing central post-stroke pain of thalamic origin early after thalamic insults. This provides a basis for pre-emptive treatment studie
Ice XII in its second regime of metastability
We present neutron powder diffraction results which give unambiguous evidence
for the formation of the recently identified new crystalline ice phase[Lobban
et al.,Nature, 391, 268, (1998)], labeled ice XII, at completely different
conditions. Ice XII is produced here by compressing hexagonal ice I_h at T =
77, 100, 140 and 160 K up to 1.8 GPa. It can be maintained at ambient pressure
in the temperature range 1.5 < T < 135 K. High resolution diffraction is
carried out at T = 1.5 K and ambient pressure on ice XII and accurate
structural properties are obtained from Rietveld refinement. At T = 140 and 160
K additionally ice III/IX is formed. The increasing amount of ice III/IX with
increasing temperature gives an upper limit of T ~ 150 K for the successful
formation of ice XII with the presented procedure.Comment: 3 Pages of RevTeX, 3 tables, 3 figures (submitted to Physical Review
Letters
Structural relaxation in a system of dumbbell molecules
The interaction-site-density-fluctuation correlators, the dipole-relaxation
functions, and the mean-squared displacements of a system of symmetric
dumbbells of fused hard spheres are calculated for two representative
elongations of the molecules within the mode-coupling theory for the evolution
of glassy dynamics. For large elongations, universal relaxation laws for states
near the glass transition are valid for parameters and time intervals similar
to the ones found for the hard-sphere system. Rotation-translation coupling
leads to an enlarged crossover interval for the mean-squared displacement of
the constituent atoms between the end of the von Schweidler regime and the
beginning of the diffusion process. For small elongations, the superposition
principle for the reorientational -process is violated for parameters
and time intervals of interest for data analysis, and there is a strong
breaking of the coupling of the -relaxation scale for the diffusion
process with that for representative density fluctuations and for dipole
reorientations.Comment: 15 pages, 14 figures, Phys. Rev. E in pres
Molecular dynamics simulation of the fragile glass former ortho-terphenyl: a flexible molecule model
We present a realistic model of the fragile glass former orthoterphenyl and
the results of extensive molecular dynamics simulations in which we
investigated its basic static and dynamic properties. In this model the
internal molecular interactions between the three rigid phenyl rings are
described by a set of force constants, including harmonic and anharmonic terms;
the interactions among different molecules are described by Lennard-Jones
site-site potentials. Self-diffusion properties are discussed in detail
together with the temperature and momentum dependencies of the
self-intermediate scattering function. The simulation data are compared with
existing experimental results and with the main predictions of the Mode
Coupling Theory.Comment: 20 pages and 28 postscript figure
Crystal-like high frequency phonons in the amorphous phases of solid water
The high frequency dynamics of low- (LDA) and high-density amorphous-ice
(HDA) and of cubic ice (I_c) has been measured by inelastic X-ray Scattering
(IXS) in the 1-15 nm^{-1} momentum transfer (Q) range. Sharp phonon-like
excitations are observed, and the longitudinal acoustic branch is identified up
to Q = 8nm^{-1} in LDA and I_c and up to 5nm^{-1} in HDA. The narrow width of
these excitations is in sharp contrast with the broad features observed in all
amorphous systems studied so far. The "crystal-like" behavior of amorphous
ices, therefore, implies a considerable reduction in the number of decay
channels available to sound-like excitations which is assimilated to low local
disorder.Comment: 4 pages, 3 figure
Static and Dynamic Properties of a Viscous Silica Melt Molecular Dynamics Computer Simulations
We present the results of a large scale molecular dynamics computer
simulation in which we investigated the static and dynamic properties of a
silica melt in the temperature range in which the viscosity of the system
changes from O(10^-2) Poise to O(10^2) Poise. We show that even at temperatures
as high as 4000 K the structure of this system is very similar to the random
tetrahedral network found in silica at lower temperatures. The temperature
dependence of the concentration of the defects in this network shows an
Arrhenius law. From the partial structure factors we calculate the neutron
scattering function and find that it agrees very well with experimental neutron
scattering data. At low temperatures the temperature dependence of the
diffusion constants shows an Arrhenius law with activation energies which
are in very good agreement with the experimental values. With increasing
temperature we find that this dependence shows a cross-over to one which can be
described well by a power-law, D\propto (T-T_c)^gamma. The critical temperature
T_c is 3330 K and the exponent gamma is close to 2.1. Since we find a similar
cross-over in the viscosity we have evidence that the relaxation dynamics of
the system changes from a flow-like motion of the particles, as described by
the ideal version of mode-coupling theory, to a hopping like motion. We show
that such a change of the transport mechanism is also observed in the product
of the diffusion constant and the life time of a Si-O bond, or the space and
time dependence of the van Hove correlation functions.Comment: 30 pages of Latex, 14 figure
Afforestation impact on soil temperature in regional climate model simulations over Europe
In the context of the first phase of the Coordinated Regional Climate Downscaling Experiment in the European domain (EURO-CORDEX) flagship plot study on Land Use and Climate Across Scales (LUCAS), we investigate the biophysical impact of afforestation on the seasonal cycle of soil temperature over the European continent with an ensemble of 10 regional climate models. For this purpose, each ensemble member performed two idealized land cover experiments in which Europe is covered either by forests or grasslands. The multi-model mean exhibits a reduction of the annual amplitude of soil temperature (AAST) due to afforestation over all European regions, although this is not a robust feature among the models. In the Mediterranean, the spread of simulated AAST response to afforestation is between â4 and +2ââC at 1âm below the ground, while in Scandinavia the inter-model spread ranges from â7 to +1ââC. We show that the large range in the simulated AAST response is due to the representation of the summertime climate processes and is largely explained by inter-model differences in leaf area index (LAI), surface albedo, cloud fraction and soil moisture, when all combined into a multiple linear regression. The changes in these drivers essentially determine the ratio between the increased radiative energy at surface (due to lower albedo in forests) and the increased sum of turbulent heat fluxes (due to mixing-facilitating characteristics of forests), and consequently decide the changes in soil heating with afforestation in each model. Finally, we pair FLUXNET sites to compare the simulated results with observation-based evidence of the impact of forest on soil temperature. In line with models, observations indicate a summer ground cooling in forested areas compared to open lands. The vast majority of models agree with the sign of the observed reduction in AAST, although with a large variation in the magnitude of changes. Overall, we aspire to emphasize the biophysical effects of afforestation on soil temperature profile with this study, given that changes in the seasonal cycle of soil temperature potentially perturb crucial biochemical processes. Robust knowledge on biophysical impacts of afforestation on soil conditions and its feedbacks on local and regional climate is needed in support of effective land-based climate mitigation and adaption policies
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