24 research outputs found
Hubungan antara Sikap Konsumen dan Norma Subjektif dengan Minat Nasabah untuk Bertransaksi Logam Mulia di Pegadaian Syariah (Studi Kasus : Pegadaian Syariah Cabang Kramat Raya, Jakarta )
The purpose of this study was to determine whether the belief factor, the evaluation results, subjective norm and motivation have a correlation consumer interest in “logam mulia” sharia pawnshop transaction. Analytical techniques used in this study is correlation. Samples used in this study as many as 91 respondents. The results of this study showed that consumer interest to conduct transactions in “logam mulia” sharia pawnshop transaction is not related to his conviction, while the evaluation of results, subjective norms, and motivation have a positive relationship with consumer interest in “logam mulia” sharia pawnshop transaction
Thermolysis of trifluoromethyl-containing vinyldiazocarbonyl compounds and X-ray crystal structure analysis of unexpected reaction products
Two unusual compounds, 1,3a,6,6a-tetrahydro-3a,6a-bis(trifluoromethyl)-cyclopenta[c]pyrazol-3,4,5,6-tetracarboxylic acid tetramethyl ester (C16H14N2O8F6) (3) and 2-acetyl-5,7-bis(trifluoromethyl)-4-methyl-3-methoxy-2,4,6-cycloheptatrienecarboxylic acid methyl ester (C14H11F6O3) (4), were obtained from thermolysis of 3-trifluoromethyl-substituted vinyldiazocarbonyl compounds. The crystal structures of the products were determined as part of a larger comparison study on the thermal and Rh(II)-catalyzed reactions of F- and H-vinyldiazocarbonyl compounds. The resulting structures provide the first crystallographic characterization of bis(trifluoromethyl)substituted compounds of this kind. The pure compounds with all-carbon (4) and half-heterocyclic (3) skeletons are composed of a
seven- and two-annulated five-membered rings in folded butterfly and envelope conformations, respectively
Influence of an Internal Trifluoromethyl Group on the Rhodium(II)-Catalyzed Reactions of Vinyldiazocarbonyl Compounds
Incorporation
of a trifluoromethyl group into the structure of
4-(alkoxycarbonyl)vinyldiazocarbonyl compounds greatly decreases the
tendency of the carbenoid intermediates formed during Rh(II)-catalyzed
reactions to undergo <i>intermolecular</i> processes. Instead,
they are prone to experience <i>intramolecular</i> [1,5]-
and [1,3]-electrocyclizations to produce reactive cyclopropenes and
furans, and these are capable of further transformations
Influence of an Internal Trifluoromethyl Group on the Rhodium(II)-Catalyzed Reactions of Vinyldiazocarbonyl Compounds
Incorporation
of a trifluoromethyl group into the structure of
4-(alkoxycarbonyl)vinyldiazocarbonyl compounds greatly decreases the
tendency of the carbenoid intermediates formed during Rh(II)-catalyzed
reactions to undergo <i>intermolecular</i> processes. Instead,
they are prone to experience <i>intramolecular</i> [1,5]-
and [1,3]-electrocyclizations to produce reactive cyclopropenes and
furans, and these are capable of further transformations