Surface-Enhanced Plasmon Splitting in a Liquid-Crystal-Coated Gold Nanoparticle

We show that, when a gold nanoparticle is coated by a thin layer of nematic liquid crystal, the deformation produced by the nanoparticle surface can enhance the splitting of the nanoparticle surface plasmon. We consider three plausible liquid crystal director configurations in zero electric field: boojum pair (north-south pole configuration), baseball (tetrahedral), and homogeneous. From a calculation using the Discrete Dipole Approximation, we find that the surface plasmon splitting is largest for the boojum pair, intermediate for the homogeneous, and smallest for the baseball configuration. The boojum pair results are in good agreement with experiment. We conclude that the nanoparticle surface has a strong effect on the director orientation, but, surprisingly, that this deformation can actually enhance the surface plasmon splitting.Comment: 5 pages, 3 figures To be published in PR

Correlated analytical studies of organic material from the Tagish Lake carbonaceous chondrite

We report on correlated studies of organic material using SIMS, FIB-SEM, and TEM

Quantum Monte Carlo study of a magnetic-field-driven 2D superconductor-insulator transition

We numerically study the superconductor-insulator phase transition in a model disordered 2D superconductor as a function of applied magnetic field. The calculation involves quantum Monte Carlo calculations of the (2+1)D XY model in the presence of both disorder and magnetic field. The XY coupling is assumed to have the form -J\cos(\theta_i-\theta_j-A_{ij}), where A_{ij} has a mean of zero and a standard deviation \Delta A_{ij}. In a real system, such a model would be approximately realized by a 2D array of small Josephson-coupled grains with slight spatial disorder and a uniform applied magnetic field. The different values \Delta A_{ij} then corresponds to an applied field such that the average number of flux quanta per plaquette has various integer values N: larger N corresponds to larger \Delta A_{ij}. For any value of \Delta A_{ij}, there appears to be a critical coupling constant K_c(\Delta A_{ij})=\sqrt{[J/(2U)]_c}, where U is the charging energy, above which the system is a Mott insulator; there is also a corresponding critical conductivity \sigma^*(\Delta A_{ij}) at the transition. For \Delta A_{ij}=\infty, the order parameter of the transition is a renormalized coupling constant g. Using a numerical technique appropriate for disordered systems, we show that the transition at this value of \Delta A_{ij} takes place from an insulating (I) phase to a Bose glass (BG) phase, and that the dynamical critical exponent characterizing this transition is z \sim 1.3. By contrast, z=1 for this model at \Delta A_{ij}=0. We suggest that the superconductor to insulator transition is actually of this I to BG class at all nonzero \Delta A_{ij}'s, and we support this interpretation by both numerical evidence and an analytical argument based on the Harris criterion.Comment: 17 pages, 23 figures, accepted for publication in Phys. Rev.

There are many barriers to species’ migrations

Temperature-change trajectories are being used to identify the geographic barriers and thermal ‘cul-de-sacs’ that will limit the ability of many species to track climate change by migrating. We argue that there are many other potential barriers to species’ migrations. These include stable ecotones, discordant shifts in climatic variables, human land use, and species’ limited dispersal abilities. To illustrate our argument, for each 0.5° latitude/longitude grid cell of the Earth’s land surface, we mapped and tallied the number of cells for which future (2060–2080) climate represents an analog of the focal cell’s current climate. We compared results when only considering temperature with those for which both temperature and total annual precipitation were considered in concert. We also compared results when accounting for only geographic barriers (no cross-continental migration) with those involving both geographic and potential ecological barriers (no cross-biome migration). As expected, the number of future climate analogs available to each pixel decreased markedly with each added layer of complexity (e.g. the proportion of the Earth’s land surface without any available future climate analogs increased from 3% to more than 36% with the inclusion of precipitation and ecological boundaries). While including additional variables can increase model complexity and uncertainty, we must strive to incorporate the factors that we know will limit species’ ranges and migrations if we hope to predict the effects of climate change at a high-enough degree of accuracy to guide management decisions

Determination of Interface Atomic Structure and Its Impact on Spin Transport Using Z-Contrast Microscopy and Density-Functional Theory

We combine Z-contrast scanning transmission electron microscopy with density-functional-theory calculations to determine the atomic structure of the Fe/AlGaAs interface in spin-polarized light-emitting diodes. A 44% increase in spin-injection efficiency occurs after a low-temperature anneal, which produces an ordered, coherent interface consisting of a single atomic plane of alternating Fe and As atoms. First-principles transport calculations indicate that the increase in spin-injection efficiency is due to the abruptness and coherency of the annealed interface.Comment: 16 pages (including cover), 4 figure

Anolis Newsletter VII

Newsletter for the 7th Anolis Symposium, Fairchild Tropical Botanic Gardens, Miami, Florida, 17-18 March 2018. It had been nearly a decade since the previous Anolis symposium was held in Cambridge, MA, at the Museum for Comparative Zoology, Harvard. A reunion of anole biologists en masse was long past due and it was decided that this symposium would be slightly different – we were going to hold it somewhere with anoles! And so, on the weekend of 17-18th March, 2018, nearly 70 anole biologists traveled to sunny south Florida to attend the 7th Anolis Symposium held at the beautiful Fairchild Tropical Botanic Gardens in Miami. In the grounds of the botanical gardens, attendees were presented with a diverse community of six (!) species of anole, both native and non-native, representing four distinct ecomorphs

Correlated analyses of D- and 15N-rich carbon grains from CR2 chondrite EET 92042

Extract from introduction: Insoluble organic matter (IOM) and matrix from primitive carbonaceous chondrites carry isotope enrichments (?D?20000', ?15N?3200�) that are comparable to those in interplanetary dust particles [1, this work]. Hence, primitive organics that formed in the protosolar cloud (PSC) – or maybe in the cold outer regions of the protoplanetary disk – survived accretion and planetary processing on the asteroids, the parent bodies of the chondrites

Correlated Microscale Isotope and Scanning Transmission X-Ray Analyses of Isotopically Anomalous Organic Matter from the CR2 Chondrite EET 92042

We discuss correlated examinations of organic matter from the CR2 chondrite EET 92042, using SIMS, STXM and other methods. We found a large, isotopically highly anomalous region of probable presolar origin that is C- and 13C-poor and 15N-rich

Secondary ion mass spectrometry and x-ray absorption near-edge structure spectroscopy of isotopically anomalous organic matter from CR1 chondrites GRO 95577

We located interstellar organics from a CR1 chondrite with NanoSIMS and analyzed FIB-extracted sections with XANES. D-rich material appears not associated with a functional group, whereas 15N-rich matter shows some affinity to nitrile functionality