388 research outputs found
Magnetic Field Dependent Tunneling in Glasses
We report on experiments giving evidence for quantum effects of
electromagnetic flux in barium alumosilicate glass. In contrast to expectation,
below 100 mK the dielectric response becomes sensitive to magnetic fields. The
experimental findings include both, the complete lifting of the dielectric
saturation by weak magnetic fields and oscillations of the dielectric response
in the low temperature resonant regime. As origin of these effects we suggest
that the magnetic induction field violates the time reversal invariance leading
to a flux periodicity in the energy levels of tunneling systems. At low
temperatures, this effect is strongly enhanced by the interaction between
tunneling systems and thus becomes measurable.Comment: 4 pages, 4 figure
Low temperature acoustic properties of amorphous silica and the Tunneling Model
Internal friction and speed of sound of a-SiO(2) was measured above 6 mK
using a torsional oscillator at 90 kHz, controlling for thermal decoupling,
non-linear effects, and clamping losses. Strain amplitudes e(A) = 10^{-8} mark
the transition between the linear and non-linear regime. In the linear regime,
excellent agreement with the Tunneling Model was observed for both the internal
friction and speed of sound, with a cut-off energy of E(min) = 6.6 mK. In the
non-linear regime, two different behaviors were observed. Above 10 mK the
behavior was typical for non-linear harmonic oscillators, while below 10 mK a
different behavior was found. Its origin is not understood.Comment: 1 tex file, 6 figure
Electrothermal Icing Protection of Aerosurfaces Using Conductive Polymer Nanocomposites
Ice protection systems (IPS) are critical components for many aerospace flight vehicles, including commercial transports and unmanned aerial systems (UAS), and can include anti-icing, de-icing, ice sensing, etc. Here, an IPS is created using nanomaterials to create a surface-modified external layer on an aerosurface based on observations that polymer nanocomposites have tailorable and attractive heating properties. The IPS uses Joule heating of aligned carbon nanotube (CNT) arrays to create highly efficient de-icing and anti-icing of aerosurfaces. An ice wind tunnel test of a CNT enhanced aerosurface is performed to demonstrate the system under a range of operating regimes (temperature, wind speed, water content in air) including operation down to -20.6°C (-5°F) at 55.9 m/s (125 mph) under heavy icing. Manufacturing, design considerations, and further improvements to the materials and systems are discussed.United States. Dept. of the Navy. Small Business Innovation Research (Contract N68335-11-C-0424)National Science Foundation (U.S.). Materials Research Science and Engineering Centers (Program) (Grant DMR-0819762
Kinetic detection of osmium(VI) ester intermediates during the OsO4‐mediated aqueous dihydroxylation of chloroethylenes
The kinetics and mechanism of the cis dihydroxylation of cis‐1,2‐ dichloroethylene, trans‐1,2‐dichloroethylene, and trichloroethylene by osmium tetroxide was studied systematically in aqueous solution. The stoichiometry of the process was determined based on the principle of continuous variation of reactant ratios with spectrophotometric detection. The results always showed 1:1 stoichiometry, which is in agreement with dihydroxylation. All three reactions were found to proceed in two distinct steps. The first step occurred on a time scale of seconds and was associated with a minor change in absorbance and was identified as the formation of a 1:1 adduct between the two reagents, which is the osmium(VI) ester that plays a decisive role in catalytic applications. This species is formed in an equilibrium that is very much shifted toward the reactants, so the osmium(VI) complex is a short‐lived intermediate of the process, which is detected kinetically, but its concentration is never high enough for structural characterization. The second reaction is accompanied by major spectral changes; it involves the formation of the final products. Our results clearly show that it is possible to detect the intermediate of the process by careful kinetic studies. It is also possible that the same strategy might be successful in other OsO4‐dependent dihydroxylation processes
The influence of anesthetics, neurotransmitters and antibiotics on the relaxation processes in lipid membranes
In the proximity of melting transitions of artificial and biological
membranes fluctuations in enthalpy, area, volume and concentration are
enhanced. This results in domain formation, changes of the elastic constants,
changes in permeability and slowing down of relaxation processes. In this study
we used pressure perturbation calorimetry to investigate the relaxation time
scale after a jump into the melting transition regime of artificial lipid
membranes. This time corresponds to the characteristic rate of domain growth.
The studies were performed on single-component large unilamellar and
multilamellar vesicle systems with and without the addition of small molecules
such as general anesthetics, neurotransmitters and antibiotics. These drugs
interact with membranes and affect melting points and profiles. In all systems
we found that heat capacity and relaxation times are related to each other in a
simple manner. The maximum relaxation time depends on the cooperativity of the
heat capacity profile and decreases with a broadening of the transition. For
this reason the influence of a drug on the time scale of domain formation
processes can be understood on the basis of their influence on the heat
capacity profile. This allows estimations of the time scale of domain formation
processes in biological membranes.Comment: 12 pages, 6 figure
Impact Forecasting to Support Emergency Management of Natural Hazards
Forecasting and early warning systems are important investments to protect lives, properties, and livelihood. While early warning systems are frequently used to predict the magnitude, location, and timing of potentially damaging events, these systems rarely provide impact estimates, such as the expected amount and distribution of physical damage, human consequences, disruption of services, or financial loss. Complementing early warning systems with impact forecasts has a twofold advantage: It would provide decision makers with richer information to take informed decisions about emergency measures and focus the attention of different disciplines on a common target. This would allow capitalizing on synergies between different disciplines and boosting the development of multihazard early warning systems. This review discusses the state of the art in impact forecasting for a wide range of natural hazards. We outline the added value of impact-based warnings compared to hazard forecasting for the emergency phase, indicate challenges and pitfalls, and synthesize the review results across hazard types most relevant for Europe
Dynamics of fluctuations in a fluid below the onset of Rayleigh-B\'enard convection
We present experimental data and their theoretical interpretation for the
decay rates of temperature fluctuations in a thin layer of a fluid heated from
below and confined between parallel horizontal plates. The measurements were
made with the mean temperature of the layer corresponding to the critical
isochore of sulfur hexafluoride above but near the critical point where
fluctuations are exceptionally strong. They cover a wide range of temperature
gradients below the onset of Rayleigh-B\'enard convection, and span wave
numbers on both sides of the critical value for this onset. The decay rates
were determined from experimental shadowgraph images of the fluctuations at
several camera exposure times. We present a theoretical expression for an
exposure-time-dependent structure factor which is needed for the data analysis.
As the onset of convection is approached, the data reveal the critical
slowing-down associated with the bifurcation. Theoretical predictions for the
decay rates as a function of the wave number and temperature gradient are
presented and compared with the experimental data. Quantitative agreement is
obtained if allowance is made for some uncertainty in the small spacing between
the plates, and when an empirical estimate is employed for the influence of
symmetric deviations from the Oberbeck-Boussinesq approximation which are to be
expected in a fluid with its density at the mean temperature located on the
critical isochore.Comment: 13 pages, 10 figures, 52 reference
A Systematic Review of Music Therapy Practice and Outcomes with Acute Adult Psychiatric In-Patients
PMCID: PMC3732280This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited
Optical properties of MgH2 measured in situ in a novel gas cell for ellipsometry/spectrophotometry
The dielectric properties of alpha-MgH2 are investigated in the photon energy
range between 1 and 6.5 eV. For this purpose, a novel sample configuration and
experimental setup are developed that allow both optical transmission and
ellipsometric measurements of a transparent thin film in equilibrium with
hydrogen. We show that alpha-MgH2 is a transparent, colour neutral insulator
with a band gap of 5.6 +/- 0.1 eV. It has an intrinsic transparency of about
80% over the whole visible spectrum. The dielectric function found in this work
confirms very recent band structure calculations using the GW approximation by
Alford and Chou [J.A. Alford and M.Y. Chou (unpublished)]. As Pd is used as a
cap layer we report also the optical properties of PdHx thin films.Comment: REVTeX4, 15 pages, 12 figures, 5 table
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