Niemcza diorites and moznodiorites (Sudetes, SW Poland): a record of changing geotectonic setting at ca. 340 Ma

Granites sensu lato in the Sudetes intruded in several episodes during the Variscan orogeny recording different stages of crust and mantle evolution. Correlating precise ages with geochemistry of the Variscan granites provides information on the evolution of these sources within the Variscan orogen. The Variscan intrusive rocks from the Niemcza Zone (Bohemian Massif, Sudetes, SW Poland) include undeformed dioritic to syenitic rocks and magmatically foliated granodiorites. In this study we analysed low SiO2 (48–53 wt.%) monzodioritic rocks from Przedborowa and Koźmice. The monzodiorites contain late-magmatic zircons with ages of 341.8 ± 1.9 Ma for Przedborowa and 335.6 ± 2.3 Ma for Koźmice, interpreted as emplacement ages of the dioritic magmas. Older Przedborowa rocks are lower in K, Mg, Rb and Ni than the Koźmice rocks and similar compositional trend is also observed in the Central Bohemian Plutonic Complex. The implication is that the mantle underlying the Niemcza Zone became more enriched from ca. 342 to ca. 336 Ma, probably following the collision of the Saxothuringian and Moldanubian/Lugian domains. The magmatism related to the collision occurred ca. 12 Ma later than that in the Central Bohemian Plutonic Complex, but was accompanied by a similar change in magma chemistry from high-K (Przedborowa) to shoshonitic (Koźmice, Kośmin enclaves) and probably to ultrapotassic (Wilków Wielki)

Metal source and tectonic setting of iron oxide-copper-gold (IOCG) deposits:Evidence from an in situ Nd isotope study of titanite from Norrbotten, Sweden

AbstractTitanite occurs as a widespread accessory phase in mineralised zones and alteration associated with iron oxide-copper gold (IOCG) and iron oxide-apatite (IOA) deposits of Norrbotten County, Sweden, and is a major host of the REE in these deposits. In situ analyses of SmNd isotope ratios in titanites previously analysed for UPb geochronology and trace element composition confirms previous interpretations of grain scale isotopic heterogeneity. Initial Nd-isotope ratios expressed relative to CHUR range from ~−3 to −8 in IOA deposits, from ~−1 to −9 in IOCG deposits, and from +2 to −4 in the most Cu-rich, deformed IOCG deposits of the Nautanen Deformation zone. Within individual IOA deposits εNd varies relative to CHUR: from −3.1 to −4.0 at Valkommen (Malmberget), from −1.4 to −5.7 in grain cores, and −7.2 to −8.2 in grain rims rim at Gruvberget; and from −3.0 to −6.0 in grain cores and from −5.8 to −7.1 in grain rims at Luossavaara. In IOCG deposits at Rakkurijärvi εNd varies from −6.1. to −7.1, and in deformed IOCG deposits at Nautanen from −1.3 to −2.3. These values are consistent with the derivation of the REE, and potentially economically enriched metals, from the local volcanic sequence, either via granitic melts, or directly by leaching by metasomatic fluids. The most Cu-rich deposits reflect the involvement of more basic protoliths. The age distribution of these deposits suggest IOA deposit formation during the collisional phase of the Svecofennian orogeny (~1.9–1.8Ga), and IOCG mineralisation during this phase and during post-orogenic collapse (~1.8–1.7Ga), whilst model ages indicate the ultimate enrichment of the continental crust in these metals during pre-collisional extensional and subduction-related basic magmatism. These processes underscore the importance of continental cycles both in producing the preserved geological record of orogenic ore deposition, and in the generation of fertile continental crust, from which metals can be mobilised by subsequent events

Direct dating of mid-crustal shear zones with synkinematic allanite:new in situ U-Th-Pb geochronological approaches applied to the Mont Blanc massif

International audienceDating the timing of motion on crustal shear zones is of tremendous importance for understanding the assembly of orogenic terranes. This objective is achieved in this paper by combining petrological and structural observations with novel developments in in situ U-Th-Pb geochronology of allanite. A greenschist facies shear zone within the Mont Blanc Massif is documented. Allanite is synkinematic and belongs to the mylonitic assemblage. LA-ICP-MS U-Th-Pb isotope analyses of allanite reveal high contents and highly radiogenic isotopic compositions of the common-Pb component. The use of measured Pb-isotope compositions of associated minerals (feldspars and chlorite) is critical for accurate common-Pb correction, and provides a powerful mechanism for linking allanite growth to the metamorphic assemblage. A mean 208Pb/232Th age of 29.44 ± 0.95 Ma is accordingly taken for synkinematic allanite crystallisation under greenschist facies conditions. This age reflects the timing of the Mont Blanc underthrusting below the Penninic Front and highlights the potential of directly dating deformation with allanite

Using perovskite to determine the pre-shallow level contamination magma characteristics of kimberlite

It remains difficult to obtain reliable geochemical signatures of uncontaminated kimberlite magma from bulk rock studies due to the combined effects of crustal assimilation and element mobility during post-emplacement alteration processes. Groundmass perovskite (CaTiO3), a typical accessory phase, from Orapa (Botswana) and Wesselton (South Africa) kimberlites has been used to evaluate the isotope and trace element composition of the pre-contamination magmas and the effects of shallow level contamination. In-situ trace element signatures of Orapa and Wesselton perovskite grains are broadly similar and unaffected by crustal contamination. Single grain Sr-87/Sr-86 isotope ratios of perovskite from Orapa (0.7030-0.7036) are less scattered than bulk rock analyses (0.7063-0.7156), which are variably affected by contamination and late stage alteration. Initial Sr-87/Sr-86 isotope ratios of perovskite (0.7044-0.7049) from Wesselton overlap with published whole rock studies on fresh hypabyssal kimberlites (0.7042-0.7047). The limited intra-kimberlite variation in Sr isotope ratios recorded by the perovskite are unlikely to be due to crustal contamination as the calculated liquid compositions in equilibrium with the perovskite analysed typically have &gt;1500 ppmSr, and most common crustal lithologies underlying these kimberlites have relatively low Sr contents and are not highly radiogenic. Calculated pre-shallow level contamination magma compositions for Orapa and Wesselton have significantly fractionated LREE and highly variable non-smooth trace element patterns. Initial Sr and Nd isotope ratios of both kimberlites fall on the mantle Nd-Sr array with enriched Sr and slightly depleted Nd signatures, similar to Group I kimberlites. Overall, the trace element and isotopic composition of Orapa and Wesselton kimberlites are similar to the reported Group I kimberlites from southern Africa, which are derived by very low degrees of partial melting from a LREE depleted metasomatised sub-continental lithospheric mantle (SCLM) source. (C) 2013 Elsevier B.V. All rights reserved.</p

A change in the geodynamics of continental growth 3 billion years ago

Continental Growth Spurts The appearance and persistence of continents through geologic time has influenced most processes on Earth, from the evolution of new species to the climate. The relative proportion of newly formed crust compared to reworked, or destroyed, older crust reveals which processes controlled continental growth. Based on the combined analyses of Hf-Pb and O isotopes in zircon minerals, Dhuime et al. (p. 1334 ) measured continuous but variable rates of new crustal production throughout Earth's history. Increased rates of crustal destruction starting around 3 billion years ago coincide with the onset of subduction-drive plate tectonics, slowing down the overall rate of crustal growth. </jats:p