Polaronic signatures and spectral properties of graphene antidot lattices

We explore the consequences of electron-phonon (e-ph) coupling in graphene antidot lattices (graphene nanomeshes), i.e., triangular superlattices of circular holes (antidots) in a graphene sheet. They display a direct band gap whose magnitude can be controlled via the antidot size and density. The relevant coupling mechanism in these semiconducting counterparts of graphene is the modulation of the nearest-neighbor electronic hopping integrals due to lattice distortions (Peierls-type e-ph coupling). We compute the full momentum dependence of the e-ph vertex functions for a number of representative antidot lattices. Based on the latter, we discuss the origins of the previously found large conduction-band quasiparticle spectral weight due to e-ph coupling. In addition, we study the nonzero-momentum quasiparticle properties with the aid of the self-consistent Born approximation, yielding results that can be compared with future angle-resolved photoemission spectroscopy measurements. Our principal finding is a significant e-ph mass enhancement, an indication of polaronic behavior. This can be ascribed to the peculiar momentum dependence of the e-ph interaction in these narrow-band systems, which favors small phonon momentum scattering. We also discuss implications of our study for recently fabricated large-period graphene antidot lattices.Comment: published versio

Economic feasibility of second generation ethanol with and without indirect greenhouse gas reduction benefits : a simulation for Brazil

The aim of this study is to determine the economic feasibility of second generation ethanol from sugar cane, whereby traditional ethanol production is combined with the use of lignocellulosic biomass for ethanol production. By applying cost-benefit analysis, this study evaluated the viability of the second generation ethanol technology as an alternative to conventional sugarcaneto- ethanol, both in terms of processing technology, and of land use impacts. Furthermore, an attempt is made to analyze impacts on CO2 mitigation and land use in economic. The research results indicate that: i) from an economic point of view, the first generation plant is clearly preferable. With IRR of 18.7%, Minimum selling price of US$0.31 per liter, and NPV of US$ 213.0 million, first generation ethanol production from sugar cane has a large economic advantage compared to the second generation plant (IRR of 13.5%, Minimum selling price of US$0.40 per liter and NPV of US$ 78.5 million). ii) from an environmental point of view, a second generation biofuel that makes use of lignocellulosic biomass plant is clearly preferable. The second generation plant uses 49.6% less land and avoids a CO2 debt average of 942,282 ton per year throughout the life of the project. iii) Productivity gains improve profitability (IRR) and reduce biofuel prices (Minimum selling prices). Increasing the yearlt Ethanol and sugar cane productivity’s growth rate from 0.5% to 4.0% leads to a range of IRR from 17.5% to 21.5%, and of price from 0.29 US$/l to 0.32 US$/l for first generation plant, and from 13.2% to 14.2% and of price from 0.39 US$/l to 0.40 US$/l for second generation plant. iv) Process improvement shows little economic impact but matters on environmental side because less land is needed. Up to 10% more land can be saved compared to least advanced technology. v) Energy conversion development can improve income of the plant, especially for the first generation plant. Each 5% improvement can lead to 0.6% change in IRR project, and a reduction of 1.1% in the Minimum selling price. vi) Equipment investment is the most sensitive parameter to alter biofuel prices and profitability. The conventional plant is more sensitive to equipment investment, land prices and trash costs in this order while second generation plant is sensitive to equipment investment and almost insensitive to land prices and trash costs changes. vii) Assuming an average payment of US$29.43 or higher per ton CO2 debt, the second generation plant may become a competing alternative to conventional, first generation plant. On average, the technology could be paid at reasonable cost (Revenue average of US$ 27.7 million). viii) Productivity gains reduce the repayment time of CO2 debt, with ethanol productivity having a stronger contribution. Besides, from a growth rate of ethanol and sugar cane productivity from 0.5% to 4.0% per year, the repayment time changes from 11.8 years to a range between 6.5 years and 5.5 years and 13 and 9.5, respectively. In conclusion, the appraisal model represents a useful tool for analyzing many issues related with the dilemmas involved in biofuel production

The first 1000 cultured species of the human gastrointestinal microbiota

Peer reviewe

Multiple-Resampling Receiver Design for OFDM Over Doppler-Distorted Underwater Acoustic Channels

Cataloged from PDF version of article.In this paper, we focus on orthogonal frequency-divisionmultiplexing (OFDM) receiver designs for underwater acoustic (UWA) channels with user- and/or path-specific Doppler scaling distortions. The scenario is motivated by the cooperative communications framework, where distributed transmitter/receiver pairs may experience significantly different Doppler distortions, as well as by the single-user scenarios, where distinct Doppler scaling factors may exist among different propagation paths. The conventional approach of front–end resampling that corrects for common Doppler scalingmay not be appropriatein such scenarios, rendering a post-fast-Fourier-transform (FFT) signal that is contaminated by user- and/or path-specific intercarrier interference. To counteract this problem, we propose a family of front–end receiver structures thatutilizemultiple-resampling (MR)branches,eachmatched to the Doppler scaling factor of a particular user and/or path. Following resampling, FFT modules transform the Doppler-compensated signals into the frequency domain for further processing through linear or nonlinear detection schemes. As part of the overall receiver structure, a gradient–descent approachis also proposed to refine the channel estimates obtained by standard sparse channel estimators. The effectiveness and robustness of the proposed receivers are demonstrated via simulations, as well as emulations based on real data collected during the 2010 Mobile Acoustic Communications Experiment (MACE10, Martha’s Vineyard, MA) and the 2008 Kauai Acomms MURI (KAM08, Kauai, HI) experiment

An Infrastructure for acquiring high quality semantic metadata

Because metadata that underlies semantic web applications is gathered from distributed and heterogeneous data sources, it is important to ensure its quality (i.e., reduce duplicates, spelling errors, ambiguities). However, current infrastructures that acquire and integrate semantic data have only marginally addressed the issue of metadata quality. In this paper we present our metadata acquisition infrastructure, ASDI, which pays special attention to ensuring that high quality metadata is derived. Central to the architecture of ASDI is a erification engine that relies on several semantic web tools to check the quality of the derived data. We tested our prototype in the context of building a semantic web portal for our lab, KMi. An experimental evaluation omparing the automatically extracted data against manual annotations indicates that the verification engine enhances the quality of the extracted semantic metadata

Adaptive OFDM Modulation for Underwater Acoustic Communications: Design Considerations and Experimental Results

Cataloged from PDF version of article.In this paper, we explore design aspects of adaptive modulation based on orthogonal frequency-division multiplexing (OFDM) for underwater acoustic (UWA) communications, and study its performance using real-time at-sea experiments. Our design criterion is to maximize the system throughput under a target average bit error rate (BER). We consider two different schemes based on the level of adaptivity: in the first scheme, only the modulation levels are adjusted while the power is allocated uniformly across the subcarriers, whereas in the second scheme, both the modulation levels and the power are adjusted adaptively. For both schemes we linearly predict the channel one travel time ahead so as to improve the performance in the presence of a long propagation delay. The system design assumes a feedback link from the receiver that is exploited in two forms: one that conveys the modulation alphabet and quantized power levels to be used for each subcarrier, and the other that conveys a quantized estimate of the sparse channel impulse response. The second approach is shown to be advantageous, as it requires significantly fewer feedback bits for the same system throughput. The effectiveness of the proposed adaptive schemes is demonstrated using computer simulations, real channel measurements recorded in shallow water off the western coast of Kauai, HI, USA, in June 2008, and real-time at-sea experiments conducted at the same location in July 2011. We note that this is the first paper that presents adaptive modulation results for UWA links with real-time at-sea experiments. © 2013 IEEE