Photochemical Electrocyclic Ring Closure and Leaving Group Expulsion from N-(9-oxothioxanthenyl)Benzothiophene Carboxamides

N-(9-Oxothioxanthenyl)benzothiophene carboxamides bearing leaving groups (LG− = Cl−, PhS−, HS−, PhCH2S−) at the C-3 position of the benzothiophene ring system photochemically cyclize with nearly quantitative release of the leaving group, LG−. The LG− photoexpulsions can be conducted with 390 nm light or with a sunlamp. Solubility in 75% aqueous CH3CN is achieved by introducing a carboxylate group at the C-6 position of the benzothiophene ring. The carboxylate and methyl ester derivatives regiospecifically cyclize at the more hindered C-1 position of the thioxanthone ring. Otherwise, the photocyclization favors the C-3 position of the thioxanthone. Quantum yields for reaction are 0.01–0.04, depending on LG− basicity. Electronic structure calculations for the triplet excited state show that excitation transfer occurs from the thioxanthone to the benzothiophene ring. Subsequent cyclization in the triplet excited state is energetically favourable and initially generates the triplet excited state of the zwitterionic species. Expulsion of LG− is thought to occur once this species converts to the closed shell ground state

Planes of satellite galaxies and the cosmic web

Recent observational studies have demonstrated that the majority of satellite galaxies tend to orbit their hosts on highly flattened, vast, possibly co-rotating planes. Two nearly parallel planes of satellites have been confirmed around the M31 galaxy and around the Centaurus A galaxy, while the Milky Way also sports a plane of satellites. It has been argued that such an alignment of satellites on vast planes is unexpected in the standard ({\Lambda}CDM) model of cosmology if not even in contradiction to its generic predictions. Guided by {\Lambda}CDM numerical simulations, which suggest that satellites are channeled towards hosts along the axis of the slowest collapse as dictated by the ambient velocity shear tensor, we re-examine the planes of local satellites systems within the framework of the local shear tensor derived from the Cosmicflows-2 dataset. The analysis reveals that the Local Group and Centaurus A reside in a filament stretched by the Virgo cluster and compressed by the expansion of the Local Void. Four out of five thin planes of satellite galaxies are indeed closely aligned with the axis of compression induced by the Local Void. Being the less massive system, the moderate misalignment of the Milky Way's satellite plane can likely be ascribed to its greater susceptibility to tidal torques, as suggested by numerical simulations. The alignment of satellite systems in the local universe with the ambient shear field is thus in general agreement with predictions of the {\Lambda}CDM model.Comment: 9 pages, 3 figures, 3 tables. Accepted by MNRAS, 9 June 201

The influence of baryons on the mass distribution of dark matter halos

Using a set of high-resolution N-body/SPH cosmological simulations with identical initial conditions but run with different numerical setups, we investigate the influence of baryonic matter on the mass distribution of dark halos when radiative cooling is NOT included. We compare the concentration parameters of about 400 massive halos with virial mass from $10^{13}$ \Msun to $7.1 \times 10^{14}$ \Msun. We find that the concentration parameters for the total mass and dark matter distributions in non radiative simulations are on average larger by ~3% and 10% than those in a pure dark matter simulation. Our results indicate that the total mass density profile is little affected by a hot gas component in the simulations. After carefully excluding the effects of resolutions and spurious two-body heating between dark matter and gas particles, we conclude that the increase of the dark matter concentration parameters is due to interactions between baryons and dark matter. We demonstrate this with the aid of idealized simulations of two-body mergers. The results of individual halos simulated with different mass resolutions show that the gas profiles of densities, temperature and entropy are subjects of mass resolution of SPH particles. In particular, we find that in the inner parts of halos, as the SPH resolution increases the gas density becomes higher but both the entropy and temperature decrease.Comment: 8 pages, 6 figures, 1 table, ApJ in press (v652n1); updated to match with the being published versio

The alignment of galaxy spin with the shear field in observations

Tidal torque theory suggests that galaxies gain angular momentum in the linear stage of structure formation. Such a theory predicts alignments between the spin of haloes and tidal shear field. However, non-linear evolution and angular momentum acquisition may alter this prediction significantly. In this paper, we use a reconstruction of the cosmic shear field from observed peculiar velocities combined with spin axes extracted from galaxies within $115\, \mathrm{Mpc}$ ($\sim8000 \, {\mathrm {km}}{\mathrm s}^{-1}$) from 2MRS catalog, to test whether or not galaxies appear aligned with principal axes of shear field. Although linear reconstructions of the tidal field have looked at similar issues, this is the first such study to examine galaxy alignments with velocity-shear field. Ellipticals in the 2MRS sample, show a statistically significant alignment with two of the principal axes of the shear field. In general, elliptical galaxies have their short axis aligned with the axis of greatest compression and perpendicular to the axis of slowest compression. Spiral galaxies show no signal. Such an alignment is significantly strengthened when considering only those galaxies that are used in velocity field reconstruction. When examining such a subsample, a weak alignment with the axis of greatest compression emerges for spiral galaxies as well. This result indicates that although velocity field reconstructions still rely on fairly noisy and sparse data, the underlying alignment with shear field is strong enough to be visible even when small numbers of galaxies are considered - especially if those galaxies are used as constraints in the reconstruction.Comment: 9 pages, 3 figures, accepted in MNRA

Engineering chromium related single photon emitters in single crystal diamond

Color centers in diamond as single photon emitters, are leading candidates for future quantum devices due to their room temperature operation and photostability. The recently discovered chromium related centers are particularly attractive since they possess narrow bandwidth emission and a very short lifetime. In this paper we investigate the fabrication methodologies to engineer these centers in monolithic diamond. We show that the emitters can be successfully fabricated by ion implantation of chromium in conjunction with oxygen or sulfur. Furthermore, our results indicate that the background nitrogen concentration is an important parameter, which governs the probability of success to generate these centers.Comment: 14 pages, 5 figure

Galactic Archaeology with CoRoT and APOGEE: Creating mock observations from a chemodynamical model

In a companion paper, we have presented the combined asteroseismic-spectroscopic dataset obtained from CoRoT lightcurves and APOGEE infra-red spectra for 678 solar-like oscillating red giants in two fields of the Galactic disc (CoRoGEE). We have measured chemical abundance patterns, distances, and ages of these field stars which are spread over a large radial range of the Milky Way's disc. Here we show how to simulate this dataset using a chemodynamical Galaxy model. We also demonstrate how the observation procedure influences the accuracy of our estimated ages.Comment: 5 pages, 6 figures. To appear in Astronomische Nachrichten, special issue "Reconstruction the Milky Way's History: Spectroscopic surveys, Asteroseismology and Chemo-dynamical models", Guest Editors C. Chiappini, J. Montalb\'an, and M. Steffe