Comprehensive two-dimensional gas chromatography (GC x GC) measurements of volatile organic compounds in the atmosphere

Abstract. During the MINOS campaign in August 2001 comprehensive two-dimensional gas chromatography (GC×GC) was applied to the in situ measurements of atmospheric volatile organic compounds (VOCs) at the Finokalia ground station, Crete. The measurement system employs a thermal desorption unit for on-line sampling and injection, and a GC×GC separation system equipped with a flame ionization detector (FID) for detection. The system was optimized to resolve C7 − C14 organic components. Two-dimensional chromatograms from measurements of Finokalia air samples show several hundred wellseparated peaks. To facilitate peak identification, cartridge samples collected at Finokalia were analyzed using the same GC×GC system coupled with a time-of-flight mass spectrometer (TOF-MS). The resulting mass spectra were deconvoluted and compared to spectra from a database for tentative peak identification. About 650 peaks have been identified in the two-dimensional plane, with significant signal/noise ratios (>100) and high spectra similarities (>800). By comparing observed retention indices with those found in the literature, 235 of the identifications have been confirmed. 150 of the confirmed compounds show up in the C7 − C14 range of the chromatogram from the in situ measurement. However, at least as many peaks remain unidentified. For quantification of the GC×GC measurements, peak volumes of measured compounds have been integrated and externally calibrated using a standard gas mixture.

Cyclical behaviour and disc truncation in the Be/X-ray binary A0535+26

A0535+26 is shown to display quantised IR excess flux states, which are interpreted as the first observational verification of the resonant truncation scheme proposed by Okazaki and Negueruela (2001) for BeXRBs. The simultaneity of X-ray activity with transitions between these states strongly suggests a broad mechanism for outbursts, in which material lost from the disc during the reduction of truncation radius is accreted by the NS. Furthermore changes between states are shown to be governed by a 1500 day period, probably due to precession of the Be disc, which profoundly dictates the global behaviour of the system. Such a framework appears to be applicable to BeXRBs in general.Comment: 10 pages, 11 figs, submitted to MNRA

Critical study of the distribution of rotational velocities of Be stars; II: Differential rotation and some hidden effects interfering with the interpretation of the Vsin i parameter

We assume that stars may undergo surface differential rotation to study its impact on the interpretation of $V\!\sin i$ and on the observed distribution $\Phi(u)$ of ratios of true rotational velocities u=V/V_\rm c (V_\rm c is the equatorial critical velocity). We discuss some phenomena affecting the formation of spectral lines and their broadening, which can obliterate the information carried by $V\!\sin i$ concerning the actual stellar rotation. We studied the line broadening produced by several differential rotational laws, but adopted Maunder's expression $\Omega(\theta)=\Omega_o(1+\alpha\cos^2\theta)$ as an attempt to account for all of these laws with the lowest possible number of free parameters. We studied the effect of the differential rotation parameter $\alpha$ on the measured $V\!\sin i$ parameter and on the distribution $\Phi(u)$ of ratios u=V/V_\rm c. We conclude that the inferred $V\!\sin i$ is smaller than implied by the actual equatorial linear rotation velocity V_\rm eq if the stars rotate with $\alpha0$. For a given $|\alpha|$ the deviations of $V\!\sin i$ are larger when $\alpha<0$. If the studied Be stars have on average $\alpha<0$, the number of rotators with V_\rm eq\simeq0.9V_\rm c is larger than expected from the observed distribution $\Phi(u)$; if these stars have on average $\alpha>0$, this number is lower than expected. We discuss seven phenomena that contribute either to narrow or broaden spectral lines, which blur the information on the rotation carried by $V\!\sin i$ and, in particular, to decide whether the Be phenomenon mostly rely on the critical rotation. We show that two-dimensional radiation transfer calculations are needed in rapid rotators to diagnose the stellar rotation more reliably.Comment: To appear in A&

Constraining Disk Parameters of Be Stars using Narrowband H-alpha Interferometry with the NPOI

Interferometric observations of two well-known Be stars, gamma Cas and phi Per, were collected and analyzed to determine the spatial characteristics of their circumstellar regions. The observations were obtained using the Navy Prototype Optical Interferometer equipped with custom-made narrowband filters. The filters isolate the H-alpha emission line from the nearby continuum radiation, which results in an increased contrast between the interferometric signature due to the H-alpha-emitting circumstellar region and the central star. Because the narrowband filters do not significantly attenuate the continuum radiation at wavelengths 50 nm or more away from the line, the interferometric signal in the H-alpha channel is calibrated with respect to the continuum channels. The observations used in this study represent the highest spatial resolution measurements of the H-alpha-emitting regions of Be stars obtained to date. These observations allow us to demonstrate for the first time that the intensity distribution in the circumstellar region of a Be star cannot be represented by uniform disk or ring-like structures, whereas a Gaussian intensity distribution appears to be fully consistent with our observations.Comment: 23 pages, 14 figures, accepted for publication in A

Estimating Be Star Disk Radii using H-alpha Emission Equivalent Widths

We present numerical models of the circumstellar disks of Be stars, and we describe the resulting synthetic H-alpha emission lines and maps of the wavelength-integrated emission flux projected onto the sky. We demonstrate that there are monotonic relationships between the emission line equivalent width and the ratio of the angular half-width at half maximum of the projected disk major axis to the radius of the star. These relationships depend mainly upon the temperatures of the disk and star, the inclination of the disk normal to the line of sight, and the adopted outer boundary for the disk radius. We show that the predicted H-alpha disk radii are consistent with those observed directly through long baseline interferometry of nearby Be stars (especially once allowance is made for disk truncation in binaries and for dilution of the observed H-alpha equivalent width by continuum disk flux in the V-band).Comment: 12 pages, 2 figures, ApJL in pres

The fundamental parameters of the roAp star γ\gamma Equulei

Physical processes working in the stellar interiors as well as the evolution of stars depend on some fundamental stellar properties, such as mass, radius, luminosity, and chemical abundances. A classical way to test stellar interior models is to compare the predicted and observed location of a star on theoretical evolutionary tracks in a H-R diagram. This requires the best possible determinations of stellar mass, radius, luminosity and abundances. To derive its fundamental parameters, we observed the well-known rapidly oscillating Ap star, $\gamma$ Equ, using the visible spectro-interferometer VEGA installed on the optical CHARA array. We computed the calibrated squared visibility and derived the limb-darkened diameter. We used the whole energy flux distribution, the parallax and this angular diameter to determine the luminosity and the effective temperature of the star. We obtained a limb-darkened angular diameter of 0.564~$\pm$~0.017~mas and deduced a radius of $R$~=~2.20~$\pm$~0.12~${\rm R_{\odot}}$. Without considering the multiple nature of the system, we derived a bolometric flux of $(3.12\pm 0.21)\times 10^{-7}$ erg~cm$^{-2}$~s$^{-1}$ and an effective temperature of 7364~$\pm$~235~K, which is below the effective temperature that has been previously determined. Under the same conditions we found a luminosity of $L$~=~12.8~$\pm$~1.4~${\rm L_{\odot}}$. When the contribution of the closest companion to the bolometric flux is considered, we found that the effective temperature and luminosity of the primary star can be, respectively, up to $\sim$~100~K and up to $\sim$~0.8~L$_\odot$ smaller than the values mentioned above.These new values of the radius and effective temperature should bring further constraints on the asteroseismic modelling of the star.Comment: Accepted by A&

The Thermal Structure of the Circumstellar Disk Surrounding the Classical Be Star gamma Cassiopeia

We have computed radiative equilibrium models for the gas in the circumstellar envelope surrounding the hot, classical Be star $\gamma$Cassiopeia. This calculation is performed using a code that incorporates a number of improvements over previous treatments of the disk's thermal structure by \citet{mil98} and \citet{jon04}; most importantly, heating and cooling rates are computed with atomic models for H, He, CNO, Mg, Si, Ca, & Fe and their relevant ions. Thus, for the first time, the thermal structure of a Be disk is computed for a gas with a solar chemical composition as opposed to assuming a pure hydrogen envelope. We compare the predicted average disk temperature, the total energy loss in H$\alpha$, and the near-IR excess with observations and find that all can be accounted for by a disk that is in vertical hydrostatic equilibrium with a density in the equatorial plane of $\rho(R)\approx 3$ to $5\cdot 10^{-11} (R/R_*)^{-2.5} \rm g cm^{-3}$. We also discuss the changes in the disk's thermal structure that result from the additional heating and cooling processes available to a gas with a solar chemical composition over those available to a pure hydrogen plasma.Comment: 11 pages, 8 figures high resolution figures available at http://inverse.astro.uwo.ca/sig_jon07.htm

A study of the B and Be star population in the field of the LMC open cluster NGC2004 with VLT-FLAMES

Observations of hot stars belonging to the young cluster LMC-NGC2004 and its surrounding region have been obtained with the VLT-GIRAFFE facilities in MEDUSA mode. 25 Be stars were discovered; the proportion of Be stars compared to B-type stars is found to be of the same order in the LMC and in the Galaxy fields. 23 hot stars were discovered as spectroscopic binaries (SB1 and SB2), 5 of these are found to be eclipsing systems from the MACHO database, with periods of a few days. About 75% of the spectra in our sample are polluted by hydrogen (Halpha and Hgamma), [SII] and [NII] nebular lines. These lines are typical of HII regions. They could be associated with patchy nebulosities with a bi-modal distribution in radial velocity, with higher values (+335 kms^{-1}) preferentially seen inside the southern part of the known bubble LMC4 observed in HI at 21 cm.Comment: 12 pages, 17 figures, accepted to A&

Properties of the H-alpha-emitting Circumstellar Regions of Be Stars

Long-baseline interferometric observations obtained with the Navy Prototype Optical Interferometer of the H-alpha-emitting envelopes of the Be stars eta Tauri and beta Canis Minoris are presented. For compatibility with the previously published interferometric results in the literature of other Be stars, circularly symmetric and elliptical Gaussian models were fitted to the calibrated H-alpha observations. The models are sufficient in characterizing the angular distribution of the H-alpha-emitting circumstellar material associated with these Be stars. To study the correlations between the various model parameters and the stellar properties, the model parameters for eta Tau and beta CMi were combined with data for other Be stars from the literature. After accounting for the different distances to the sources and stellar continuum flux levels, it was possible to study the relationship between the net H-alpha emission and the physical extent of the H-alpha-emitting circumstellar region. A clear dependence of the net H-alpha emission on the linear size of the emitting region is demonstrated and these results are consistent with an optically thick line emission that is directly proportional to the effective area of the emitting disk. Within the small sample of stars considered in this analysis, no clear dependence on the spectral type or stellar rotation is found, although the results do suggest that hotter stars might have more extended H-alpha-emitting regions.Comment: 24 pages, 16 figures, accepted for publication in Ap