The budgetary responsibility

Diplomová práce se zabývá pojmem rozpočtové odpovědnosti, dosavadními návrhy zavedení úpravy tohoto pojmu do českého právního řádu a jeho výskytu v právu Evropské unie. Cílem práce je prostřednictvím zhodnocení pokusů zavést úpravu rozpočtových pravidel do českého právního řádu, se zvláštním zaměřením na průběh přijímání a obsah posledního návrhu, dospět k ideálnímu návrhu těchto pravidel v podobě de lege ferenda. První kapitola obsahuje popis důležitých pojmů a teoretický základ pro zbytek práce. Je postupováno od základních pojmů až k úžeji zaměřené problematice samotné zásadě dlouhodobé vyrovnanosti veřejných rozpočtů a rozpočtové odpovědnosti. Druhá kapitola je zaměřena na popis všech učiněných návrhů zavést tyto pravidla do našeho právního řádu. Zvýšená pozornost je věnována poslednímu pokusu, tedy návrhu ústavního zákona o rozpočtové odpovědnosti a doprovodných zákonů, který byl předložen v roce 2015. Třetí kapitola se věnuje úpravě rozpočtové odpovědnosti na evropské úrovni. Nejprve je popsána úprava ve Smlouvě o fungování Evropské unie. Poté se práce věnuje popisu pravidel a vývoji Paktu o Stabilitě a růstu a doprovobným právním předpisům. Zmíněna je také Smlouva o stabilitě, koordinaci a správě v hospodářské a měnové unii, ke které se Česká republika spolu s Velkou Británií nepřidala. Na...The thesis deals with the term of budgetary responsibility, past drafts trying to enact this term to the legal system of Czech Republic, and also deals with applicable legal rules contained in the European Union legal system. The aim of this thesis is to analyze every existing draft in the Czech legal system (with the special attention to the last legal draft), and trough this analysis reach to the ideal set of rules for the budgetary responsibility. The first chapter contains the description of the basic term and the theoretical basis for the rest of this thesis. Elementary terms are described first and trough that it comes to the main term of the principle of the long-term balance of public budgets and to the term of budgetary responsibility. The second chapter aims to describe every single legal draft made in Czech Republic during the past year. Main attention is provided to the last legal draft of the constitutional act of budgetary responsibility and to the related draft of the secondary legal adaptation, which was presented in the year 2015. The third chapter aids to the European Union legal adaptation of the budgetary responsibility. At first the thesis deals with the form of budgetary responsibility in the Treaty on European Union and the Treaty on the Functioning of the European Union....Department of Financial Law and FinancesKatedra finančního práva a finanční vědyPrávnická fakultaFaculty of La

Fischer indolisation of N-(α-ketoacyl)anthranilic acids into 2-(indol-2-carboxamido)benzoic acids and 2-indolyl-3,1-benzoxazin-4-ones and their NMR study

N-(α-ketoacyl)anthranilic acids reacted with phenylhydrazinium chloride in boiling acetic acid to afford 2-(indol-2-carboxamido)benzoic acids in good to excellent yields and 2-indolyl-3,1-benzoxazin-4-ones as by-products. The formation of the latter products could easily be suppressed by a hydrolytic workup. Alternatively, by increasing the reaction temperature and/or time, 2-indolyl-3,1-benzoxazin-4-ones can be obtained exclusively. Optimisations of the reaction conditions as well as the scope and the course of the transformations were investigated. The products were characterized by 1H, 13C and 15N NMR spectroscopy. The corresponding resonances were assigned on the basis of the standard 1D and gradient selected 2D NMR experiments (1H-1H gs-COSY, 1H-13C gs-HSQC, 1H-13C gs-HMBC) with 1H-15N gs-HMBC as a practical tool to determine 15N NMR chemical shifts at the natural abundance level of 15N isotope.TBU in Zlin [IGA/FT/2014/010]; Ministry of Education, Science and Sport, Republic of Slovenia; Slovenian Research Agency [P1-0230, 430-168/2013/114]; EN-FIST Centre of Excellence, Ljubljan

Copper(I)-Catalyzed [3+2] Cycloaddition of 3-Azidoquinoline-2,4(1H,3H)-diones with Terminal Alkynes

Peer reviewe

Synthesis of bis(1,2,3-triazole) functionalized quinoline-2,4-diones

Derivatives of 3-(1H-1,2,3-triazol-1-yl)quinoline-2,4(1H,3H)-dione unsubstituted on quinolone nitrogen atom, which are available by the previously described four step synthesis starting from aniline, were exploited as intermediates in obtaining the title compounds. The procedure involves the introduction of propargyl group onto the quinolone nitrogen atom of mentioned intermediates by the reaction of them with propargyl bromide in N,N-dimethylformamide (DMF) in presence of a potassium carbonate and the subsequent formation of a second triazole ring by copper catalyzed cyclisation reaction with azido compounds. The products were characterized by 1H, 13C and 15N NMR spectroscopy. The corresponding resonances were assigned on the basis of the standard 1D and gradient selected 2D NMR experiments (1H–1H gs-COSY, 1H–13C gs-HSQC, 1H–13C gs-HMBC) with 1H–15N gs-HMBC as a practical tool to determine 15N NMR chemical shifts at the natural abundance level of 15N isotope. © 2018 b the authors.Slovenian Research Agency [P1-0230, J1-8147, J1-9166]; [IGA/FT/2018/007

Reaction of tertiary 2-chloroketones with cyanide ions: Application to 3-chloroquinolinediones

3-Chloroquinoline-2,4-diones react with cyanide ions in dimethyl formamide to give 3-cyanoquinoline-2,4-diones in small yields due to the strong hindrance of the substituent at the C-3 atom. Good yields can be achieved if the substituent at this position is the methyl group. In the methanol solution, the reaction proceeds by an addition mechanism to form 2-oxo-1a,2,3,7b-tetrahydrooxireno[2,3-c]quinoline-7b-carbonitriles, from which 4-hydroxy-3-methoxy-2-oxo-1,2,3,4-tetrahydroquinoline-4-carbonitriles are subsequently formed by opening of the epoxide ring with methanol. Some minor products of these reactions have also been isolated. The 1 H, 13 C and 15 N NMR spectra of the prepared compounds were measured, and all resonances were assigned using appropriate two-dimensional spectra. © 2021 The Authors. Published by Wiley-VCH GmbH.Tomas Bata University in Zlin [IGA/FT/2020/007] Funding Source: MedlineUniverzita Tomáše Bati ve Zlíně: IGA/FT/2020/00

The budgetary responsibility

The thesis deals with the term of budgetary responsibility, past drafts trying to enact this term to the legal system of Czech Republic, and also deals with applicable legal rules contained in the European Union legal system. The aim of this thesis is to analyze every existing draft in the Czech legal system (with the special attention to the last legal draft), and trough this analysis reach to the ideal set of rules for the budgetary responsibility. The first chapter contains the description of the basic term and the theoretical basis for the rest of this thesis. Elementary terms are described first and trough that it comes to the main term of the principle of the long-term balance of public budgets and to the term of budgetary responsibility. The second chapter aims to describe every single legal draft made in Czech Republic during the past year. Main attention is provided to the last legal draft of the constitutional act of budgetary responsibility and to the related draft of the secondary legal adaptation, which was presented in the year 2015. The third chapter aids to the European Union legal adaptation of the budgetary responsibility. At first the thesis deals with the form of budgetary responsibility in the Treaty on European Union and the Treaty on the Functioning of the European Union...

Copper(I)-Catalyzed [ 3+ 2] Cycloaddition of 3-Azidoquinoline-2,4(1H,3H)-diones with Terminal Alkynes

3-Azidoquinoline-2,4(1H,3H)-diones 1, which are readily available from 4-hydroxyquinolin-2(1H)-ones 4 via 3-chloroquinoline-2,4(1H,3H)-diones 5, afford, in copper(I)-catalyzed [3 + 2] cycloaddition reaction with terminal acetylenes, 1,4-disubstituted 1,2,3-triazoles 3 in moderate to excellent yields. The structures of compounds 3 were confirmed by 1H and 13C-NMR spectroscopy, combustion analyses and mass spectrometry

1,3-Dipolar cycloadditions of 3-azidoquinoline-2,4(1H,3H)-diones

The reactions of 3-azidoquinoline-2,4(1H,3H)-diones with alkynes were investigated

Novel ring contraction of 3-hydroxy-2,4 (1H,3H) -quinolinediones in aqueous alkali. The first convenient route to 2-hydroxyindoxyls

Ring contraction of 3-hydroxy-2,4(1H,3H)-quinolinediones (1) in aqueous potassium hydroxide resulted in the formation of 2-hydroxyindoxyls and/or dioxindoles. The choice of N-substituent and the reaction conditions govern the chemoselectivity of the reaction. N-Phenyl-substituted derivatives 1 give 2-hydroxyindoxyls, while N-alkyl- and N-benzyl-substituted derivatives afford the corresponding dioxindols. On the basis of byproduct analysis, as well as independent experiments, the most plausible reaction mechanism is proposed

Reaction of malonates with camphoranile. Synthesis of 4-hydroxy-2-pyridones attached to the Bornane ring system

Reakce anilů kafru, N-((1R,4R)-1,7,7-trimethylbicyklo[2.2.1]heptan-2-yliden)benzenaminu a N-(1,7,7-trimethylbicyklo[2.2.1]heptan-2-yliden)benzenaminu, s magickými malonáty (bis(2,4,6-trichlorfenyl)-2-butyl- a bis(2,4,6-trichlorfenyl)-2-fenylmalonát) vede ke 4-hydroxy-2(1H)-pyridonům připojeným k bornanovému cyklickému systému (např. (5S,8R)-3-butyl-5,6,7,8-tetrahydro-4-hydroxy-8,9,9-trimethyl-1-fenyl-5,8-methanochinolin-2(1H)-on) s dobrými výtěžky. Méně uspokojivé výtěžky byly dosaženy s diethyl-2-fenylmalonátem. Reakce přebytku diethyl-malonátu s N-(1,7,7-trimethylbicyklo[2.2.1]heptan-2-yliden)benzenaminem poskytuje pyronoderivát 4-hydroxy-7,11,11-trimethyl-6-fenyl-7,8,9,10-tetrahydro-7,10-methano-2H-pyrano[3,2-c]chinolin-2,5(6H)-dion, který lze snadno odbourat přes jeho acetylderivát 3-acetyl-4-hydroxy-8,9,9-trimethyl-1-fenyl-5,6,7,8-tetrahydro-5,8-methanochinolin-2(1H)-on na základní sloučeninu se structurou 4-hydroxy-8,9,9-trimethyl-1-fenyl-5,6,7,8-tetrahydro-5,8-methanochinolin-2(1H)-on.The reaction of camphoranils N-((1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ylidene)benzenamine and N-(1,7,7-trimethylbicyclo[2.2.1]heptan-2-ylidene)benzenamine with magic malonates (bis(2,4,6-trichlorophenyl) 2-butyl- and 2-phenylmalonates) leads to 4-hydroxy-2(1H)-pyridones attached to bornane ring system (e.g. (5S,8R)-3-butyl-5,6,7,8-tetrahydro-4-hydroxy-8,9,9-trimethyl-1-phenyl-5,8-methanoquinolin-2(1H)-one) in good yields. Less satisfactory yields were obtained with the di-Et 2-phenylmalonate. The reaction of an excess of di-Et malonate with N-(1,7,7-trimethylbicyclo[2.2.1]heptan-2-ylidene)benzenamine yields the pyrono deriv. 4-hydroxy-7,11,11-trimethyl-6-phenyl-7,8,9,10-tetrahydro-7,10-methano-2H-pyrano[3,2-c]quinoline-2,5(6H)-dione, which can readily be degraded via the acetyl deriv. 3-acetyl-4-hydroxy-8,9,9-trimethyl-1-phenyl-5,6,7,8-tetrahydro-5,8-methanoquinolin-2(1H)-one to the basic structure 4-hydroxy-8,9,9-trimethyl-1-phenyl-5,6,7,8-tetrahydro-5,8-methanoquinolin-2(1H)-one