Molecular dynamic simulations of the elastic and inelastic surface scattering of nanoparticles

Molecular dynamics calculations have been undertaken to simulate the collision of a solid, rotating nanoparticle with a planar, two-dimensional surface at thermal velocities (linear and rotational) equivalent to 500 K. During the course of a collision, mechanisms have been introduced into the simulation process that allows for the dissipation of kinetic energy and for components of linear and angular velocity to couple. Although previous studies of particle–particle collisions have used a similar energy dissipation procedure, in these first calculations on particle–surface collisions, it is found that the mechanism actually facilitates the movement of particles across a surface. It is also shown that the direction of travel of particles on a surface is strongly influenced by their rotational motion

Experimental measurements of water molecule binding energies for the second and third solvation shells of [Ca(H₂O)n]2+ complexes

Further understanding of the biological role of the Ca2+ ion in an aqueous environment requires quantitative measurements of both the short and long range interactions experienced by the ion in an aqueous medium. Here we present experimental measurements of binding energies for water molecules occupying the second and, quite possibly, the third solvation shell surrounding a central Ca2+ ion in [Ca(H2O)n]2+ complexes. Results for these large, previously inaccessible, complexes have come from the application of finite heat bath theory to kinetic energy measurements following unimolecular decay. Even at n = 20 the results show water molecules to be more strongly bound to Ca2+ than would be expected just from the presence of an extended network of hydrogen bonds. For n > 10, there is very good agreement between the experimental binding energies and recently published DFT calculations. Comparisons are made with similar data recorded for [Ca(NH3)n]2+ and [Ca(CH3OH)n]2+ complexes

The effect of noise correlations on randomized benchmarking

Among the most popular and well studied quantum characterization, verification and validation techniques is randomized benchmarking (RB), an important statistical tool used to characterize the performance of physical logic operations useful in quantum information processing. In this work we provide a detailed mathematical treatment of the effect of temporal noise correlations on the outcomes of RB protocols. We provide a fully analytic framework capturing the accumulation of error in RB expressed in terms of a three-dimensional random walk in "Pauli space." Using this framework we derive the probability density function describing RB outcomes (averaged over noise) for both Markovian and correlated errors, which we show is generally described by a gamma distribution with shape and scale parameters depending on the correlation structure. Long temporal correlations impart large nonvanishing variance and skew in the distribution towards high-fidelity outcomes -- consistent with existing experimental data -- highlighting potential finite-sampling pitfalls and the divergence of the mean RB outcome from worst-case errors in the presence of noise correlations. We use the Filter-transfer function formalism to reveal the underlying reason for these differences in terms of effective coherent averaging of correlated errors in certain random sequences. We conclude by commenting on the impact of these calculations on the utility of single-metric approaches to quantum characterization, verification, and validation.Comment: Updated and expanded to include full derivation. Related papers available from http://www.physics.usyd.edu.au/~mbiercuk/Publications.htm

Non-absorbing high-efficiency counter for itinerant microwave photons

Detecting an itinerant microwave photon with high efficiency is an outstanding problem in microwave photonics and its applications. We present a scheme to detect an itinerant microwave photon in a transmission line via the nonlinearity provided by a transmon in a driven microwave resonator. With a single transmon we achieve 84% distinguishability between zero and one microwave photons and 90% distinguishability with two cascaded transmons by performing continuous measurements on the output field of the resonator. We also show how the measurement diminishes coherence in the photon number basis thereby illustrating a fundamental principle of quantum measurement: the higher the measurement efficiency, the faster is the decoherence

Mesoscopic one-way channels for quantum state transfer via the Quantum Hall Effect

We show that the one-way channel formalism of quantum optics has a physical realisation in electronic systems. In particular, we show that magnetic edge states form unidirectional quantum channels capable of coherently transporting electronic quantum information. Using the equivalence between one-way photonic channels and magnetic edge states, we adapt a proposal for quantum state transfer to mesoscopic systems using edge states as a quantum channel, and show that it is feasible with reasonable experimental parameters. We discuss how this protocol may be used to transfer information encoded in number, charge or spin states of quantum dots, so it may prove useful for transferring quantum information between parts of a solid-state quantum computer.Comment: 4 pages, 3 figure

Phonon number quantum jumps in an optomechanical system

We describe an optomechanical system in which the mean phonon number of a single mechanical mode conditionally displaces the amplitude of the optical field. Using homodyne detection of the output field we establish the conditions under which phonon number quantum jumps can be inferred from the measurement record: both the cavity damping rate and the measurement rate of the phonon number must be much greater than the thermalization rate of the mechanical mode. We present simulations of the conditional dynamics of the measured system using the stochastic master equation. In the good-measurement limit, the conditional evolution of the mean phonon number shows quantum jumps as phonons enter and exit the mechanical resonator via the bath.Comment: 13 pages, 4 figures. minor revisions since first versio

Experimental quantum verification in the presence of temporally correlated noise

Growth in the complexity and capabilities of quantum information hardware mandates access to practical techniques for performance verification that function under realistic laboratory conditions. Here we experimentally characterise the impact of common temporally correlated noise processes on both randomised benchmarking (RB) and gate-set tomography (GST). We study these using an analytic toolkit based on a formalism mapping noise to errors for arbitrary sequences of unitary operations. This analysis highlights the role of sequence structure in enhancing or suppressing the sensitivity of quantum verification protocols to either slowly or rapidly varying noise, which we treat in the limiting cases of quasi-DC miscalibration and white noise power spectra. We perform experiments with a single trapped $^{171}$Yb$^{+}$ ion as a qubit and inject engineered noise ($\propto \sigma^z$) to probe protocol performance. Experiments on RB validate predictions that the distribution of measured fidelities over sequences is described by a gamma distribution varying between approximately Gaussian for rapidly varying noise, and a broad, highly skewed distribution for the slowly varying case. Similarly we find a strong gate set dependence of GST in the presence of correlated errors, leading to significant deviations between estimated and calculated diamond distances in the presence of correlated $\sigma^z$ errors. Numerical simulations demonstrate that expansion of the gate set to include negative rotations can suppress these discrepancies and increase reported diamond distances by orders of magnitude for the same error processes. Similar effects do not occur for correlated $\sigma^x$ or $\sigma^y$ errors or rapidly varying noise processes, highlighting the critical interplay of selected gate set and the gauge optimisation process on the meaning of the reported diamond norm in correlated noise environments.Comment: Expanded and updated analysis of GST, including detailed examination of the role of gauge optimization in GST. Full GST data sets and supplementary information available on request from the authors. Related results available from http://www.physics.usyd.edu.au/~mbiercuk/Publications.htm