153 research outputs found
Focussing quantum states
Does the size of atoms present a lower limit to the size of electronic
structures that can be fabricated in solids? This limit can be overcome by
using devices that exploit quantum mechanical scattering of electron waves at
atoms arranged in focussing geometries on selected surfaces. Calculations
reveal that features smaller than a hydrogen atom can be obtained. These
structures are potentially useful for device applications and offer a route to
the fabrication of ultrafine and well defined tips for scanning tunneling
microscopy.Comment: 4 pages, 4 figure
In-situ synchrotron X-ray diffraction data for the dynamic reaction processes between titanium and air under laser irradiation
This article presents data related to the research article entitled âDiffusion of oxygen and nitrogen into titanium under laser irradiation in airâ [1]. When irradiated with varying laser parameters under ambient air, titanium surfaces are observed to exhibit differing colors. To better understand this phenomenon, the dynamic reaction steps between titanium and air under laser irradiation were investigated with in-situ synchrotron X-ray diffraction method. With a programmed laser profile, a set of diffraction patterns were collected by a 2D detector and then analyzed with the program FIT2D. Based on the data, the detailed high-temperature reactions between titanium and air during laser irradiation were clearly revealed. The presented raw in-situ synchrotron X-ray diffraction data can be reused for the further insights of laser surface modification of titanium in air, or for discovering the optimal laser conditions for industrial decoration or medical applications of titanium
Titanium and nitrogen interactions under laser additive manufacturing conditions
To understand how to make bulk titanium parts or coatings with desired levels of titanium nitrides, this paper investigates the dynamic interactions between titanium and nitrogen under representative laser-based additive manufacturing (AM) conditions. Under a set of gas environments containing different concentrations of nitrogen, the titanium and nitrogen reaction productsâformed under typical Selective Laser Melting (SLM) and Laser Engineered Net Shaping (LENS) AM scanning conditionsâare examined for compositions, phases, and microstructures. In-situ synchrotron X-ray diffraction (SXRD) test is performed to reveal the high temperature reaction steps between titanium and nitrogen
Direct extraction of the Eliashberg function for electron-phonon coupling: A case study of Be(1010)
We propose a systematic procedure to directly extract the Eliashberg function
for electron-phonon coupling from high-resolution angle-resolved photoemission
data. The procedure is successfully applied to the Be(1010) surface, providing
new insights to electron-phonon coupling at this surface. The method is shown
to be robust against imperfections in experimental data and suitable for wider
applications.Comment: 4 pages, 4 figures. More details concerning the procedure are
include
Formation of environmentally persistent free radicals (EPFRs) on ZnO at room temperature: Implications for the fundamental model of EPFR generation.
Environmentally persistent free radicals (EPFRs) have significant environmental and public health impacts. In this study, we demonstrate that EPFRs formed on ZnO nanoparticles provide two significant surprises. First, EPR spectroscopy shows that phenoxy radicals form readily on ZnO nanoparticles at room temperature, yielding EPR signals similar to those previously measured after 250°C exposures. Vibrational spectroscopy supports the conclusion that phenoxy-derived species chemisorb to ZnO nanoparticles under both exposure temperatures. Second, DFT calculations indicate that electrons are transferred from ZnO to the adsorbed organic (oxidizing the Zn), the opposite direction proposed by previous descriptions of EPFR formation on metal oxides
Lattice-stiffening transition in copolymer films of vinylidene fluoride (70%) with trifluoroethylene (30%)
We report the discovery of a compressibility phase transition at 160 K in crystalline copolymer films of vinylidene fluoride (70%) with trifluoroethylene (30%). This phase transition is distinct from the known bulk ferroelectric-paraelectric phase transition at 353 K and surface ferroelectric phase transition at 295 K. The new phase transition is characterized by an increase in the effective Debye temperature from 48 to 245 K along the ă010ă direction as the temperature falls below 160 K. This phase transition is evident in neutron scattering, x-ray diffraction, angle-resolved photoemission, and in the dipole active phonon modes in electron energy-loss spectroscopy. © 1999 The American Physical Society
Scanning tunneling microscopy and spectroscopy at low temperatures of the (110) surface of Te doped GaAs single crystals
We have performed voltage dependent imaging and spatially resolved
spectroscopy on the (110) surface of Te doped GaAs single crystals with a low
temperature scanning tunneling microscope (STM). A large fraction of the
observed defects are identified as Te dopant atoms which can be observed down
to the fifth subsurface layer. For negative sample voltages, the dopant atoms
are surrounded by Friedel charge density oscillations. Spatially resolved
spectroscopy above the dopant atoms and above defect free areas of the GaAs
(110) surface reveals the presence of conductance peaks inside the
semiconductor band gap. The appearance of the peaks can be linked to charges
residing on states which are localized within the tunnel junction area. We show
that these localized states can be present on the doped GaAs surface as well as
at the STM tip apex.Comment: 8 pages, 8 figures, accepted for publication in PR
Electronic properties and Fermi surface of Ag(111) films deposited onto H-passivated Si(111)-(1x1) surfaces
Silver films were deposited at room temperature onto H-passivated Si(111)
surfaces. Their electronic properties have been analyzed by angle-resolved
photoelectron spectroscopy. Submonolayer films were semiconducting and the
onset of metallization was found at a Ag coverage of 0.6 monolayers. Two
surface states were observed at -point in the metallic films,
with binding energies of 0.1 and 0.35 eV. By measurements of photoelectron
angular distribution at the Fermi level in these films, a cross-sectional cut
of the Fermi surface was obtained. The Fermi vector determined along different
symmetry directions and the photoelectron lifetime of states at the Fermi level
are quite close to those expected for Ag single crystal. In spite of this
concordance, the Fermi surface reflects a sixfold symmetry rather than the
threefold symmetry of Ag single crystal. This behavior was attributed to the
fact that these Ag films are composed by two domains rotated 60.Comment: 9 pages, 8 figures, submitted to Physical Review
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