2,374 research outputs found
Estimation of Derivates for Additive Separable Models
Additive regression models have a long history in nonparametric regression. It is well known that these models can be estimated at the one dimensional rate. Until recently, however, these models have been estimated by a backfitting procedure. Although the procedure converges quickly, its iterative nature makes analyzing its statistical properties difficult. Furthermore it is unclear how to estimate derivatives with this approach since it does not give a closed form for the estimator. Recently, an integration approach has been studied that allows for the derivation of a closed form for the estimator. This paper extends this approach to the simultaneous estimation of both the function and its derivatives by combining the integration procedure with a local polynomial approach. Finally the merits of this procedure with respect to the estimation of a production function subject to separability conditions are discussed. The procedure is applied to livestock production data from Wisconsin. It is shown that there is some evidence of increasing return to scale for larger farms
All-optical dc nanotesla magnetometry using silicon vacancy fine structure in isotopically purified silicon carbide
We uncover the fine structure of a silicon vacancy in isotopically purified
silicon carbide (4H-SiC) and find extra terms in the spin Hamiltonian,
originated from the trigonal pyramidal symmetry of this spin-3/2 color center.
These terms give rise to additional spin transitions, which are otherwise
forbidden, and lead to a level anticrossing in an external magnetic field. We
observe a sharp variation of the photoluminescence intensity in the vicinity of
this level anticrossing, which can be used for a purely all-optical sensing of
the magnetic field. We achieve dc magnetic field sensitivity of 87 nT
Hz within a volume of mm at room temperature
and demonstrate that this contactless method is robust at high temperatures up
to at least 500 K. As our approach does not require application of
radiofrequency fields, it is scalable to much larger volumes. For an optimized
light-trapping waveguide of 3 mm the projection noise limit is below 100
fT Hz.Comment: 12 pages, 6 figures; additional experimental data and an extended
theoretical analysis are added in the second versio
Changes in the Isotopic Signature of Atmospheric Nitrous Oxide and Its Global Average Source During the Last Three Millennia
Nitrous oxide (N2O) is a strong greenhouse gas whose mole fraction in the atmosphere has increased over the industrial period. We present a new set of isotope measurements of N2O in air extracted from ice cores covering the last 3,000 years. For the preindustrial (PI) atmosphere, we find an average N2O mole fraction of (267 ± 1) nmol/mol and average tropospheric N2O isotopic values of ÎŽ15Nav PI = (9.5 ± 0.1)â°, ÎŽ18OPI = (47.1 ± 0.2)â°, ÎŽ15Nα PI = (17.8 ± 0.4)â°, and ÎŽ15ÎÎČ PI = (1.2 ± 0.4)â°. From PI to modern times all isotope signatures decreased with a total change of ÎŽ15Nav = (â2.7 ± 0.2)â°, ÎŽ18O = (â2.5 ± 0.4)â°, ÎŽ15Nα = (â2.0 ± 0.7)â°, and ÎŽ15ÎÎČ (â3.5 ± 0.7)â°. Interestingly, the temporal evolution is not the same for ÎŽ15Nav and ÎŽ18O. ÎŽ18O trends are relatively larger during the early part, and ÎŽ15Nav trends are larger during the late part of the industrial period, implying a decoupling of sources over the industrial period. Using a mass balance model, we determined the isotopic composition of the total average N2O source. Assuming that the total present source is the sum of a constant natural source and an increasing anthropogenic source, this anthropogenic source has an isotopic signature of ÎŽ15Nav source,anthrop = (â15.0 ± 2.6)â°, ÎŽ18Osource,anthrop = (30.0 ± 2.6)â°, ÎŽ15Nα source,anthrop = (â4.5 ± 1.7)â°, and ÎŽ15NÎČ source,anthrop = (â24.0 ± 8.4)â°. The 15N site preference of the source has increased since PI times, which is indicative of a relative shift from denitrification to nitrification sources, consistent with agricultural emissions playing a major role in the N2O increase.SCOPUS: ar.jinfo:eu-repo/semantics/publishe
Spin fluctuations in the quasi-two dimensional Heisenberg ferromagnet GdI_2 studied by Electron Spin Resonance
The spin dynamics of GdI_2 have been investigated by ESR spectroscopy. The
temperature dependences of the resonance field and ESR intensity are well
described by the model for the spin susceptibility proposed by Eremin et al.
[Phys. Rev. B 64, 064425 (2001)]. The temperature dependence of the resonance
linewidth shows a maximum similar to the electrical resistance and is discussed
in terms of scattering processes between conduction electrons and localized
spins.Comment: to be published in PR
Enabling Technologies for Silicon Microstrip Tracking Detectors at the HL-LHC
While the tracking detectors of the ATLAS and CMS experiments have shown
excellent performance in Run 1 of LHC data taking, and are expected to continue
to do so during LHC operation at design luminosity, both experiments will have
to exchange their tracking systems when the LHC is upgraded to the
high-luminosity LHC (HL-LHC) around the year 2024. The new tracking systems
need to operate in an environment in which both the hit densities and the
radiation damage will be about an order of magnitude higher than today. In
addition, the new trackers need to contribute to the first level trigger in
order to maintain a high data-taking efficiency for the interesting processes.
Novel detector technologies have to be developed to meet these very challenging
goals. The German groups active in the upgrades of the ATLAS and CMS tracking
systems have formed a collaborative "Project on Enabling Technologies for
Silicon Microstrip Tracking Detectors at the HL-LHC" (PETTL), which was
supported by the Helmholtz Alliance "Physics at the Terascale" during the years
2013 and 2014. The aim of the project was to share experience and to work
together on key areas of mutual interest during the R&D phase of these
upgrades. The project concentrated on five areas, namely exchange of
experience, radiation hardness of silicon sensors, low mass system design,
automated precision assembly procedures, and irradiations. This report
summarizes the main achievements
Mapping the depleted area of silicon diodes using a micro-focused X-ray beam
For the Phase-II Upgrade of the ATLAS detector at CERN, the current ATLAS Inner Detector will be replaced with the ATLAS Inner Tracker (ITk). The ITk will be an all-silicon detector, consisting of a pixel tracker and a strip tracker. Sensors for the ITk strip tracker are required to have a low leakage current up to bias voltages of -500 V to maintain a low noise and power dissipation. In order to minimise sensor leakage currents, particularly in the high-radiation environment inside the ATLAS detector, sensors are foreseen to be operated at low temperatures and to be manufactured from wafers with a high bulk resistivity of several kΩ·cm. Simulations showed the electric field inside sensors with high bulk resistivity to extend towards the sensor edge, which could lead to increased surface currents for narrow dicing edges. In order to map the electric field inside biased silicon sensors with high bulk resistivity, three diodes from ATLAS silicon strip sensor prototype wafers were studied with a monochromatic, micro-focused X-ray beam at the Diamond Light Source (Didcot, U.K.). For all devices under investigation, the electric field inside the diode was mapped and its dependence on the applied bias voltage was studied.Individual authors1 were supported in part by the U.S. Department of Energy under Contract No. DE-AC02-05CH11231. The work at SCIPP4 was
supported by the Department of Energy, grant DE-SC0010107. This work5 issupported and financed in part by the Spanish Ministry of Science, Innovation
and Universities through the Particle Physics National Program, ref. FPA2015-65652-C4-4-R (MICINN/FEDER, UE), and co-financed with FEDER funds
Triplet Exciton Generation in Bulk-Heterojunction Solar Cells based on Endohedral Fullerenes
Organic bulk-heterojunctions (BHJ) and solar cells containing the trimetallic
nitride endohedral fullerene 1-[3-(2-ethyl)hexoxy
carbonyl]propyl-1-phenyl-Lu3N@C80 (Lu3N@C80-PCBEH) show an open circuit voltage
(VOC) 0.3 V higher than similar devices with [6,6]-phenyl-C[61]-butyric acid
methyl ester (PC61BM). To fully exploit the potential of this acceptor molecule
with respect to the power conversion efficiency (PCE) of solar cells, the short
circuit current (JSC) should be improved to become competitive with the state
of the art solar cells. Here, we address factors influencing the JSC in blends
containing the high voltage absorber Lu3N@C80-PCBEH in view of both
photogeneration but also transport and extraction of charge carriers. We apply
optical, charge carrier extraction, morphology, and spin-sensitive techniques.
In blends containing Lu3N@C80-PCBEH, we found 2 times weaker photoluminescence
quenching, remainders of interchain excitons, and, most remarkably, triplet
excitons formed on the polymer chain, which were absent in the reference
P3HT:PC61BM blends. We show that electron back transfer to the triplet state
along with the lower exciton dissociation yield due to intramolecular charge
transfer in Lu3N@C80-PCBEH are responsible for the reduced photocurrent
The effects of lower-body compression garments on walking performance and perceived exertion in adults with CVD risk factors
Objectives
Compression garments are used by athletes in attempts to enhance performance and recovery, although evidence to support their use is equivocal. Reducing the exertion experienced during exercise may encourage sedentary individuals to increase physical activity. The aim of this study was to assess the effect of compression garments on walking performance (self-paced and enforced pace) and rate of perceived exertion (RPE) in adults who presented with two or more CVD risk factors. Participants (n = 15, 10 female, 58.9 ± 11.5 years, BMI 27.5 ± 4.5 kg m2) were recruited.
Design
A repeated measures design.
Methods
Participants were randomised to Modified Bruce Protocol (enforced pace), or the 6 min walk test (self-paced), and completed the test wearing compression garments or normal exercise clothes (Control). Outcome measures included stage completed, gross efficiency (%) and RPE in Modified Bruce Protocol, and distance walked (m) and RPE in 6 min walk test.
Results
In the Modified Bruce Protcol participants had a higher RPE (15.5 ± 2.5 vs 14.3 ± 2.2) and a lower efficiency (19.1 ± 5.9 vs 21.1 ± 6.7) in the compression garment condition compared with control, p < 0.05. In the 6 min walk test participants walked 9% less in the compression garment condition (p < 0.05) but did not have a lower RPE.
Conclusions
Compared with previous studies reporting enhanced or no effects of compression garments on performance or RPE, this study shows adverse effects of such clothing in untrained individuals with CVD risk factors. The mechanisms underlying this negative effect require further exploration. Use of garments designed for the athletic individuals may not be suitable for the wider population
A systematic review of correlates of sedentary behaviour in adults aged 18â65 years: a socio-ecological approach
Background: Recent research shows that sedentary behaviour is associated with adverse cardio-metabolic consequences even among those considered sufficiently physically active. In order to successfully develop interventions to address this unhealthy behaviour, factors that influence sedentariness need to be identified and fully understood. The aim of this review is to identify individual, social, environmental, and policy-related determinants or correlates of sedentary behaviours among adults aged 18-65 years. Methods: PubMed, Embase, CINAHL, PsycINFO and Web of Science were searched for articles published between January 2000 and September 2015. The search strategy was based on four key elements and their synonyms: (a) sedentary behaviour (b) correlates (c) types of sedentary behaviours (d) types of correlates. Articles were included if information relating to sedentary behaviour in adults (18-65 years) was reported. Studies on samples selected by disease were excluded. The full protocol is available from PROSPERO (PROSPERO 2014:CRD42014009823). Results: 74 original studies were identified out of 4041: 71 observational, two qualitative and one experimental study. Sedentary behaviour was primarily measured as self-reported screen leisure time and total sitting time. In 15 studies, objectively measured total sedentary time was reported: accelerometry (nâ=â14) and heart rate (nâ=â1). Individual level factors such as age, physical activity levels, body mass index, socio-economic status and mood were all significantly correlated with sedentariness. A trend towards increased amounts of leisure screen time was identified in those married or cohabiting while having children resulted in less total sitting time. Several environmental correlates were identified including proximity of green space, neighbourhood walkability and safety and weather. Conclusions: Results provide further evidence relating to several already recognised individual level factors and preliminary evidence relating to social and environmental factors that should be further investigated. Most studies relied upon cross-sectional design limiting causal inference and the heterogeneity of the sedentary measures prevented direct comparison of findings. Future research necessitates longitudinal study designs, exploration of policy-related factors, further exploration of environmental factors, analysis of inter-relationships between identified factors and better classification of sedentary behaviour domains
- âŠ