33 research outputs found
Occurrence of Synthetic Phenolic Antioxidants and Major Metabolites in Municipal Sewage Sludge in China
Distribution and Preliminary Exposure Assessment of Bisphenol AF (BPAF) in Various Environmental Matrices around a Manufacturing Plant in China
Quantitative Inversion of Fixed Carbon Content in Coal Gangue by Thermal Infrared Spectral Data
Determination of nine benzotriazole UV stabilizers in environmental water samples by automated on-line solid phase extraction coupled with high-performance liquid chromatography-tandem mass spectrometry
A method using automated on-line solid phase extraction coupled with a high-performance liquid chromatography-tandem mass spectrometry system was developed for the determination of emerging benzotriazole UV stabilizers (BZTs) in different environmental water matrices including river water, sewage influent and effluent. Water sample was injected directly and the analytes were preconcentrated on a Polar Advantage II on-line SPE cartridge. After cleanup step the target BZTs were eluted in back flush mode and then separated on a liquid chromatography column. Experimental parameters such as sample loading flow rate, SPE cartridge, pH value and methanol ratio in the sample were optimized in detail. The method detection limits ranged from 0.21 to 2.17 ng/L. Recoveries of the target BZTs at 50 ng/L spiking level ranged from 76% to 114% and the inter-day RSDs ranged from 1% to 15%. The optimized method was successfully applied to analyze twelve water samples collected from different wastewater treatment plants and rivers, and five BZTs (UV-P, UV-329, UV-350, UV-234 and UV-328) were detected with concentrations up to 37.1 ng/L. The proposed method is simple, sensitive and suitable for simultaneous analysis and monitoring of BZTs in water samples.Sponsors:National Natural Science Foundation Grant(s): 21207140 20890110 20621703 National Basic Research Program of China Grant(s): 2009CB421605 </p
Occurrence of Synthetic Phenolic Antioxidants and Major Metabolites in Municipal Sewage Sludge in China
Synthetic
phenolic antioxidants (SPAs) are one group of widely
used additive chemicals, which have not yet had focused attention
except for a few compounds such as 2,6-di-<i>tert</i>-butyl-4-methylphenol
(BHT). In this study, the occurrence and composition profiles of 12
frequently used SPAs and three BHT metabolites were investigated in
fifty-six sludge samples collected from individual wastewater treatment
plants in China. Eleven SPAs were positively found in the sludge samples,
in which, to our knowledge, eight SPA compounds were identified for
the first time in the environment. BHT, 4-<i>tert</i>-octylphenol
(4-<i>t</i>OP), and 2,4,6-tri-<i>tert</i>-bultylphenol
(AO 246) were the most dominant SPAs in the sludge at mean concentrations
of 4.14 μg/g, 374 ng/g, and 98.1 ng/g d.w. (dry weight). Meanwhile,
three BHT metabolites, including 3,5-di-<i>tert</i>-butyl-4-hydroxybenzaldehyde
(BHT-CHO), 2,6-di-<i>tert</i>-butyl-1,4-benzoquinone (BHT-Q),
and 2,6-di-<i>tert</i>-butyl-4-hydroxy-4-methyl-2,5-cyclohexadienone
(BHT-quinol), were also found in most of the samples (>98.2%) with
mean concentrations of 141, 562, and 225 ng/g d.w., respectively.
The activated sludge system (anaerobic, anoxic, and oxic tanks) of
a wastewater treatment plant was further investigated for the removal
efficiencies of the SPAs. High removal efficiencies (80.1–89.2%)
were found for the six detected SPAs in the aqueous phase, while generation
of large proportions of the three BHT metabolites was also observed
Distribution and Preliminary Exposure Assessment of Bisphenol AF (BPAF) in Various Environmental Matrices around a Manufacturing Plant in China
Increasing attention has been paid to bisphenol A and
bisphenol
(BP) analogues due to high production volumes, wide usage and potential
adverse effects. Bisphenol AF (BPAF) is considered a new bisphenol
analogue which is used as raw material in plastic industry, but little
is known about its occurrence in the environment and the potential
associated risk. In this work, BPAF levels and environmental distribution
were reported in samples collected around a manufacturing plant and
a preliminary exposure risk assessment to local residents was conducted.
BPAF was detected in most of the samples, with levels in river ranging
between 4 ng/L, sediments (0.520–2.00
× 10<sup>3</sup> ng/g dry weight, dw), soils
Identification and Composition of Emerging Quaternary Ammonium Compounds in Municipal Sewage Sludge in China
Quaternary ammonium compounds (QACs)
have raised considerable attention
due to their wide commercial applications and recent discovery of
unknown persistent analogues in aqueous environment. In this work,
the occurrence and distribution of alkyltrimethylammonium (ATMAC),
benzylakyldimethylethylammonium (BAC) and dialkyldimethylammonium
(DADMAC) homologues were investigated in fifty-two municipal sewage
sludge samples. ATMAC C10–18, BAC C8–18 and paired DADMAC
C8:8-C18:18 as well as emerging homologues such as ATMAC-20, 22 and
mixed DADMAC-16:18 and 14:16 were present. Furthermore, paired DADMAC-20:20
and mixed DADMAC-14:18, 18:20 were identified for the first time by
nontarget qualitative strategies. A triple quadruple mass spectrometer
quantification method was also initially verified with the aid of
laboratory synthesized standards for the analysis of the mixed DADMACs
with no certificated commercial standards currently available. The
total concentrations of ATMACs, BACs and DADMACs were in the range
of 0.38–293, 0.09–191 and 0.64–344 μg/g
dry weight, respectively, and particularly, mixed DADMACs constituted
39 ± 7% of total DADMAC concentrations. The concentrations and
profiles of individual homologues further suggested different QAC
applications and fate in China. Significant correlations were also
found among the concentrations of various QAC homologues as well as
wastewater treatment plant (WWTP) characteristics (total organic carbon
contents and daily treatment volumes)
The electronic properties of hydrogenated Janus MoSSe monolayer: a first principles investigation
Data_Sheet_1_Phthalates and phthalate metabolites in urine from Tianjin and implications for platelet mitochondrial DNA methylation.docx
BackgroundPhthalates (PAEs) are important synthetic substances in plastics, attracting much attention due to their potential effects on the cardiovascular system.MethodsIn this study, urine and blood samples from 39 individuals were collected in Tianjin, China. Phthalates and phthalate metabolites (mPAEs) were analyzed using gas chromatography-mass spectrometry (GC-MS) and high-performance liquid chromatography-mass spectrometry (HPLC-MS), respectively. The polymerase chain reaction (PCR) products from bisulfite-treated mitochondrial DNA (mtDNA) samples were analyzed using pyrosequencing technology.ResultsThe detection frequencies for 9 PAEs varied from 2.56 to 92.31%, and those for 10 mPAEs varied from 30.77 to 100%. The estimated daily intakes (EDIs) and cumulative risk of PAEs were calculated based on the experimental statistics of urinary PAEs and mPAEs. For PAEs, the HIRfD (hazard index corresponding to reference doses) values of 10.26% of participants and the HITDI (hazard index corresponding to tolerable daily intake) values of 30.77% of participants were estimated to exceed 1, suggesting a relatively high exposure risk. The mtDNA methylation levels in the MT-ATP8 and MT-ND5 were observed to be lower than in the MT-ATP6. Mono-ethyl phthalate (MEP) and MT-ATP8 were positively correlated with triglyceride levels (p ConclusionThe effects of PAE exposure on cardiovascular diseases (CVDs) should be investigated further.</p