Luminescent coordination polymers based on Ca²⁺ and octahedral cluster anions [{M₆Clⁱ₈}Clᵃ₆}²⁻ (M = Mo, W) : synthesis and thermal stability studies

Luminescent coordination polymers (CPs) based of inexpensive stable precursors are attractive materials for applications. Here we report the synthesis and evaluation of the stability and photophysical characteristics of the first examples of phosphorescent CPs based on octahedral molybdenum and tungsten cluster anions. Specifically 1D CP trans-[{Ca(OPPh₃)₄}{{M₆Clⁱ₈}Clᵃ₆}]∞ (M = Mo, W) can be obtained either directly at increased temperature or via intermediate phases [cis-Ca(OPPh₃)₄(H₂O)₂][{M₆Clⁱ₈}Clᵃ₆]∙2CH₃CN that are stable at room-temperature, but convert to the titled CP at temperatures above 100 °C

Relationship of methane consumption with the respiration of soil and grass-moss layers in forest ecosystems of the southern taiga in Western Siberia

The consumption of methane by some soils in the southern taiga of Western Siberia was studied by the static chamber method in the summer of 2013. The median of the specific CH4 flux through the soil was −0.05 mg C/(m2 h) for the entire set of measurements (the negative flux indicates the consumption of methane by the soil). A statistically significant (R2 = 0.81) linear relationship has been found between the specific CH4 flux to the soil and the total respiration of the soil and the grass-moss layers in the studied forest ecosystems. The quantitative theoretical explanation of this relationship is based on the plant-associated and free methanotrophy

Octahedral chalcogenide rhenium cluster complexes with imidazole

Reactions of [{Re6Q8}Br6]4−/3− (Q = S, Se) with molten imidazole lead to the formation of two new neutral cluster complexes [{Re6Q8}(imzH)4(imz)2] (imzH = imidazole). The interaction of [{Re6Q8}(imzH)4(imz)2] with hydrohalic acids resulted in cationic complexes [{Re6Q8}(imzH)6]X2 (X = Cl, Br). All compounds were characterised by X-ray single-crystal and powder diffraction analyses, elemental analysis, energy dispersive X-ray and IR spectroscopies. The luminescence of the neutral compounds [{Re6Q8}(imzH)4(imz)2] was also studied

Synthetic receptors for transition metal cations - Tetrahydrazides on the basis of p-tert-butylthiacalix[4]arene

Stereoisomers of tetrahydrazide on the basis of p-tert-butylthiacalix[4] arene have been synthesised and characterised by IR spectroscopy, 1H and 13C NMR spectroscopy and mass spectrometry; the receptor properties of novel compounds towards metal cations, including most dangerous environmental pollutants, have been characterised by picrate extraction

New NIR-emissive tetranuclear Er(III) complexes with 4-hydroxo-2,1,3-benzothiadiazolate and dibenzoylmethanate ligands: synthesis and characterization

New tetranuclear heteroleptic complexes [Er4(dbm)6(O-btd)4(OH)2] (1) and [Er4(dbm)4(O-btd)6(OH)2] (2) (O-btd = 4-hydroxo-2,1,3-benzothiadiazolate and dbm = dibenzoylmethanide) and their solvates with toluene, THF and CH2Cl2 were prepared using two synthetic approaches. The structures of the products were confirmed by single-crystal X-ray diffraction. Magnetic properties of 1 and 2 are in good agreement with X-ray data. The effective magnetic moment (μeff) values at 300 K for 1 and 2 corresponds to a system of 4 non-interacting Er(III) ions in the ground state 4J15/2 with g = 6/5. At ambient temperature and upon excitation with λexc = 450 nm, complexes 1 and 2 exhibit luminescence at ∼1530 nm, i.e. in the near infra-red (NIR) region. The luminescence intensity grows with increasing the number of the (O-btd)−ligands in the complexes. This observation suggests (O-btd)− as a new efficient antenna ligand for the lanthanide-based NIR luminescence

Planning of Technological Development of New Products and Its Impact on the Economic Performance of the Enterprise

The market economy is characterized by competition of enterprises, defining the upgrade of production. Improvement of the economic activity of industrial enterprises implies development of new methods, forms and mechanisms of creation and mastering of new competitive products designed to ensure the predominant position of enterprises on domestic and foreign markets. Modern approaches to the creation and development of new competitive products high-tech require a huge amount of costs. But on the other hand it is the development of new products allows companies to survive in the current competitive environment. Planning for new products refers to the section of strategic planning. Therefore, the ability of the company to develop and introduce to the market its new product depends on its financial performance. A necessary step in production planning is the development of new products, representing a diverse set of processes and activities in the process which is carried out inspection and testing of structures and technologies to specified technical requirements, development of new forms of organization of production. During the development of new products are achieved the planned production volumes, scheduled economic indicators and technical and economic parameters of products. The period of development of new products begins with production of a prototype and ends with serial production. Keywords: innovation, innovation economy, economic indicators, new products, development of production JEL Classifications: O14, O21, O32, O3

A process-based model of methane consumption by upland soils

This study combines a literature survey and field observation data in an ad initio attempt to construct a process-based model of methane sink in upland soils including both the biological and physical aspects of the process. Comparison is drawn between the predicted sink rates and chamber measurements in several forest and grassland sites in the southern part of West Siberia. CH4 flux, total respiration, air and soil temperature, soil moisture, pH, organic content, bulk density and solid phase density were measured during a field campaign in summer 2014. Two datasets from literature were also used for model validation. The modeled sink rates were found to be in relatively good correspondence with the values obtained in the field. Introduction of the rhizospheric methanotrophy significantly improves the match between the model and the observations. The Q10 values of methane sink observed in the field were 1.2-1.4, which is in good agreement with the experimental results from the other studies. Based on modeling results, we also conclude that soil oxygen concentration is not a limiting factor for methane sink in upland forest and grassland ecosystems.Peer reviewe

Octahedral molybdenum cluster as a photoactive antimicrobial additive to a fluoroplastic

Finding methods that fight bacterial infection or contamination, while minimising our reliance on antibiotics is one of the most pressing needs of this century. Although the utilisation of UV-C light and strong oxidising agents, such as bleach, are still efficacious methods for eliminating bacterial surface contamination, both methods present severe health and/or environmental hazards. Materials with intrinsic photodynamic activity (i.e. a material's ability upon photoexcitation to convert molecular oxygen into reactive oxygen species such as singlet oxygen), which work with light within the visible photomagnetic spectrum could offer a significantly safer alternative. Here we present a new, bespoke molybdenum cluster (Bu4N)2[Mo6I8(n-C7F15COO)6], which is both efficient in the generation of singlet oxygen upon photoirradiation and compatible with the fluoropolymer (F23-L) known for its good oxygen permeability. Thus, (Bu4N)2[Mo6I8(n-C7F15COO)6]/F23-L mixtures have been solution-processed to give homogenous films of smooth and fibrous morphologies and which displayed high photoinduced antibacterial activity against four common pathogens under visible light irradiation. These materials thus have potential in applications ranging from antibacterial coatings to filtration membranes and air conditioners to prevent spread of bacterial infections

Аутологичные стимуляторы регенерации при имплантации аллогенных костнопластических материалов

There are many different surgical techniques for bone reconstruction. However, biological reconstruction methods are being increasingly developed. The main purpose is not only to fill up defects, but to stimulate the processes of reconstruction and regeneration of bone as a complete organ. In this report, we describe the basic principles of orthobiology and the essential orthobiological materials. A clinical case is presented where a combination of allogeneic osteoplastic materials with autologous platelet-rich plasma is used to reconstruct a  cavity defect in the tibia.В настоящее время существует множество разных методов хирургического восстановления костной ткани, но все большее развитие получают способы биологической реконструкции, основной целью которых является не только восполнение дефекта, но стимуляция  процессов регенерации и восстановления кости как органа. В данной публикации авторы описывают базовые принципы ортобиологии и основные ортобиологические материалы. Приведен клинический случай, где применена комбинация аллогенных костнопластических материалов с аутологичной обогащенной тромбоцитами плазмой для реконструкции полостного дефекта большеберцовой кости

Treatment of cryptorchidism in pediatric surgical practice: a multicenter study

Introduction. Cryptorchidism is a common disease in pediatric urological and andrological practice since the issues of tactical approaches and its optimal treatment remain extremely relevant. Cryptorchidism makes a significant contribution to the structure of male infertility.Objective. To conduct a retrospective analysis of treatment results in children and adolescents with cryptorchidism.Materials & methods. This study summarises the treatment results of 8308 patients with cryptorchidism aged from 6 months to 17 years who underwent inpatient treatment in the Russian Federation and the Republic of Uzbekistan.Results. It was revealed that from 2015 to 2019, patients were admitted for surgical treatment evenly over the years. The ratio of right-sided / left-sided / bilateral cryptorchidism was 4.6 : 4.4 : 1 The inguinal form prevailed more than 6 times over the abdominal location. At the same time, 26.1% of the patients underwent surgery at the optimal time, and 9.8% were older than 10 years. More often, children are operated from an open inguinal access (95.0%), much less often — laparoscopically and percutaneously. Stage-by-stage treatment was carried out in 6.0% of patients.Conclusion. Thus, the approach presented in the study in the surgical treatment of cryptorchidism provided good treatment results. The number of disease relapses was 1.9% (mainly among children over 7 years old). Most surgeons are very reserved about primary orchidectomies (only 3.8% were performed)