Compression properties of polymeric syntactic foam composites under cyclic loading

Syntactic foams are composite materials frequently used in applications requiring the properties of low density and high damage tolerance. In the present work, polymer-based syntactic foams were studied under cyclic compression in order to investigate their compressibility, recoverability, energy dissipation and damage tolerance. These syntactic foams were manufactured by adding hollow polymer microspheres of various sizes and wall thicknesses into a polyurethane matrix. The associated loading and unloading curves during cyclic testing were recorded, revealing the viscoelastic nature of the materials. SEM images of the samples were obtained in order to study potential damage mechanisms during compression. It was observed that these syntactic foams exhibit high elastic recovery and energy dissipation over a wide range of compressional strains and the addition of polymer microspheres mitigate the damage under compressional loading.Comment: 25 pages, 13 figure

Modification of the National Weather Service Distributed Hydrologic Model for subsurface water exchanges between grids

To account for spatial variability of precipitation, as well as basin physiographic properties, the National Weather Service (NWS) has developed a distributed version of its hydrologic component, termed the Hydrology Laboratory-Research Distributed Hydrologic Model (HL-RDHM). Because channels are the only source of water exchange between neighboring computational elements, the absence of such exchange has been identified as a weakness in the model. The primary objective of this paper is to modify the model structure to account for subsurface water exchanges without dramatically altering the conceptual framework of the water balance module. The subsurface exchanges are established by partitioning the slow response components released from the lower layer storages into two parts: the first part involves the grid's conceptual channel, while the second is added to the lower layer storages of the downstream pixel. Realizing the deficiency of the water balance module to locate the lower zone layers in sufficient depths, a complementary study is conducted to test the feasibility of further improvement in the modified model by equally shifting downward the lower zone layers of all pixels over the basin. The Baron Fork at Eldon, Oklahoma, is chosen as the test basin. Ten years of grid-based multisensor precipitation data are used to investigate the effects of the modification, plus shifting the lower zone layers on model performance. The results show that the modified-shifted HL-RDHM can markedly improve the streamflow simulations at the interior point, as well as very high peak-flow simulations at the basin's outlet. Copyright 2011 by the American Geophysical Union

Australopithecus afarensis endocasts suggest ape-like brain organization and prolonged brain growth

Human brains are three times larger, are organized differently, and mature for a longer period of time than those of our closest living relatives, the chimpanzees. Together, these characteristics are important for human cognition and social behavior, but their evolutionary origins remain unclear. To study brain growth and organization in the hominin species Australopithecus afarensis more than 3 million years ago, we scanned eight fossil crania using conventional and synchrotron computed tomography. We inferred key features of brain organization from endocranial imprints and explored the pattern of brain growth by combining new endocranial volume estimates with narrow age at death estimates for two infants. Contrary to previous claims, sulcal imprints reveal an ape-like brain organization and no features derived toward humans. A comparison of infant to adult endocranial volumes indicates protracted brain growth in A. afarensis, likely critical for the evolution of a long period of childhood learning in hominins

Effects of lattice mismatch on interfacial structures of liquid and solidified Al in contact with hetero-phase substrates: MD simulations

Published under licence in IOP Conference Series: Material Science and Engineering by IOP Publishing Ltd. Content from this work may be used under the terms of the Creative Commons Attribution 3.0 licence. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI.In this study, the effects of the misfit on in-plane structures of liquid Al and interfacial structure of solidified Al in contact with the heterophase substrates have been investigated, using molecular dynamics (MD) simulations. The MD simulations were conducted for Al/fcc (111) substrates with varied misfits. The order parameter and atomic arrangement indicated that the in-plane ordering of the liquid at the interface decreases significantly with an increase of the misfit, i.e., solid-like for small misfit and liquid-like for large misfit. Further, our MD simulation results revealed that a perfect orientation relationship forms at the interface between the substrate and the solidified Al for a misfit of less than -3% and the boundary is coherent. With an increase in the misfit, Shockley partial and extended dislocations form at the interface, and the boundary becomes a semi-coherent or low-angle twist boundary.EPSR

On the nonlocal viscosity kernel of mixtures

In this report we investigate the multiscale hydrodynamical response of a liquid as a function of mixture composition. This is done via a series of molecular dynamics simulations where the wave vector dependent viscosity kernel is computed for three mixtures each with 7-15 different compositions. We observe that the nonlocal viscosity kernel is dependent on composition for simple atomic mixtures for all the wave vectors studied here, however, for a model polymer melt mixture the kernel is independent of composition for large wave vectors. The deviation from ideal mixing is also studied. Here it is shown that a Lennard-Jones mixture follows the ideal mixing rule surprisingly well for a large range of wave vectors, whereas for both the Kob-Andersen mixture and the polymer melt large deviations are found. Furthermore, for the polymer melt the deviation is wave vector dependent such that there exists a critical length scale at which the ideal mixing goes from under-estimating to over-estimating the viscosity

<i>Schistosoma mansoni</i> cercariae experience influx of macromolecules during skin penetration

We have observed that when cercariae penetrate the skin of mice, there is influx into their tissues of Lucifer Yellow and certain labelled molecules of up to 20 kDa molecular weight. This observation was made using a variety of fluorescent membrane-impermeant compounds injected into the skin before the application of cercariae. This unexpected phenomenon was investigated further by transforming cercariae in vitro in the presence of the membrane-impermeant compounds and examining the distribution by microscopy. In schistosomula derived from this procedure, the nephridiopore and surface membrane were labelled while the pre- and post-acetabular glands were not labelled. The region associated with the oesophagus within the pharyngeal muscle clearly contained the fluorescent molecules, as did the region adjacent to the excretory tubules and the germinal mass. We used cercariae stained with carmine to aid identification of regions labelled with Lucifer Yellow. Although the mechanism of this influx is unclear, the observation is significant. From it, we can suggest an hypothesis that, during skin penetration, exposure of internal tissues of the parasite to external macromolecules represents a novel host-parasite interfac

A high resolution coupled hydrologic–hydraulic model (HiResFlood-UCI) for flash flood modeling

HiResFlood-UCI was developed by coupling the NWS's hydrologic model (HL-RDHM) with the hydraulic model (BreZo) for flash flood modeling at decameter resolutions. The coupled model uses HL-RDHM as a rainfall-runoff generator and replaces the routing scheme of HL-RDHM with the 2D hydraulic model (BreZo) in order to predict localized flood depths and velocities. A semi-automated technique of unstructured mesh generation was developed to cluster an adequate density of computational cells along river channels such that numerical errors are negligible compared with other sources of error, while ensuring that computational costs of the hydraulic model are kept to a bare minimum. HiResFlood-UCI was implemented for a watershed (ELDO2) in the DMIP2 experiment domain in Oklahoma. Using synthetic precipitation input, the model was tested for various components including HL-RDHM parameters (a priori versus calibrated), channel and floodplain Manning n values, DEM resolution (10 m versus 30 m) and computation mesh resolution (10 m+ versus 30 m+). Simulations with calibrated versus a priori parameters of HL-RDHM show that HiResFlood-UCI produces reasonable results with the a priori parameters from NWS. Sensitivities to hydraulic model resistance parameters, mesh resolution and DEM resolution are also identified, pointing to the importance of model calibration and validation for accurate prediction of localized flood intensities. HiResFlood-UCI performance was examined using 6 measured precipitation events as model input for model calibration and validation of the streamflow at the outlet. The Nash–Sutcliffe Efficiency (NSE) obtained ranges from 0.588 to 0.905. The model was also validated for the flooded map using USGS observed water level at an interior point. The predicted flood stage error is 0.82 m or less, based on a comparison to measured stage. Validation of stage and discharge predictions builds confidence in model predictions of flood extent and localized velocities, which are fundamental to reliable flash flood warning

Far-infrared optical properties of the pyrochlore spin ice compound Dy2Ti2O4

Near normal incident far-infrared reflectivity spectra of [111] dysprosium titanate (Dy2Ti2O4) single crystal have been measured at different temperatures. Seven phonon modes (eight at low temperature) are identified at frequency below 1000 cm-1. Optical conductivity spectra are obtained by fitting all the reflectivity spectra with the factorized form of the dielectric function. Both the Born effective charges and the static optical primitivity are found to increase with decreasing temperature. Moreover, phonon linewidth narrowering and phonon modes shift with decreasing temperature are also observed, which may result from enhanced charge localization. The redshift of several low frequency modes is attributed to the spin-phonon coupling. All observed optical properties can be explained within the framework of nearest neighbor ferromagnetic(FM) spin ice model