45 research outputs found

    Late Svecofennian shear zones in southwestern Finland

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    The bedrock of southwestern Finland is transected by a shear zone network with two dominant directions: ∼E-W and ∼N-S. The shear activity occurred after peak metamorphism and crustal melting at 1840-1810 Ma. The shear zones began to form as a consequence of north vergent oblique continent-continent collision and accommodated the resulting dextral transpression. The 150-200 km long ∼E-W oriented Somero and South Finland Shear Zones acted as dextral strike-slip faults, while the crustal unit between them was transported westward and deformed along the ∼N-S oriented reverse faults. The main deformation within these contractional shear zones took place at 1.81-1.79 Ga. After that, extensional faulting took place, tentatively at 1.79-1.77 Ga, 1.64-1.55 Ga and 1.26 Ga.</p

    Preservation of Palaeoproterozoic early Svecofennian structures in the Orijärvi area, SW Finland-Evidence for polyphase strain partitioning

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    The predominantly migmatitic Palaeoproterozoic Uusimaa belt preserves early lower-grade Svecofennian structures in the Orijärvi area in SW Finland. This study aims at explaining the deformational history responsible for its preservation and also at defining the age of the early Svecofennian deformation. Detailed structural analysis reveals that the preservation was enabled by polyphase strain partitioning, which initiated during the early Svecofennian D deformation, ∼1875 Ma ago, as revealed by ion microprobe U-Pb data on zircons from granodioritic and intermediate syn-D intrusive dykes. The D structures were low-strain upright folds at high crustal levels and sub-horizontal high-strain folds at deeper crustal levels. The sub-horizontal D structures were refolded into upright folds during the subsequent late Svecofennian D deformation, whereas the upright D structures behaved as almost rigid blocks that caused strain partitioning into high-strain zones along the block margins. This accounts for the low cumulative strain in specific parts of the Orijärvi area. Further strain partitioning during D caused reverse dip-slip movements along regional-scale shear zones. Crustal depth controlled the metamorphic grade during D , when local migmatisation took place at deep crustal levels. Later metamorphic overprint during D deformation is evident from post-D growth of sillimanite and a second generation of andalusite. Similarities in the structural patterns between the Orijärvi area and the Tampere-Vammala area (∼100 km to the north) suggest that irrespective of the age of the later overprint, subsequent deformation was localised along the margins of the early formed upright domains, while the low-grade rocks within the domains were preserved. © 2006 Elsevier B.V. All rights reserved.</p

    Isomer-Resolved Mobility-Mass Analysis of alpha-Pinene Ozonolysis Products

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    Highly oxygenated organic molecules (HOMs) are important sources of atmospheric aerosols. Resolving the molecular-level formation mechanisms of these HOMs from freshly emitted hydrocarbons improves the understanding of aerosol properties and their influence on the climate. In this study, we measure the electrical mobility and mass-to-charge ratio of alpha-pinene oxidation products using a secondary electrospray-differential mobility analyzer-mass spectrometer (SESI-DMA-MS). The mass-mobility spectrum of the oxidation products is measured with seven different reagent ions generated by the electrospray. We analyzed the mobility-mass spectra of the oxidation products C9-10H14-18O2-6. Our results show that acetate and chloride yield the highest charging efficiencies. Analysis of the mobility spectra suggests that the clusters have 1-5 isomeric structures (i.e., ion-molecule cluster structures with distinct mobilities), and the number is affected by the reagent ion. Most of the isomers are likely cluster isomers originating from binding of the reagent ion to different sites of the molecule. By comparing the number of observed isomers and measured mobilities and collision cross sections between standard pinanediol and pinonic acid to the values observed for C10H18O2 and C10H16O3 produced from oxidation of alpha-pinene, we confirm that pinanediol and pinonic acid are the only isomers for these elemental compositions in our experimental conditions. Our study shows that the SESI-DMA-MS produces new information from the first steps of oxidation of alpha-pinene.Peer reviewe

    LITHOSPHERE 2021: ELEVENTH SYMPOSIUM ON STRUCTURE, COMPOSITION AND EVOLUTION OF THE LITHOSPHERE: PROGRAMME AND EXTENDED ABSTRACTS

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    The bedrock of the Salo area in SW Finland is mainly occupied by granitoids. We dated five granitoids and two mafic volcanic rocks with single zircon method. The granitoids fall in two age groups, 1.86–1.85 and 1.83–1.82 Ga. Mafic plutonic rocks occur in both age groups. The volcanic rocks are 1.90 and 1.89 Ga in age. Further, the samples display two periods of metamorphic zircon growth at 1.86 and 1.83 Ga, synchronous with the granitoid magmatism.</p

    Total elbow arthroplasty in rheumatoid arthritis: A population-based study from the Finnish Arthroplasty Register

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    Background and purpose Although total elbow arthroplasty (TEA) is a recognized procedure for the treatment of the painful arthritic elbow, the choice of implant is still obscure. We evaluated the survival of different TEA designs and factors associated with survival using data from a nationwide arthroplasty register

    Troponin T-release associates with cardiac radiation doses during adjuvant left-sided breast cancer radiotherapy

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    Background Adjuvant radiotherapy (RT) for left-sided breast cancer increases cardiac morbidity and mortality. For the heart, no safe radiation threshold has been established. Troponin T is a sensitive marker of myocardial damage. Our aim was to evaluate the effect of left-sided breast cancer RT on serum high sensitivity troponin T (hscTnT) levels and its association with cardiac radiation doses and echocardiographic parameters. Methods A total of 58 patients with an early stage, left-sided breast cancer or ductal carcinoma in situ (DCIS) who received adjuvant breast RT without prior chemotherapy were included in this prospective, non-randomized study. Serum samples were taken before, during and after RT. An increase of hscTnT >30 % was predefined as significant. A comprehensive 2D echocardiograph and electrocardiogram (ECG) were performed before and after RT. Dose-volume histograms (DVHs) were generated for different cardiac structures. Results The hscTnT increased during RT from baseline in 12/58 patients (21 %). Patients with increased hscTnT values (group A, N = 12) had significantly higher radiation doses for the whole heart (p = 0.02) and left ventricle (p = 0.03) than patients without hscTnT increase (group B, N = 46). For the left anterior descending artery (LAD), differences between groups A and B were found in volumes receiving 15 Gy (p = 0.03) and 20 Gy (p = 0.03) Furthermore, after RT, the interventricular septum thickened (p = 0.01), and the deceleration time was prolonged (p = 0.008) more in group A than in group B. Conclusions The increase in hscTnT level during adjuvant RT was positively associated with the cardiac radiation doses for the whole heart and LV in chemotherapy-naive breast cancer patients. Whether these acute subclinical changes increase the risk of excessive long-term cardiovascular morbidity or mortality, will be addressed in the follow-up of our patients.BioMed Central open acces
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