2,328 research outputs found
A Formalism for Scattering of Complex Composite Structures. 2 Distributed Reference Points
Recently we developed a formalism for the scattering from linear and acyclic
branched structures build of mutually non-interacting sub-units.{[}C. Svaneborg
and J. S. Pedersen, J. Chem. Phys. 136, 104105 (2012){]} We assumed each
sub-unit has reference points associated with it. These are well defined
positions where sub-units can be linked together. In the present paper, we
generalize the formalism to the case where each reference point can represent a
distribution of potential link positions. We also present a generalized
diagrammatic representation of the formalism. Scattering expressions required
to model rods, polymers, loops, flat circular disks, rigid spheres and
cylinders are derived. and we use them to illustrate the formalism by deriving
the generic scattering expression for micelles and bottle brush structures and
show how the scattering is affected by different choices of potential link
positions.Comment: Paper no. 2 of a serie
Modelling of Mercury in the Arctic with the Danish Eulerian Hemispheric Model
International audienceA new 3-D mercury model has been developed within the Danish Arctic Monitoring and Assessment Programme (AMAP). The model is based on the Danish Eulerian Hemispheric Model, which in the original version has been used to study the transport of SO2, SO42- and Pb into the Arctic. It was developed for sulphur in 1990 and in 1999 also lead was included. For the current study a chemical scheme for mercury has been included and the model is now applied to the mercury transport problem. Some experiments with the formulation of the mercury chemistry during the Polar Sunrise are carried out in order to investigate the observed depletion. Some of the main conclusions of the work described in this paper are that atmospheric transport of mercury is a very important pathway into the Arctic and that mercury depletion in the Arctic troposphere during the Polar Sunrise contributes considerably to the deposition of mercury in the Arctic
Modelling of mercury with the Danish Eulerian Hemispheric Model
International audienceA new 3-D mercury model has been developed within the Danish Arctic Monitoring and Assessment Programme (AMAP). The model is based on the Danish Eulerian Hemispheric Model, which in the original version has been used to study the transport of SO2, SO42? and Pb into the Arctic. It was developed for sulphur in 1990 and in 1999 also lead was included. For the current study a chemical scheme for mercury has been included and the model is now applied to the mercury transport problem. Some experiments with the formulation of the mercury chemistry during the Polar Sunrise are carried out in order to investigate the observed depletion. Some of the main conclusions of the work described in this paper are that atmospheric transport of mercury is a very important pathway into the Arctic and that mercury depletion in the Arctic troposphere during the Polar Sunrise contributes considerably to the deposition of mercury in the Arctic
Notes on the birds of the tidal lowlands and floodplains of South Sumatra province, Indonesia
During an environmental baseline survey of the tidal lowlands and floodplains of South Sumatra Province in 1988-89, a total of 270 bird species was recorded. This paper focuses on wetland species, including those inhabiting swamp forests. No upland forest habitats are found within the region described. The area supports a diverse avifauna, including some globally threatened species that have a core population here, notably Milky Stork Mycteria cinerea, Storm's Stork Ciconia stormi, Lesser Adjutant Leptoptilos javanicus, Black-headed Ibis Threskiomis melanocephatus and Asian Dowitcher Limnodromus semipalmatus. The coast has vital passage and wintering grounds that rank second in importance only to coastal wetlands in Bangladesh for East Palaearctic waders in terms of numbers of birds. Three species were recorded for the first time in Sumatra: Spotted Eagle Aquila clanga, Steppe/Imperial Eagle Aquila nipalensis/heliaca and Spotted Redshank Tringa erythropa, and first Sumatran breeding records were obtained for Javan Pond-heron Ardeola speciosa and White-headed Stilt Himantopus leucocephalus. A few species were observed outside their previously recorded usual habitats. The paper discusses the principal habitats of the area, and the very rapid rate of development that has occurred during the past two decades. Only one wetland area in the province has protection status, Padang-Sugihan. This Wildlife Reserve does not provide habitat for eight out of the eleven globally threatened species recorded in the study area. Consequently the establishment of two additional swamp reserves and bird sanctuary is strongly recommended
A Formalism for Scattering of Complex Composite Structures. 1 Applications to Branched Structures of Asymmetric Sub-Units
We present a formalism for the scattering of an arbitrary linear or acyclic
branched structure build by joining mutually non-interacting arbitrary
functional sub-units. The formalism consists of three equations expressing the
structural scattering in terms of three equations expressing the sub-unit
scattering. The structural scattering expressions allows a composite structures
to be used as sub-units within the formalism itself. This allows the scattering
expressions for complex hierarchical structures to be derived with great ease.
The formalism is furthermore generic in the sense that the scattering due to
structural connectivity is completely decoupled from internal structure of the
sub-units. This allows sub-units to be replaced by more complex structures. We
illustrate the physical interpretation of the formalism diagrammatically. By
applying a self-consistency requirement we derive the pair distributions of an
ideal flexible polymer sub-unit. We illustrate the formalism by deriving
generic scattering expressions for branched structures such as stars, pom-poms,
bottle-brushes, and dendrimers build out of asymmetric two-functional
sub-units.Comment: Complete rewrite generalizing the formalism to arbitrary functional
sub-units and including a new Feynmann like diagrammatic interpretatio
Reappraisal is an effective emotion regulation strategy in children with Tourette syndrome and ADHD.
Difficulties in emotion regulation (ER) have been associated with several psychiatric disorders, emphasizing a need for a greater understanding of the concept and its associations with disruptive behavior. We aimed to study the ER strategy of cognitive reappraisal with an experimental test to increase our knowledge of emotional processes in child psychopathology.
In the present study, we examined emotional reactivity and cognitive reappraisal with a computer task in 160 medication-naïve children aged 8-12 comprising four groups: Fifty-eight children with Tourette syndrome (TS), 26 children with attention-deficit/hyperactivity disorder (ADHD), 19 children with TS and ADHD, and 57 typically developing controls.
The use of cognitive reappraisal reduced negative affect across all participants and the ability to reappraise was positively correlated with age, whereas reactivity was not. Overall, groups did not differ in reactivity or regulation success. Looking at specific differences within groups, however, only the ADHD group did not significantly decrease negative affect when reappraising. Finally, the use of strategies considered to be efficacious was correlated with regulation success, whereas the use of a less adaptive strategy related to suppression was associated with reactivity, but not regulation of emotions.
The study was limited by small, clinical contrast groups and a lack of blinding to diagnostic status in the coding of verbal strategies employed during the task.
Cognitive reappraisal appears to be a beneficial ER strategy for children regardless of diagnostic status. Our findings indicate that children can learn and employ an adaptive ER strategy when instructed in the technique, even in the presence of attention problems, which is highly relevant to therapeutic approaches to dysregulated behavior
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