Theoretical investigation into the possibility of very large moments in Fe16N2

We examine the mystery of the disputed high-magnetization \alpha"-Fe16N2 phase, employing the Heyd-Scuseria-Ernzerhof screened hybrid functional method, perturbative many-body corrections through the GW approximation, and onsite Coulomb correlations through the GGA+U method. We present a first-principles computation of the effective on-site Coulomb interaction (Hubbard U) between localized 3d electrons employing the constrained random-phase approximation (cRPA), finding only somewhat stronger on-site correlations than in bcc Fe. We find that the hybrid functional method, the GW approximation, and the GGA+U method (using parameters computed from cRPA) yield an average spin moment of 2.9, 2.6 - 2.7, and 2.7 \mu_B per Fe, respectively.Comment: 8 pages, 3 figure

Comparison of Th, Sr, Nd and Pb Isotopes in Oceanic basalts: implications for Mantle heterogeneity and Magma genesis. Earth

Abstract We report U-Th disequilibria data for a suite of 13 young basaltic samples from the Samoan Islands, which represent the endmember mantle component EM2, and 4 historic lavas from Mt. Erebus, typifying young HIMU. We interpret this observation in terms of differences in the melting regimes beneath mid-ocean ridges and ocean islands

Timescales of magmatic processes and eruption ages of the Nyiragongo volcanics from 238U-230Th-226Ra-210Pb disequilibria

Author Posting. © The Author(s), 2009. This is the author's version of the work. It is posted here by permission of Elsevier B.V. for personal use, not for redistribution. The definitive version was published in Earth and Planetary Science Letters 288 (2009): 149-1157, doi:10.1016/j.epsl.2009.09.017.The silica-undersaturated Nyiragongo volcanics, located in the East African rift, have globally unique chemical compositions and unusually low viscosities, only higher than carbonatite lavas, for terrestrial silicate magmas. We report 238U-230Th-226Ra-210Pb series disequilibria in 13 recent and prehistoric lava samples from Nyiragongo including those from the 2002 flank eruption and a 2003 lava lake sample. (230Th/238U) ranges from 0.90- 0.97 in the recent lavas and from 0.94-1.09 in the prehistoric lavas. To explain the variable 230Th and 238U excesses in these lavas, we hypothesize that different processes with opposite effects in terms of fractionating Th/U in the mantle source are involved. These processes include: 1) low degree partial melting of a phlogopite-bearing mantle source (consistent with low K/Rb) with residual garnet (consistent with high chondrite-normalized Dy/Yb), to produce the observed 230Th excesses; and, 2) carbonate metasomatism for the 238U enrichment, consistent with high Zr/Hf in the Nyiragongo lavas. The Nyiragongo volcanics have higher (230Th/232Th) values than observed in most mantle-derived rocks, especially ocean-island basalts, suggesting that their mantle-source was affected by carbonate metasomatism less than 300 ka ago. Several Nyiragongo samples display significant 226Ra excesses implying rapid magma transport (less than 8 ka) from the mantle-source to the surface. Modeling the observed (226Ra/230Th) versus Zr/Hf correlation in the lavas indicates that the 2002, 2003 and a few pre-historic lavas incorporated 50-60% of a carbonate-metasomatized mantle source while the other prehistoric lavas show 10-22% contribution of this source. This result indicates that the Nyiragongo lavas were derived from a heterogeneous, non-uniformly carbonated mantle source. The 2002 lava shows (210Pb/226Ra) equilibrium, whereas the 2003 lava lake sample shows initial (210Pb/226Ra) < 1. The latter observation suggests that Nyiragongo magmas degas as they rise to the surface over years or decades before eruption. (210Pb/226Ra) equilibrium in the 2002 lava suggests that the 2002 magma may have stagnated for more than a decade before eruption. The high CO2 content, high emission rates, extreme fluidity, along with the inferred short residence time and our inferences of rapid magma transport and high eruptive frequency suggest that the volcanic hazards of Nyiragongo, both from lava flows and gas emissions, are higher than previously estimated.Lava samples were collected as a part of a field work in Nyiragongo, supported by UN-OCHA grants. The field team included Paolo Papale, Alba Santo, Dario Tedesco and Orlando Vaselli with support from the staff of Goma Volcanological Observatory, D. R. Congo. The 2003 lava lake sample was collected by Jacques Durieux. Funding for U-series analyses was covered by NSF-EAR 063824101 and NSF-EAR 083887800 to KWWS. 210Po analyses were funded with EAR0738776 to MR. Sample preparation and dissolution was covered by NSF-EAR 0732679 to ARB. RC acknowledges guest student award from WHOI

Biological Transformation and Detoxification of 7,12-Dimethylbenzanthracene in Soil

Biological transformation and detoxification of 7,12-dimethylbenz(a)anathracene (DMBA) were studied in a nonacclimated sandy loam soil. Parent 14C DMBA biodegraded extensively (62% to 20%), accompanying an increase of metabolite 14C fraction (4% to 53%). Incorporation of DMBA into non extractable soil residue ,4C increased from 12 to 17%, but the increase was not statistically significant. DMBA was transformed into several metabolic products in the soil system, including 4-hydroxy-, 5-hydroxy-, and 10-hydroxy-DMBA and 7,12-dihydro 12-methyl-7-methylene-benz(a)anthracene-12-ol. High polarity transformation products of DMBA demonstrated a negative mu tagenic response with the Ames mutagenicity assay, strain TA 100, for both low and neutral pH soils. Moderate and low polar metabolites, however, induced mutagenicity for both soil samples. The mutagenicity of these metabolites decreased with incubation time in the soil, suggesting detoxification and assimilation of this polyaromatic hydrocarbon in soil systems. Mutagenic responses for the metabolites formed from low and neutral pH soil were similar. J. Water Pollut. Control Fed. 60, 1822 (1988)

Mental health and wellbeing of postgraduate researchers: exploring the relationship between mental health literacy, help-seeking behaviour, psychological distress, and wellbeing.

Studies of Postgraduate Researchers (PGRs) have highlighted that the population may be at risk of developing symptoms of common mental health problems. Early intervention and preventative measures may reduce this risk, such as improving mental health literacy (MHL). However, it is unclear what the relationship is between MHL and outcomes such as help-seeking behaviour, psychological distress and wellbeing, in PGRs. Therefore, the current study aimed to explore this relationship. A secondary aim of this study was to compare data collected from PGRs with undergraduate students. Two hundred and forty-one PGRs from two universities in England completed an anonymous online quantitative survey, with PGRs reporting on their MHL, help-seeking behaviour, psychological distress, and wellbeing, in addition to demographic and academic characteristics. Results indicated that 70% of PGRs were experiencing symptoms categorised as mild to severe psychological distress. Stepwise multiple regressions revealed that lower levels of wellbeing predicted higher levels of distress and lower levels of help-seeking behaviour. Compared with undergraduate students, PGRs in this study reported higher levels of psychological distress compared to undergraduate students, after adjusting for age, sex, and previous diagnosis of a mental health problem, as well as MHL, after adjusting for sex and previous diagnosis (p 0.05). Study findings suggest that PGRs, at the start of the academic year, are distressed and may not be seeking appropriate help for their concerns. Further studies should explore the environmental factors that may exacerbate mental health concerns beyond that associated with a challenging degree, within the PGR population

MAPIR: An Airborne Polarmetric Imaging Radiometer in Support of Hydrologic Satellite Observations

In this age of dwindling water resources and increasing demands, accurate estimation of water balance components at every scale is more critical to end users than ever before. Several near-term Earth science satellite missions are aimed at global hydrologic observations. The Marshall Airborne Polarimetric Imaging Radiometer (MAPIR) is a dual beam, dual angle polarimetric, scanning L band passive microwave radiometer system developed by the Observing Microwave Emissions for Geophysical Applications (OMEGA) team at MSFC to support algorithm development and validation efforts in support of these missions. MAPIR observes naturally-emitted radiation from the ground primarily for remote sensing of land surface brightness temperature from which we can retrieve soil moisture and possibly surface or water temperature and ocean salinity. MAPIR has achieved Technical Readiness Level 6 with flight heritage on two very different aircraft, the NASA P-3B, and a Piper Navajo

A translational research experience in Argentina.

Background: The Argentinean programwas initiatedmore than a decade ago as the first experience of systematic translational research focused on NCL in Latin America. The aim was to overcome misdiagnoses and underdiagnoses in the region. Subjects: 216 NCL suspected individuals from 8 different countries and their direct family members. Methods: Clinical assessment, enzyme testing, electron microscopy, and DNA screening. Results and discussion: 1) The study confirmed NCL disease in 122 subjects. Phenotypic studies comprised epileptic seizures and movement disorders, ophthalmology, neurophysiology, image analysis, rating scales, enzyme testing, and electron microscopy, carried out under a consensus algorithm; 2) DNA screening and validation of mutations in genes PPT1 (CLN1), TPP1 (CLN2), CLN3, CLN5, CLN6, MFSD8 (CLN7), and CLN8: characterization of variant types, novel/knownmutations and polymorphisms; 3) Progress of the epidemiological picture in Latin America; and 4) NCL-like pathology studies in progress. The Translational Research Program was highly efficient in addressing the misdiagnosis/underdiagnosis in the NCL disorders. The study of “orphan diseases” in a public administrated hospital should be adopted by the health systems, as it positively impacts upon the family's quality of life, the collection of epidemiological data, and triggers research advances. This article is part of a Special Issue entitled: “Current Research on the Neuronal Ceroid Lipofuscinoses (Batten Disease)”publishedVersio