Magnetic structure of Yb2Pt2Pb: Ising moments on the Shastry-Sutherland lattice.

Neutron diffraction measurements were carried out on single crystals and powders of Yb2Pt2Pb, where Yb moments form two interpenetrating planar sublattices of orthogonal dimers, a geometry known as Shastry-Sutherland lattice, and are stacked along the c axis in a ladder geometry. Yb2Pt2Pb orders antiferromagnetically at TN=2.07K, and the magnetic structure determined from these measurements features the interleaving of two orthogonal sublattices into a 5×5×1 magnetic supercell that is based on stripes with moments perpendicular to the dimer bonds, which are along (110) and (−110). Magnetic fields applied along (110) or (−110) suppress the antiferromagnetic peaks from an individual sublattice, but leave the orthogonal sublattice unaffected, evidence for the Ising character of the Yb moments in Yb2Pt2Pb that is supported by point charge calculations. Specific heat, magnetic susceptibility, and electrical resistivity measurements concur with neutron elastic scattering results that the longitudinal critical fluctuations are gapped with ΔE≃0.07meV

Human Physiological Responses to Cycle Ergometer Leg Exercise During +Gz Acceleration

Spaceflight and bed-rest deconditioning decrease maximal oxygen uptake (aerobic power), strength, endurance capacity, and orthostatic tolerance. In addition to extensive use of muscular exercise conditioning as a countermeasure for the reduction in aerobic power (VO(sub 2max)), stimuli from some form of +Gz acceleration conditioning may be necessary to attenuate the orthostatic intolerance component of this deconditioning. Hypothesis: There will be no significant difference in the physiological responses (oxygen uptake, heart rate, ventilation, or respiratory exchange ratio) during supine exercise with moderate +Gz acceleration

A New Model for the Spiral Structure of the Galaxy. Superposition of 2+4-armed patterns

We investigate the possibility of describing the spiral pattern of the Milky Way in terms of a model of superposition 2- and 4-armed wave harmonics (the simplest description, besides pure modes). Two complementary methods are used: a study of stellar kinematics, and direct tracing of positions of spiral arms. In the first method, the parameters of the galactic rotation curve and the free parameters of the spiral density waves were obtained from Cepheid kinematics, under different assumptions. To turn visible the structure corresponding to these models, we computed the evolution of an ensemble of N-particles, simulating the ISM clouds, in the perturbed galactic gravitational field. In the second method, we present a new analysis of the longitude-velocity (l-v) diagram of the sample of galactic HII regions, converting positions of spiral arms in the galactic plane into locii of these arms in the l-v diagram. Both methods indicate that the ``self-sustained'' model, in which the 2-armed and 4-armed mode have different pitch angles (6 arcdeg and 12 arcdeg, respectively) is a good description of the disk structure. An important conclusion is that the Sun happens to be practically at the corotation circle. As an additional result of our study, we propose an independent test for localization of the corotation circle in a spiral galaxy: a gap in the radial distribution of interstellar gas has to be observed in the corotation region.Comment: 17 pages, 9 figures, Latex, uses aas2pp4.st

Free Energy Simulations of a GTPase: GTP and GDP Binding to Archaeal Initiation Factor 2

International audienceArchaeal initiation factor 2 (aIF2) is a protein involved in the initiation of protein biosynthesis. In its GTP-bound, "ON" conformation, aIF2 binds an initiator tRNA and carries it to the ribosome. In its GDP-bound, "OFF" conformation, it dissociates from tRNA. To understand the specific binding of GTP and GDP and its dependence on the ON or OFF conformational state of aIF2, molecular dynamics free energy simulations (MDFE) are a tool of choice. However, the validity of the computed free energies depends on the simulation model, including the force field and the boundary conditions, and on the extent of conformational sampling in the simulations. aIF2 and other GTPases present specific difficulties; in particular, the nucleotide ligand coordinates a divalent Mg(2+) ion, which can polarize the electronic distribution of its environment. Thus, a force field with an explicit treatment of electronic polarizability could be necessary, rather than a simpler, fixed charge force field. Here, we begin by comparing a fixed charge force field to quantum chemical calculations and experiment for Mg(2+):phosphate binding in solution, with the force field giving large errors. Next, we consider GTP and GDP bound to aIF2 and we compare two fixed charge force fields to the recent, polarizable, AMOEBA force field, extended here in a simple, approximate manner to include GTP. We focus on a quantity that approximates the free energy to change GTP into GDP. Despite the errors seen for Mg(2+):phosphate binding in solution, we observe a substantial cancellation of errors when we compare the free energy change in the protein to that in solution, or when we compare the protein ON and OFF states. Finally, we have used the fixed charge force field to perform MDFE simulations and alchemically transform GTP into GDP in the protein and in solution. With a total of about 200 ns of molecular dynamics, we obtain good convergence and a reasonable statistical uncertainty, comparable to the force field uncertainty, and somewhat lower than the predicted GTP/GDP binding free energy differences. The sign and magnitudes of the differences can thus be interpreted at a semiquantitative level, and are found to be consistent with the experimental binding preferences of ON- and OFF-aIF2

Relationship between C-telopeptide pyridinoline cross-links (ICTP) and putative periodontal pathogens in periodontitis

Crevicular fluid pyridinoline cross-linked carboxyterminal telopeptide of type 1 collagen (ICTP) is predictive for future alveolar bone loss in experimental periodontitis in dogs. The present study sought to relate ICTP to a panel of subgingival species in subjects exhibiting various clinical presentations such as health ( n = 7), gingivitis ( n = 8) and periodontitis (n=21), 28 subgingival plaque and GCF samples were taken from mesiobuccal sites m each of 36 subjects. The presence and levels of 40 subgtngivai taxa were determined in plaque samples using whole genomic DNA probes and checkerboard DNA-DNA hybridization. GCF ICTP levels were quantified using radioimmunoassay (RIA). Clinical assessments made at the same sites included: BOP, gingival redness, plaque, pocket depth, and attachment level. Differences among ICTP levels in the 3 subject groups were sought using the Kruskal-Wallis test. Relationships between ICTP levels and clinical parameters as well as subgingival species were determined by regression analysis. The results demonstrated significant differences among disease categories for GCF ICTP levels for healthy (1.1+0.6 pg/site (mean±SEM)) gingivitis (14.8±6.6 pg/site) and penodontitts subjects (30.3 + 5.7 pg/site) ( p = 0.0017). ICTP levels related modestly to several clinical parameters. Regression analysis indicated that ICTP levels correlated strongly with mean subject levels of several periodontal pathogens including B. forsythus, P. gingivitis, P. intermedia, P. nigrescens and T. dentcola ( p < 0.01). The data indicate that there is a positive relationship between the putative bone resorptive marker ICTP and periodontal pathogens.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/74809/1/j.1600-051X.1998.tb02383.x.pd

Significance of Soil Lightness Versus Physicochemical Soil Properties in Semiarid Areas

This is an author's accepted manuscript of an article published in " Arid Land Research and Management"; Volume 28, Issue 4, 2014; copyright Taylor & Francis; available online at: http://www.tandfonline.com/doi/abs/10.1080/15324982.2014.882871Modern agriculture aims to encompass all soil attributes to optimize soil use and minimize environmental impacts. One of those attributes is soil color, which allows determining important soil variables for crop management and soil conservation. In this study, the relationships between lightness and several pedologic, topographic, and soil management variables were determined. One hundred and ten topsoil points were sampled in an area where the Mediterranean climate is the only homogeneous soil forming factor. Soil samples were air dried, crushed, and sieved, and lightness measurements were made using a trichromatic colorimeter. The relationships between lightness and soil-related parameters were carried out by means of bivariate linear correlation, and Mann-Witney and Kruskal-Wallis tests. Soil textural fractions (sand and silt), electrical conductivity and carbonates were statistically significant (p<0.001) and exhibited moderate correlation coefficients (0.32 0.45). Topographic variables (slope and aspect), soil organic carbon, iron, nitrogen, pH, and parent material (marls) exhibited lower effect on lightness. The response of lightness to clay content was highly conditioned by iron content. Stoniness, phosphorous, elevation, and soil management variables (irrigation and land use) were not statistically significant. The results obtained with calcareous samples from semiarid areas showed that soil lightness behavior agree with findings in developed soils, despite of the large differences in soil composition and the heterogeneity of the study area.Moreno-Ramón, H.; Marqués-Mateu, Á.; Ibañez Asensio, S. (2014). Significance of Soil Lightness Versus Physicochemical Soil Properties in Semiarid Areas. Arid Land Research and Management. 28(4):371-382. doi:10.1080/15324982.2014.882871S371382284Al-Mahawili , S. M. H. , M. F. Baumgardner , R. A. Weismiller , and W. N. Melhorn . 1983 . Satellite image interpretation and laboratory spectral reflectance measurements of saline and gypsiferous soils of West Baghdad, Iraq.LARS Technical Reports. Paper 104.Barrett, L. R. (2002). Spectrophotometric color measurement in situ in well drained sandy soils. Geoderma, 108(1-2), 49-77. doi:10.1016/s0016-7061(02)00121-0Bogrekci, I., & Lee, W. S. (2005). Spectral Phosphorus Mapping using Diffuse Reflectance of Soils and Grass. Biosystems Engineering, 91(3), 305-312. doi:10.1016/j.biosystemseng.2005.04.015Buol, S. W., Southard, R. J., Graham, R. C., & McDaniel, P. A. (2011). Soil Genesis and Classification. doi:10.1002/9780470960622Christensen, L. K., Bennedsen, B. S., Jørgensen, R. N., & Nielsen, H. (2004). Modelling Nitrogen and Phosphorus Content at Early Growth Stages in Spring Barley using Hyperspectral Line Scanning. Biosystems Engineering, 88(1), 19-24. doi:10.1016/j.biosystemseng.2004.02.006Doi, R., Wachrinrat, C., Teejuntuk, S., Sakurai, K., & Sahunalu, P. (2009). Semiquantitative color profiling of soils over a land degradation gradient in Sakaerat, Thailand. Environmental Monitoring and Assessment, 170(1-4), 301-309. doi:10.1007/s10661-009-1233-xDuiker, S. W., Rhoton, F. E., Torrent, J., Smeck, N. E., & Lal, R. (2003). Iron (Hydr)Oxide Crystallinity Effects on Soil Aggregation. Soil Science Society of America Journal, 67(2), 606. doi:10.2136/sssaj2003.0606Ehsani, M. R., Upadhyaya, S. K., Slaughter, D., Shafii, S., & Pelletier, M. (1999). Precision Agriculture, 1(2), 219-236. doi:10.1023/a:1009916108990Gunal, H., Ersahin, S., Yetgin, B., & Kutlu, T. (2008). Use of Chromameter‐Measured Color Parameters in Estimating Color‐Related Soil Variables. Communications in Soil Science and Plant Analysis, 39(5-6), 726-740. doi:10.1080/00103620701879422Ibarra-F., F. A., Martin-R., M. H., Cox, J. R., Crowl, T. A., Post, D. F., Miller, R. W., & Rasmussen, G. A. (1995). Relationship between Buffelgrass Survival, Organic Carbon, and Soil Color in Mexico. Soil Science Society of America Journal, 59(4), 1120. doi:10.2136/sssaj1995.03615995005900040025xKonen, M. E., Burras, C. L., & Sandor, J. A. (2003). Organic Carbon, Texture, and Quantitative Color Measurement Relationships for Cultivated Soils in North Central Iowa. Soil Science Society of America Journal, 67(6), 1823. doi:10.2136/sssaj2003.1823Mouazen, A. M., Maleki, M. R., De Baerdemaeker, J., & Ramon, H. (2007). On-line measurement of some selected soil properties using a VIS–NIR sensor. Soil and Tillage Research, 93(1), 13-27. doi:10.1016/j.still.2006.03.009Pan, G., Xu, X., Smith, P., Pan, W., & Lal, R. (2010). An increase in topsoil SOC stock of China’s croplands between 1985 and 2006 revealed by soil monitoring. Agriculture, Ecosystems & Environment, 136(1-2), 133-138. doi:10.1016/j.agee.2009.12.011Sánchez-Marañón, M., Martín-García, J. M., & Delgado, R. (2011). Effects of the fabric on the relationship between aggregate stability and color in a Regosol–Umbrisol soilscape. Geoderma, 162(1-2), 86-95. doi:10.1016/j.geoderma.2011.01.008Sánchez-Marañón, M., Ortega, R., Miralles, I., & Soriano, M. (2007). Estimating the mass wetness of Spanish arid soils from lightness measurements. Geoderma, 141(3-4), 397-406. doi:10.1016/j.geoderma.2007.07.005Sánchez-Marañón, M., Delgado, G., Melgosa, M., Hita, E., & Delgado, R. (1997). CIELAB COLOR PARAMETERS AND THEIR RELATIONSHIP TO SOIL CHARACTERISTICS IN MEDITERRANEAN RED SOILS. Soil Science, 162(11), 833-842. doi:10.1097/00010694-199711000-00007Singleton, P. (1991). 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From antiferromagnetic insulator to correlated metal in pressurized and doped LaMnPO

Widespread adoption of superconducting technologies requires the discovery of new materials with enhanced properties, especially higher superconducting transition temperatures T$_{c}$. The unexpected discovery of high T$_{c}$ superconductivity in cuprates and in materials as diverse as heavy fermions, organic conductors, and endohedrally-doped fullerenes suggests that the highest T$_{c}$s occur when pressure or doping transform the localized and moment-bearing electrons in antiferromagnetic insulators into itinerant and weakly magnetic metals. The absence of this delocalization transition in Fe-based superconductors may limit their T$_{c}$s, but even larger T$_{c}$s may be possible in their isostructural Mn analogs, which are antiferromagnetic insulators like the cuprates. It is generally believed that prohibitively large pressures would be required to suppress the strong Hund's rule coupling in these Mn-based compounds, collapsing the insulating gap and enabling superconductivity. Indeed, no Mn-based compounds are known to be superconductors. The electronic structure calculations and x-ray diffraction measurements presented here challenge these long held beliefs, finding that only modest pressures are required to transform LaMnPO, isostructural to superconducting host LaFeAsO, from an insulating tetragonal structure with a large Mn moment to a gapless orthorhombic structure with a small Mn moment. Proximity to this electronic delocalization transition in LaMnPO results in a highly interacting metallic state, the familiar breeding ground of superconductivity.Comment: 5 pages, 5 figure