Strengthening measurements from the edges: application-level packet loss rate estimation

Network users know much less than ISPs, Internet exchanges and content providers about what happens inside the network. Consequently users cannot either easily detect network neutrality violations or readily exercise their market power by knowledgeably switching ISPs. This paper contributes to the ongoing efforts to empower users by proposing two models to estimate -- via application-level measurements -- a key network indicator, i.e., the packet loss rate (PLR) experienced by FTP-like TCP downloads. Controlled, testbed, and large-scale experiments show that the Inverse Mathis model is simpler and more consistent across the whole PLR range, but less accurate than the more advanced Likely Rexmit model for landline connections and moderate PL

The Rio Games Legacy in Mobility: Challenges Beyond Infrastructure

The City of Rio de Janeiro, Brazil, a city of 6.5 million inhabitants, had several years to plan, invest, and prepare for the 2016 Olympic and Paralympic Games. A significant part of these efforts were in mobility infrastructure and operations, as they would become a fundamental legacy for the city. Silva, Maiolino and Torres, who were involved in these efforts in various capacities, discuss this experience and some of the challenges that go beyond investments in infrastructure such as behavior and operational changes

2-(Phenyl­carbonothio­ylsulfan­yl)acetic acid

The title compound, C9H8O2S2, can be used as a chain transfer agent and may be used to control the behavior of polymerization reactions. O—H⋯O hydrogen bonds of moderate character link the mol­ecules into dimers. In the crystal, the dimers are linked into sheets by C—H⋯O inter­actions, forming R 4 2(12) and R 2 2(8) edge-fused rings running parallel to [101]. There are no inter­molecular inter­actions involving the S atoms

Sustainable Horticulture: A bibliometric Study

This paper examines the scientific researches regarding "sustainable horticulture" to identify research flows with potential for future investigation. Through a bibliometric and content analysis for the 2011-2015 periods and the 2016 first semester, 12 articles, according and relevant to the theme, were selected. The results obtained from the analysis demonstrated the importance of the subject for both academic research and for the practice, since it elucidated scientific production and trends, impact factor, relevant scientific periodicals, contribution by countries and its institutions, methods and research tools, keywords. It stands out that the theme "sustainable horticulture" is used in most cases to address only the environmental dimension and, in a few cases, in the economic and social dimensions. Based in the analysis of the keywords, the terms production, systems and sustainability formed the main research clusters, attracting great attention during the study period

3-(2,4-Dibromo­anilino)-2,2-dimethyl-2,3-dihydro­naphtho[1,2-b]furan-4,5-dione: a new substituted aryl­amino nor-β-lapachone derivative

The title compound, C20H15Br2NO3, shows the furan ring to adopt a half-chair conformation and the two ring systems to be approximately perpendicular [dihedral angle = 71.0 (2)°]. In the crystal structure, inter­molecular C—H⋯O contacts link the mol­ecules

Modelling the Inorganic Bromine Partitioning in the Tropical Tropopause over the Pacific Ocean

The stratospheric inorganic bromine burden (Bry) arising from the degradation of brominated very short-lived organic substances (VSL org ), and its partitioning between reactive and reservoir species, is needed for a comprehensive assessment of the ozone depletion potential of brominated trace gases. Here we present modelled inorganic bromine abundances over the Pacific tropical tropopause based on aircraft observations of VSL org of two campaigns of the Airborne Tropical TRopopause EXperiment (ATTREX 2013 carried out over eastern Pacific and ATTREX 2014 carried out over the western Pacific) and chemistry-climate simulations (along ATTREX flight tracks) using the specific meteorology prevailing. Using the Community Atmosphere Model with Chemistry (CAM-Chem), we model that BrO and Br are the daytime dominant species. Integrated across all ATTREX flights BrO represents ~ 43 % and 48 % of daytime Bry abundance at 17 km over the Western and Eastern Pacific, respectively. The results also show zones where Br/BrO >1 depending on the solar zenith angle (SZA), ozone concentration and temperature. On the other hand, BrCl and BrONO 2 were found to be the dominant night-time species with ~ 61% and 56 % of abundance at 17 km over the Western and Eastern Pacific, respectively. The western-to-eastern differences in the partitioning of inorganic bromine are explained by different abundances of ozone (O3), nitrogen dioxide (NO2) , and total inorganic chlorine (Cly).Fil: Navarro, María A.. University of Miami; Estados UnidosFil: Saiz-lopez, Alfonso. Consejo Superior de Investigaciones Científicas. Instituto de Química Física; EspañaFil: Cuevas, Carlos Alberto. Consejo Superior de Investigaciones Científicas. Instituto de Química Física; EspañaFil: Fernandez, Rafael Pedro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza; Argentina. Universidad Nacional de Cuyo. Facultad de Ciencias Exactas y Naturales; Argentina. Universidad Tecnologica Nacional. Facultad Regional Mendoza. Secretaría de Ciencia, Tecnología y Postgrado; ArgentinaFil: Atlas, Elliot. University of Miami; Estados UnidosFil: Rodriguez Lloeveras, Xavier. Consejo Superior de Investigaciones Científicas. Instituto de Química Física; EspañaFil: Kinnison, Douglas E.. National Center For Atmospheric Research. Amospheric Chemistry División; Estados UnidosFil: Lamarque, Jean Francois. National Center For Atmospheric Research. Amospheric Chemistry División; Estados UnidosFil: Tilmes, Simone. National Center For Atmospheric Research. Amospheric Chemistry División; Estados UnidosFil: Thornberry, Troy. State University of Colorado at Boulder; Estados Unidos. Earth System Research Laboratory; Estados UnidosFil: Rollins, Andrew. State University of Colorado at Boulder; Estados Unidos. Earth System Research Laboratory; Estados UnidosFil: Elkins, James W.. Earth System Research Laboratory; Estados UnidosFil: Hintsa, Eric J.. State University of Colorado at Boulder; Estados Unidos. Earth System Research Laboratory; Estados UnidosFil: Moore, Fred L.. State University of Colorado at Boulder; Estados Unidos. Earth System Research Laboratory; Estados Unido

Functional nanostructured chitosan–siloxane hybrids

New organic–inorganic hybrids were prepared by a sol–gel method from the biopolymer chitosan and a silane coupling agent, 3-isocyanatopropyltriethoxysilane (ICPTES), in which covalent bridges, essentially composed of urea, bond the chitosan to the poly(siloxane) network. The structural characterization of the advanced chitosan–siloxane hybrids was performed by Fourier transform infrared spectroscopy, X-ray diffraction and 29Si and 13C nuclear magnetic resonance. The presence of siloxane nanodomains was detected by small angle X-ray diffraction. The chitosan–siloxane hybrids are bifunctional materials with interesting photoluminescent features and bioactive behaviour. The photoluminescence spectra display an additional high-energy band with longer lifetime, relatively to the characteristic emission of pure chitosan. This band is associated with electron–hole recombinations arising from silicon-related defects at the surface of the siliceous nanodomains. The bioactive behaviour of these materials was also evaluated; the apatite formation was shown to depend on the amount and arrangement of silanol groups

4-Methyl­phenyl 4-bromo­benzoate

In the title compound, C14H11BrO2, an ester formed from the reaction of 4-methyl­phenol with 4-bromo­benzoyl­chloride, the dihedral angle between the benzene rings is 54.43 (7)°, indicating a twist in the mol­ecule. In the crystal, weak C—H⋯O inter­actions link the mol­ecules into supra­molecular layers in the bc plane, and these are connected along the a axis by Br⋯Br contacts [3.6328 (5) Å]