729 research outputs found
Scalable slot-die coated flexible supercapacitors from upcycled PET face shields
\ua9 2024 The Royal Society of Chemistry.Upcycling Covid19 plastic waste into valuable carbonaceous materials for energy storage applications is a sustainable and green approach to minimize the burden of waste plastic on the environment. Herein, we developed a facile single step activation technique for producing activated carbon consisting of spherical flower like carbon nanosheets and amorphous porous flakes from used PET [poly(ethylene terephthalate)] face shields for supercapacitor applications. The as-obtained activated carbon exhibited a high specific surface area of 1571 m2 gâ1 and pore volume of 1.64 cm3 gâ1. The specific capacitance of these carbon nanostructure-coated stainless steel electrodes reached 228.2 F gâ1 at 1 A gâ1 current density with excellent charge transport features and good rate capability in 1 M Na2SO4 aqueous electrolyte. We explored the slot-die coating technique for large-area coatings of flexible high-performance activated carbon electrodes with special emphasis on optimizing binder concentration. Significant improvement in electrochemical performance was achieved for the electrodes with 15 wt% Nafion concentration. The flexible supercapacitors fabricated using these electrodes showed high energy and power density of 21.8 W h kgâ1 and 20 600 W kgâ1 respectively, and retained 96.2% of the initial capacitance after 10 000 cycles at 2 A gâ1 current density. The present study provides a promising sustainable approach for upcycling PET plastic waste for large area printable supercapacitors
Feed rate modeling in circularâcircular interpolation discontinuity for high-speed milling
In this paper, a modeling approach is presented in order to evaluate feed rate during a circular interpolation in high-speed milling. The developed model depends on the type of discontinuity and the kinematic performance of the machine tool. To begin with, a feed rate modeling for circular interpolation with continuity in tangency is developed. After, the discontinuity in tangency between two circular interpolations is replaced by discontinuity in curvature by adding a fillet which is in relation to the functional tolerance Δ imposed in the part design. An experimental study has been carried out to validate the models
Sixty-one macrofungi species new to Hungary in ĆrsĂ©g National Park
In this paper, an annotated checklist of macrofungi from ĆrsĂ©g National Park, West Hungary, is provided. A total of 726 macrofungi taxa representing 214 genera, 84 classes and 2 phyla (Asco- and Basidiomycota) were revealed. Sixty-one macrofungi species were new to the mycobiota of Hungary. Sporocarps were collected three times (in May, August and SeptemberâOctober) between 2009 and 2010 in 35 (40 m Ă 40 m) forest stands with different tree species compositions. Preferred tree species compositions and substrata of registered macrofungi are also listed
Superconductivity and antiferromagnetism in a hard-core boson spin-1 model in two dimensions
A model of hard-core bosons and spin-1 sites with single-ion anisotropy is
proposed to approximately describe hole pairs moving in a background of
singlets and triplets with the aim of exploring the relationship between
superconductivity and antiferromagnetism. The properties of this model at zero
temperature were investigated using quantum Monte Carlo techniques. The most
important feature found is the suppression of superconductivity, as long range
coherence of preformed pairs, due to the presence of both antiferromagnetism
and excitations. Indications of charge ordered and other phases are
also discussed.Comment: One figure, one reference, adde
Los mosquitos del estado de Quintana Roo, MĂ©xico (Diptera: Culicidae).
A study on the distribution of the mosquitoes of Quintana Roo State of MĂ©xico was carried out by collecting immature and adult stages during September and October 2006. The collections were made from different locations in the three physiogeographical provinces of the state: Carso Yucateco, Carso, LomerĂos de Campeche, and Costa Baja de Quintana Roo. A total of 420 larvae, 294 pupae, and 726 adults representing 13 genera and 41 species were collected. Two genera, three subgenera, and 11 species are new to the mosquito fauna of Quintana Roo State. Collection and bionomical data are included for species collected during the study, and a checklist of species newly and previously recorded from the state is provided.Un estudio de la distribuciĂłn de los mosquitos del estado de Quintana Roo, MĂ©xico fue realizado por medio de colectas de estados inmaduros y adultos durante Septiembre y Octubre del 2006. Las colectas fueron realizadas en diferentes localidades de las tres provincias fisiogrĂĄficas del estado: Carso Yucateco, Carso, LomerĂos de Campeche y Costa Baja de Quintana Roo. Un total de 420 larvas, 294 pupas y 726 adultos fueron colectados representando 13 gĂ©neros y 41 especies. Dos gĂ©neros, tres subgĂ©neros y 11 especies son nuevos registros estatales para Quintana Roo
Nematic suspension of a microporous layered silicate obtained by forceless spontaneous delamination via repulsive osmotic swelling for casting high-barrier all-inorganic films
Exploiting the full potential of layered materials for a broad range of applications requires delamination into functional nanosheets. Delamination via repulsive osmotic swelling is driven by thermodynamics and represents the most gentle route to obtain nematic liquid crystals consisting exclusively of single-layer nanosheets. This mechanism was, however, long limited to very few compounds, including 2:1-type clay minerals, layered titanates, or niobates. Despite the great potential of zeolites and their microporous layered counterparts, nanosheet production is challenging and troublesome, and published procedures implied the use of some shearing forces. Here, we present a scalable, eco-friendly, and utter delamination of the microporous layered silicate ilerite into single-layer nanosheets that extends repulsive delamination to the class of layered zeolites. As the sheet diameter is preserved, nematic suspensions with cofacial nanosheets of â9000 aspect ratio are obtained that can be cast into oriented films, e.g., for barrier applications
The Wisconsin Plasma Astrophysics Laboratory
The Wisconsin Plasma Astrophysics Laboratory (WiPAL) is a flexible user
facility designed to study a range of astrophysically relevant plasma processes
as well as novel geometries that mimic astrophysical systems. A multi-cusp
magnetic bucket constructed from strong samarium cobalt permanent magnets now
confines a 10 m, fully ionized, magnetic-field free plasma in a spherical
geometry. Plasma parameters of to eV and
to cm provide an ideal testbed
for a range of astrophysical experiments including self-exciting dynamos,
collisionless magnetic reconnection, jet stability, stellar winds, and more.
This article describes the capabilities of WiPAL along with several
experiments, in both operating and planning stages, that illustrate the range
of possibilities for future users.Comment: 21 pages, 12 figures, 2 table
Metabolism of ticagrelor in patients with acute coronary syndromes.
© The Author(s) 2018Ticagrelor is a state-of-the-art antiplatelet agent used for the treatment of patients with acute coronary syndromes (ACS). Unlike remaining oral P2Y12 receptor inhibitors ticagrelor does not require metabolic activation to exert its antiplatelet action. Still, ticagrelor is extensively metabolized by hepatic CYP3A enzymes, and AR-C124910XX is its only active metabolite. A post hoc analysis of patient-level (nâ=â117) pharmacokinetic data pooled from two prospective studies was performed to identify clinical characteristics affecting the degree of AR-C124910XX formation during the first six hours after 180âmg ticagrelor loading dose in the setting of ACS. Both linear and multiple regression analyses indicated that ACS patients presenting with ST-elevation myocardial infarction or suffering from diabetes mellitus are more likely to have decreased rate of ticagrelor metabolism during the acute phase of ACS. Administration of morphine during ACS was found to negatively influence transformation of ticagrelor into AR-C124910XX when assessed with linear regression analysis, but not with multiple regression analysis. On the other hand, smoking appears to increase the degree of ticagrelor transformation in ACS patients. Mechanisms underlying our findings and their clinical significance warrant further research.Peer reviewedFinal Published versio
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