Uncovering the spatial heterogeneity of Ediacaran carbon cycling

Author Posting. © The Author(s), 2016. This is the author's version of the work. It is posted here under a nonexclusive, irrevocable, paid-up, worldwide license granted to WHOI. It is made available for personal use, not for redistribution. The definitive version was published in Geobiology 15 (2017): 211–224, doi:10.1111/gbi.12222.Records of the Ediacaran carbon cycle (635 to 541 million years ago) include the Shuram excursion (SE), the largest negative carbonate-carbon isotope excursion in Earth history (down to -12 ‰). The nature of this excursion remains enigmatic given the difficulties of interpreting a perceived extreme global decrease in the δ13C of seawater dissolved inorganic carbon (DIC). Here, we present carbonate and organic carbon isotope (δ13Ccarb and δ13Corg) records from the Ediacaran Doushantuo Formation along a proximal-to-distal transect across the Yangtze Platform of South China as a test of the spatial variation of the SE. Contrary to expectations, our results show that the magnitude and morphology of this excursion and its relationship with coexisting δ13Corg are highly heterogeneous across the platform. Integrated geochemical, mineralogical, petrographic, and stratigraphic evidence indicates that the SE is a primary marine signature. Data compilations demonstrate that the SE was also accompanied globally by parallel negative shifts of δ34S of carbonate-associated sulfate (CAS) and increased 87Sr/86Sr ratio and coastal CAS concentration, suggesting elevated continental weathering and coastal marine sulfate concentration during the SE. In light of these observations, we propose a heterogeneous oxidation model to explain the high spatial heterogeneity of the SE and coexisting δ13Corg records of the Doushantuo, with likely relevance to the SE in other regions. In this model, we infer continued marine redox stratification through the SE but with increased availability of oxidants (e.g., O2 and sulfate) limited to marginal near-surface marine environments. Oxidation of limited spatiotemporal extent provides a mechanism to drive heterogeneous oxidation of subsurface reduced carbon mostly in shelf areas. Regardless of the mechanism driving the SE, future models must consider the evidence for spatial heterogeneity in δ13C presented in this study.We thank the National Key Basic Research Program of China (Grant 2013CB955704) and the State Key R&D project of China (Grant 2016YFA060104) as well as the NSF-ELT program and the NASA Astrobiology Institute (TWL) for funding

Central Bank Digital Currencies: Towards a Chinese Approach : Design Choices of Digital Currency Electronic Payment

Inspired by the digital revolution to the financial industry, the discussion around central bank digital currency also attract attention from academics and central banks. The People’s Bank of China (PBOC) is also researching on China’s CBDC: digital currency electronic payment (DCEP) and announced that DCEP would be issued as soon as possible.  However, the PBOC does not systematically disclose the information of DCEP. The characteristics and mechanism design are still obscured and need to be explored deeply. This thesis analysed the classification and mechanism design choices of DCEP from the perspective of two different demands: general demand and central bank demand. Based on pragmatism philosophy, we use a mixed-methods approach that is a combination of qualitative and quantitative research. Through the interview and surveys, we identified the demands from the PBOC and the general public in China and the characteristics of DCEP from official claims. Then generate the design choices via the money flower and the pyramid of CBDC models and compare the result with the demand. The analysis shows that the DCEP belongs to type B general-purpose CB digital tokens, and it would adopt a complex multi-layer hybrid architecture design, with the support from both DLT and conventional way. In conclusion, the current mechanism design choices can meet the demands from each side to a certain extent and reached a delicate balance under the trade-off between privacy and security issues. This thesis provides an insightful view on the classification and design choices of DCEP, fulfils the lack of systematic research relating to the demand and design choices of DCEP, and reveals the public’s insufficient knowledge in DCEP

Numerical Modelling of Blasting Dust Concentration and Particle Size Distribution during Tunnel Construction by Drilling and Blasting

In order to reduce the blasting dust concentration in the tunnel during the drilling and blasting, accelerate the tunnel excavation process, and improve the working environment for the construction workers, a three-dimensional geometric model of dust transport was established based on the gas-solid two-phase flow model using the DesginModeler software, and the discrete phase model (DPM) in the FLUENT software was used to simulate the variation of dust concentration and the distribution of dust particle size at different locations along the tunnel route within 1200 s after tunnel blasting. The results showed that the concentration of blasting dust gradually decreased over time, with the fastest decrease in the range of 2 s to 120 s, and after 900 s, the dust concentration stabilized. The overall spatial distribution of the dust concentration showed a trend of decreasing from the palm face to the tunnel entrance and from the bottom plate to the upper part. The distribution pattern of dust with different particle sizes was not the same along the length of the tunnel. The large particles settled in the area of 25 m from the palm face under the action of gravity. With the increases of distance, the mass flow rate decreased, and the dust particle size became smaller, but the proportion of small particles gradually increased, while the R-R distribution index increased. The results in this study were confirmed to be reliable by comparing the measured data to provide guidance for the dust reduction technology in tunnel blasting, so as to quickly remove the dust generated during the blasting process and improve the engineering construction efficiency

Types and Genesis of Siderite in the Coal-Bearing Beds of the Late Permian Xuanwei Formation in Eastern Yunnan, China

The Late Permian strata of the Xuanwei Formation in the eastern Yunnan region exhibit extensive diverse morphological features within siderite deposits. These variations in siderite deposits suggest potential differences in their formation processes. In this study, fieldwork and comprehensive indoor studies revealed four distinct forms of siderite deposits: stratiform-laminated, lens-like nodule, sandstone cementation, and fracture filling. The stratiform-laminated siderite, varying in color from bluish-grey to dark grey, is composed of uniformly sized microcrystalline to fine-grained siderite along with detrital matter, displaying precise layering and banding structures that suggest direct deposition from cyclic iron-rich seawater under reducing conditions. Lens-like-nodule siderite, which appears grey-yellow, is composed of mud microcrystalline siderite, medium to coarse-grained pseudo-ooids, and glauconite. It shows conformable distribution characteristics resulting from the diagenetic differentiation of iron-rich sediments under reducing conditions during the diagenetic and early diagenetic periods. Siderite as sandstone cementation exhibits a yellow-brown color and consists of dispersed colloidal siderite and cemented siderite clumps that fill intergranular pores of detrital particles. It precipitated under reducing conditions within those intergranular pores. Siderite filling fractures typically appear as vein-like or network-like structures intersecting bedding at large angles. They exhibit grain structures with significant variations in size. These siderite deposits exhibit exceptional purity and result from siderite dissolution during sedimentary periods, followed by reprecipitation within regional extensional fractures during the diagenetic phase. The primary occurrence of siderite deposits in the study area is within coal-bearing strata, as revealed by the integration of sedimentary profiles and sedimentary facies analysis. The coal-bearing strata, influenced by the Emeishan large igneous province, underwent iron enrichment during and after volcanic eruptions while developing a reducing environment, which was facilitated by abundant vegetation. Consequently, geological processes led to siderite layers, lens-like siderite nodules, and siderite cementation. The Yanshan orogeny induced extensive high-angle fracture development in epigenetic coal-bearing strata, facilitating fluid circulation and the redistribution of soluble siderite. This geological activity resulted in the formation of vein-like structures composed of siderite

Gut lymph purification alleviates acute lung injury induced by intestinal ischemia-reperfusion in rats by removing danger-associated molecular patterns from gut lymph

Background: The potential effect of removing danger-associated molecular patterns (DAMPs) from gut lymph on reducing acute lung injury (ALI) induced by gut ischemia-reperfusion injury (GIRI) is uncertain. This study aimed to investigate whether gut lymph purification (GLP) could improve GIRI-induced acute lung injury in rats by clearing danger-associated molecular patterns. Materials and methods: Rats were divided into four groups: Sham, GIRI, GIRI + gut lymph drainage (GLD), and GIRI + GLP. After successful modeling, lung tissue samples were collected from rats for hematoxylin-eosin (HE) staining and detection of apoptotic indexes. We detected the DAMPs levels in blood and lymph samples. We observed the microstructure of AEC Ⅱ and measured the expression levels of apoptosis indexes. Results: The GIRI group showed destruction of alveolar structure, thickened alveolar walls, and inflammatory cell infiltration. This was accompanied by significantly increased levels of high mobility group protein-1 (HMGB-1) and Interleukin-6 (IL-6), while reduced levels of heat shock protein 70 (HSP 70) and Interleukin-10 (IL-10) in both lymph and serum. In contrast, the lung tissue damage in the GIRI + GLP group was significantly improved compared to the GIRI group. This was evidenced by a reduction in the expression levels of HMGB-1 and IL-6 in both lymph and serum and an increase in HSP 70 and IL-10 levels. Additionally, organelle structure of AEC II was significantly improved in the GIRI + GLP group compared to the GIRI group. Conclusions: GLP inhibits inflammation and cell apoptosis in GIRI-induced ALI by blocking the link between DAMPs and mononuclear phagocytes, reducing the severity of ALI

Improvement of human-induced wildfire occurrence modeling from a spatial variation of anthropogenic ignition factor in the CLM5

Wildfire is an essential form of natural disturbance for the Earth system, and it is challenging for the current numerical models to accurately retrieve the spatiotemporal distributions of wildfire occurrence. One of the deficiencies could result from the parameterization of anthropogenic impact on wildfire occurrences. This study develops an approach to advance human-induced wildfire modeling by calibrating the parameter of human ignition count (HIC) in the fire module of the Community Land Model version 5. This study modifies the source code to allow a grid-scale variation of HIC. Sensitivity experiments with different grid-uniform HIC values are conducted to quantify the model biases with satellite-based observation data as the reference. The theoretically optimal HIC for each grid is obtained by linear rescaling the HIC based on the model biases in the sensitivity tests. The model evaluation takes place in southwest China where there is complex terrain and land use/land cover features. The involvement of grid-scale HIC significantly reduces the model bias in the climatology of wildfire occurrence. The pattern correlation coefficient increases from 0.57 to 0.78, and the root mean square error (RMSE) decreases from 0.58 to 0.18. The correlation coefficient of the annual sums of wildfire occurrences increases from 0.69 to 0.77, and the RMSE decreases from 560.8 to 146.4. A global-scale test verifies that such an approach can be extended to multiple regions with a reasonable scale of population density and economy

Comparison of the Proximate Composition and Nutritional Profile of Byproducts and Edible Parts of Five Species of Shrimp

The nutritional components of different parts (meat, head, shell and tail) of Litopenaeus vannamei (L.v), Macrobrachium rosenbergii (M.r), Penaeus monodon (P.m), Fenneropenaeus chinensis (F.c), and Penaeus japonicus (P.j) were analyzed and their nutritional values were evaluated. For the five species of shrimp, the meat yield was 37.47–55.94%, and the byproduct yield was 44.06–62.53%. The meat yields of L.v and F.c were the highest (55.94 and 55.92%, respectively), and the meat yield of M.r was the lowest (37.47%). The shrimp contain high amounts of crude protein, and the values of the amino acid score (AAS), chemical score (CS), and essential amino index (EAAI) were greater than or close to 1.00, indicating that shrimp protein had higher nutritional value. The shrimp head was rich in polyunsaturated fatty acids and the ratio of n-6 to n-3 PUFAs was from 0.37 to 1.68, indicating that the shrimp head is rich in n-3 PUFAs and is a good source of n-3 PUFAs. The five species of shrimp were rich in macro- and micro-minerals, especially in shrimp byproducts. The shrimp byproducts were also rich in other bioactive ingredients (astaxanthin), which are also very valuable for developing biological resources. Therefore, shrimp have many nutritional benefits, and their byproducts can also be used to develop natural nutraceuticals, which are considered to be one of the healthiest foods