Lingin Derived Organic Matter in Georgia Coastal Waters

The importance of riverine- and saltmarsh-derived organic matter to the food web of Georgia coastal waters has been a focus of ecological research over the past thirty years. Studies based on energy budgets, carbon flux measurements, and stable isotope ratios have generally implicated marsh detritus as an important, although not always dominant, source of organic matter within the marshes and adjacent estuaries (Teal 1962, Odum and de la Cruz 1967, Haines 1977, Peterson and Howarth 1987). However, data on the contribution of exported marsh and riverine organic matter to productivity futher offshore, in continental shelf waters off the coast of Georgia, remains equivocal (Chalmers et al. 1985, Hopkinson 1985). Dissolved lignin-derived compounds provide molecular level markers by which to determine the presence of terrestrially-derived organic matter in marine ecosystems. Lignin is found only in vascular plants and has no known oceanic sources. Thus its presence in seawater serves as unequivocal evidence of input of marsh or riverine organic matter, and indeed such lignin-derived material has been found in open ocean water a great distance from its probable point of origin (Meyers-Schulte and Hedges 1986). In this study, we present data on concentrations and distribution of lignin phenols in seawater samples collected during October and November 1987 on the continental shelf of the southeastern U.S., between Cape Hattaras and Cape Canaveral

Distribution of Terrestrially Derived Dissolved Organic Matter on the Southeastern United States Continental Shelf

Dissolved lignin-derived compounds in seawater indicate the presence of organic matter originating from vascular plants and therefore from terrestrial (upland and coastal marsh) ecosystems. We used a hydrophobic resin to concentrate lignin-rich humic substances and to determine concentrations of lignin oxidation products (vanillyl lignin phenols) for waters of the continental shelf of the southeastern U.S. Lignin phenol concentrations ranged from 0.05 to 4.2µg liter‒1 and accounted for 0.002–0.13% of the total dissolved organic carbon (DOC) pool in continental shelf waters. Dissolved lignin concentrations were generally highest near the shore and in those areas receiving greatest river and marsh discharge. Concentrations varied on both short-term (weekly) and seasonal time scales, however, indicating that the contribution of terrestrially derived dissolved organic matter to the C budget of the shelf is quite variable. Salinity (\u3e 31‰) was significantly correlated (negatively) with lignin phenol concentrations during three of four cruises, suggesting largely conservative mixing of lignin-derived material on the shelf In selected rivers and salt marshes contributing terrestrially derived organic matter to the continental shelf, lignin phenol C accounted for 0.14–1.0% of the DOC. A simple mixing model which assumes no biological or physical sinks of lignin-derived material during transport from terrestrial sources to the shelf predicts that an average of 6–36% of nearshore DOC derives from terrestrial ecosystems, depending on whether the terrestrial end-member (lignin source) is assumed to be a river or a salt marsh, while 5–26% of inner shelf DOC and 3–18% of mid- to outer-shelf DOC is of terrestrial origin

PokeME: Applying context-driven notifications to increase worker engagement in mobile crowd-sourcing

National Research Foundation (NRF) Singapore under International Research Centres in Singapore Funding Initiativ

The AllWISE Motion Survey, Part 2

We use the AllWISE Data Release to continue our search for WISE-detected motions. In this paper, we publish another 27,846 motion objects, bringing the total number to 48,000 when objects found during our original AllWISE motion survey are included. We use this list, along with the lists of confirmed WISE-based motion objects from the recent papers by Luhman and by Schneider et al. and candidate motion objects from the recent paper by Gagne et al. to search for widely separated, common-proper-motion systems. We identify 1,039 such candidate systems. All 48,000 objects are further analyzed using color-color and color-mag plots to provide possible characterizations prior to spectroscopic follow-up. We present spectra of 172 of these, supplemented with new spectra of 23 comparison objects from the literature, and provide classifications and physical interpretations of interesting sources. Highlights include: (1) the identification of three G/K dwarfs that can be used as standard candles to study clumpiness and grain size in nearby molecular clouds because these objects are currently moving behind the clouds, (2) the confirmation/discovery of several M, L, and T dwarfs and one white dwarf whose spectrophotometric distance estimates place them 5-20 pc from the Sun, (3) the suggestion that the Na 'D' line be used as a diagnostic tool for interpreting and classifying metal-poor late-M and L dwarfs, (4) the recognition of a triple system including a carbon dwarf and late-M subdwarf, for which model fits of the late-M subdwarf (giving [Fe/H] ~ -1.0) provide a measured metallicity for the carbon star, and (5) a possible 24-pc-distant K5 dwarf + peculiar red L5 system with an apparent physical separation of 0.1 pc.Comment: 62 pages with 80 figures, accepted for publication in The Astrophysical Journal Supplement Series, 23 Mar 2016; second version fixes a few small typos and corrects the footnotes for Table

New Y and T dwarfs from WISE identified by Methane Imaging

We identify new Y- and T-type brown dwarfs from the WISE All Sky data release using images obtained in filters that divide the traditional near-infrared H and J bands into two halves -- specifically CH4s & CH4l in the H and J2 & J3 in the J. This proves to be very effective at identifying cool brown dwarfs via the detection of their methane absorption, as well as providing preliminary classification using methane colours and WISE-to-near-infrared colours. New and updated calibrations between T/Y spectral types and CH4s-CH4l, J3-W2, and CH4s-W2 colours are derived, producing classification estimates good to a few spectral sub-types. We present photometry for a large sample of T and Y dwarfs in these filters, together with spectroscopy for 23 new ultra-cool dwarfs - two Y dwarfs and twenty one T dwarfs. We identify a further 8 new cool brown dwarfs, which we have high confidence are T dwarfs based on their methane photometry. We find that, for objects observed on a 4m-class telescope at J band magnitudes of ~20 or brighter, CH4s-CH4l is the more powerful colour for detecting objects and then estimating spectral types. Due to the lower sky background in the J-band, the J3 and J2 bands are more useful for identifying fainter cool dwarfs at J>22. The J3-J2 colour is poor at estimating spectral types. But fortunately, once J3-J2 confirms that an object is a cool dwarf, the J3-W2 colour is very effective at estimating approximate spectral types.Comment: 29 pages, 6 figures. To appear in the Astrophysical Journal Supplemen

A Study of the Diverse T Dwarf Population Revealed by WISE

We report the discovery of 87 new T dwarfs uncovered with the Wide-field Infrared Survey Explorer (WISE) and three brown dwarfs with extremely red near-infrared colors that exhibit characteristics of both L and T dwarfs. Two of the new T dwarfs are likely binaries with L7+/-1 primaries and mid-type T secondaries. In addition, our follow-up program has confirmed 10 previously identified T dwarfs and four photometrically-selected L and T dwarf candidates in the literature. This sample, along with the previous WISE discoveries, triples the number of known brown dwarfs with spectral types later than T5. Using the WISE All-Sky Source Catalog we present updated color-color and color-type diagrams for all the WISE-discovered T and Y dwarfs. Near-infrared spectra of the new discoveries are presented, along with spectral classifications. To accommodate later T dwarfs we have modified the integrated flux method of determining spectral indices to instead use the median flux. Furthermore, a newly defined J-narrow index differentiates the early-type Y dwarfs from late-type T dwarfs based on the J-band continuum slope. The K/J indices for this expanded sample show that 32% of late-type T dwarfs have suppressed K-band flux and are blue relative to the spectral standards, while only 11% are redder than the standards. Comparison of the Y/J and K/J index to models suggests diverse atmospheric conditions and supports the possible re-emergence of clouds after the L/T transition. We also discuss peculiar brown dwarfs and candidates that were found not to be substellar, including two Young Stellar Objects and two Active Galactic Nuclei. The coolest WISE-discovered brown dwarfs are the closest of their type and will remain the only sample of their kind for many years to come.Comment: Accepted to ApJS on 15 January 2013; 99 pages in preprint format, 30 figures, 12 table

Does transient increase in axial length during accommodation attenuate with age?

Background: The aim was to profile transient accommodative axial length (AXL) changes from early adulthood to advanced presbyopia and to determine whether any differences exist between the responses of myopic and emmetropic individuals. Methods: Ocular biometry was measured by the LenStar biometer (Haag-Streit, Switzerland) in response to 0.00, 3.00 and 4.50 D accommodative stimuli in 35 emmetropes and 37 myopes, aged 18 to 60 years. All results were corrected to reduce errors arising from the increase in crystalline lens thickness with accommodation. Accommodative responses were measured sequentially by the WAM 5500 Auto Ref/Keratometer (Grand Seiko, Japan). Results: AXL increased significantly with accommodation (p<0.001), with a mean corrected AXL elongation of 2 ± 18 µm and 8 ± 16 µm observed at 3.00 D and 4.50 D, respectively. The magnitude of accommodative AXL change was not dependent on refractive error classification (p=0.959), however a significant reduction in the magnitude and variance of AXL change was evident after 43-44 years of age (p<0.002). Conclusion: The negative association between transient AXL elongation and age, in combination with reduced variance of data after age 43-44 years, is consistent with a significant increase in posterior ocular rigidity, which may be influential in the development of presbyopia

Composition for personal growth : program design and evaluation.

<p>Two categories were used for cross-validation of the model, either type 1 or type 2. Clinical isolates were treated as an unknown class and cross-validated sensitivity, specificity, and class error were based on their classification prediction score with their respective reference strain control class. CV, cross-validated.</p><p>Cross-validated PLS-DA modeling statistics for the prediction performance for NA-SERS typing of individual type 1 and 2 <i>M</i>. <i>pneumoniae</i> clinical isolates.</p