Demonstration of High-Temperature Operation of Beta-Gallium Oxide (β-Ga2O3) Metal-Oxide-Semiconductor Field Effect Transistors (MOSFET) with Electrostatic Model in COMSOL

β-Ga2O3 is a robust semiconductor material set with a large band gap of ~4.8 eV, low intrinsic carrier concentration, and high melting point that offers a stable platform for operating electronic devices at high temperatures and extreme environments. The first half of this thesis will cover the fabrication of a fixture and packaging to test electronic components at high temperatures. Then it will highlight the characterization of β-Ga2O3 field effect transistors from room temperature (RT) up to 500 °C. The devices, fabricated with Ni/Au and Al2O3 gate metal-oxide-semiconductor (MOS), demonstrate stable operation up to 500 oC. The tested device shows no measured current degradation in the ID-VD characteristics up to 450 oC. Improvements to the drain current, ID within this temperature range are due to activation carriers from dopants/traps and the negative push in threshold voltage, VT. The device exhibits a drop in ID at 500 °C; however, device characteristics recover once the device returns to RT. Even after 20 hours of device operation at 500 °C, the device shows negligible degradation. Device characteristics such as gate leakage, ION/IOFF ratio, gm, Ron, and contact resistance show monotonic variation with temperature. The experimental results suggest that an optimized choice of metals and gate dielectrics β-Ga2O3 will provide a platform for device operation at high temperatures and extreme environments. The second half of the thesis focuses on creating an electrostatic model of a metal-oxide-semiconductor field effect transistor with COMSOL finite element analysis software to understand the physics behind semiconductor technology

Effect of nanosized filler on mechanical properties of epoxy compositesafter electron irradiation

Введение нанодисперсных наполнителей в полимеры является перспективным способом получения материалов с улучшенными характеристиками и может способствовать повышению радиационнойстойкости. В данной работе приготовлены образцы из эпоксидной смолы без наполнителя и с наполнителем - нанодисперсным алюминием (0,35 мас. %).Изучены механические характеристики образцов после облучения потоком электронов дозами 30, 100 и 300 кГр. Введение нанопорошка алюминия в эпоксидную смолу привело к повышению устойчивости полимера к радиационному воздействию.The introduction of nanosized fillers in polymers is a promising way to obtain materials with improvedproperties and can enhance the radiation resistance. In this study, the samples were prepared from the epoxy resinwithout filler and filled with nanodispersed aluminum (0.35 wt.%).The mechanical characteristics of the samplesafter irradiation with an electron beam of doses 30, 100 and 300 kGy were studied. The introduction of aluminumnanopowder in epoxy resin resulted in increased resistance to radiation

Crystallite size dependent cation distribution in nanostructured spinels studied by nmr, mössbauer spectroscopy and XPS

Owing to the structural flexibility of spinels, providing a wide range of physical and chemical behavior, these materials have been considered as a convenient model system for the investigation of the size dependent properties of complex ionic systems. In this work, quantitative formation is obtained on the crystallite size dependent ionic configuration in nanosized spinel oxides prepared by mechanochemical processing of the corresponding bulk materials. Experimentally determined values of the crystallite size and of the mean degree of inversion of nanostructured spinels are used to calculate the volume fraction of interfaces/surfaces and their thickness in the nanomaterials

Structure and ion dynamics of mechanosynthesized oxides and fluorides

In many cases, limitations in conventional synthesis routes hamper the accessibility to materials with properties that have been predicted by theory. For instance, metastable compounds with local non-equilibrium structures can hardly be accessed by solid-state preparation techniques often requiring high synthesis temperatures. Also other ways of preparation lead to the thermodynamically stable rather than metastable products. Fortunately, such hurdles can be overcome by mechanochemical synthesis. Mechanical treatment of two or three starting materials in high-energy ball mills enables the synthesis of not only new, metastable compounds but also of nanocrystalline materials with unusual or enhanced properties such as ion transport. In this short review we report about local structures and ion transport of oxides and fluorides mechanochemically prepared by high-energy ball-milling

The mechanically induced structural disorder in barium hexaferrite, BaFe12O19, and its impact on magnetism

The response of the structure of the M-type barium hexaferrite (BaFe12O19) to mechanical action through high-energy milling and its impact on the magnetic behaviour of the ferrite are investigated. Due to the ability of the Fe-57 Mossbauer spectroscopic technique to probe the environment of the Fe nuclei, a valuable insight on a local atomic scale into the mechanically induced changes in the hexagonal structure of the material is obtained. It is revealed that the milling of BaFe12O19 results in the deformation of its constituent polyhedra (FeO6 octahedra, FeO4 tetrahedra and FeO5 triangular bi-pyramids) as well as in the mechanically triggered transition of the Fe3+ cations from the regular 12k octahedral sites into the interstitial positions provided by the magnetoplumbite structure. The response of the hexaferrite to the mechanical treatment is found to be accompanied by the formation of a non-uniform nanostructure consisting of an ordered crystallite surrounded/separated by a structurally disordered surface shell/interface region. The distorted polyhedra and the non-equilibrium cation distribution are found to be confined to the amorphous near-surface layers of the ferrite nanoparticles with the thickness extending up to about 2 nm. The information on the mechanically induced short-range structural disorder in BaFe12O19 is complemented by an investigation of its magnetic behaviour on a macroscopic scale. It is demonstrated that the milled ferrite nanoparticles exhibit a pure superparamagnetism at room temperature. As a consequence of the far-from-equilibrium structural disorder in the surface shell of the nanoparticles, the mechanically treated BaFe12O19 exhibits a reduced magnetization and an enhanced coercivity.DFG/SPP/1415APVV/0528-11VEGA/2/0097/1

Magnesium Ferrite (MgFe2O4) Nanostructures Fabricated by Electrospinning

Magnesium ferrite (MgFe2O4) nanostructures were successfully fabricated by electrospinning method. X-ray diffraction, FT-IR, scanning electron microscopy, and transmission electron microscopy revealed that calcination of the as-spun MgFe2O4/poly(vinyl pyrrolidone) (PVP) composite nanofibers at 500–800 °C in air for 2 h resulted in well-developed spinel MgFe2O4nanostuctures. The crystal structure and morphology of the nanofibers were influenced by the calcination temperature. Crystallite size of the nanoparticles contained in nanofibers increased from 15 ± 4 to 24 ± 3 nm when calcination temperature was increased from 500 to 800 °C. Room temperature magnetization results showed a ferromagnetic behavior of the calcined MgFe2O4/PVP composite nanofibers, having their specific saturation magnetization (Ms) values of 17.0, 20.7, 25.7, and 31.1 emu/g at 10 Oe for the samples calcined at 500, 600, 700, and 800 °C, respectively. It is found that the increase in the tendency ofMsis consistent with the enhancement of crystallinity, and the values ofMsfor the MgFe2O4samples were observed to increase with increasing crystallite size

Magnetic enhancement of Co0.2_{0.2}Zn0.8_{0.8}Fe2_2O4_4 spinel oxide by mechanical milling

We report the magnetic properties of mechanically milled Co$_{0.2}$Zn$_{0.8}$Fe$_2$O$_4$ spinel oxide. After 24 hours milling of the bulk sample, the XRD spectra show nanostructure with average particle size $\approx$ 20 nm. The as milled sample shows an enhancement in magnetization and ordering temperature compared to the bulk sample. If the as milled sample is annealed at different temperatures for the same duration, recrystallization process occurs and approaches to the bulk structure on increasing the annealing temperatures. The magnetization of the annealed samples first increases and then decreases. At higher annealing temperature ($\sim$ 1000$^{0}$C) the system shows two coexisting magnetic phases {\it i.e.}, spin glass state and ferrimagnetic state, similar to the as prepared bulk sample. The room temperature M\"{o}ssbauer spectra of the as milled sample, annealed at 300$^{0}$C for different durations (upto 575 hours), suggest that the observed change in magnetic behaviour is strongly related with cations redistribution between tetrahedral (A) and octahedral (O) sites in the spinel structure. Apart from the cation redistribution, we suggest that the enhancement of magnetization and ordering temperature is related with the reduction of B site spin canting and increase of strain induced anisotropic energy during mechanical milling.Comment: 14 pages LaTeX, 10 ps figure

Magnetic Response of NiFe2O4 nanoparticles in polymer matrix

We report the magnetic properties of magnetic nano-composite, consisting of different quantity of NiFe2O4 nanoparticles in polymer matrix. The nanoparticles exhibited a typical magnetization blocking, which is sensitive on the variation of magnetic field, mode of zero field cooled/field cooled experiments and particle quantity in the matrix. The samples with lower particle quantity showed an upturn of magnetization down to 5 K, whereas the blocking of magnetization dominates at lower temperatures as the particle quantity increases in the polymer. We examine such magnetic behaviour in terms of the competitive magnetic ordering between core and surface spins of nanoparticles, taking into account the effect of inter-particle (dipole-dipole) interactions on nanoparticle magnetic dynamics.Comment: 5 fihur

Modification of TiO2 and ZnO Particles Under Mechanical Stress with Polypropylene

Solid-state process of introducing oxygen vacancies into the structure of TiO2 and ZnO particles was studied. The phase transformations of metal oxides throughout the process were examined by X-ray diffraction (XRD). The influence of the loaded mechanical stress on the band gap was studied by diffuse reflectance spectroscopy (DRS). Mechanism of elimination of oxygen atoms from the surface of the oxides by co-milling with polyolefins, which can lead to creation of more effective materials for waste water treatment, was proposed.This is the peer-reviewed version of the paper: Skurikhina, O., Tothova, E., Markovic, S., Senna, M., 2020. Modification of TiO2 and ZnO Particles Under Mechanical Stress with Polypropylene, in: Petkov, P., Achour, M.E., Popov, C. (Eds.), Nanoscience and Nanotechnology in Security and Protection against CBRN Threats, NATO Science for Peace and Security Series B: Physics and Biophysics. Springer Netherlands, Dordrecht, pp. 209–213. [https://doi.org/10.1007/978-94-024-2018-0_16