Wildlife Connectivity and Which Median Barrier Designs Provide the Most Effective Permeability for Wildlife Crossings

Median barriers are usually constructed to reduce head-on-crashes between vehicles on undivided highways. Because of their position in the center of the traveled right-of-way, median barriers could affect wildlife movement across the right-of-way, decreasing wildlife connectivity. The authors coordinated and met with staff from several Caltrans Districts to gain understanding of their issues related to median barriers and wildlife permeability. The authors used previously and newly collected wildlife-vehicle collision (WVC) observations to test whether or not median types have different effects on unsuccessful wildlife crossings of the road surface. The authors used Generalized Linear Models (GLM) to compare WVC rates among median treatment types in three Caltrans Districts (2, 4, 9) for four wildlife species. The primary findings were that there are effects of median types on rates of WVC and that these effects varied by species and to some degree by geographic region (represented by Caltrans District). The primary finding is that fewer wildlife enter roadways and are killed in the presence of constructed median types than other types. Although this may result in a reduction in WVC, it also results in a reduction in wildlife permeability as most roadways do not have crossing structures and therefore attempts at wildlife permeability will be across the road surface. View the NCST Project Webpag

The effects of perceived COVID-19 threat on compensatory conviction, thought reliance, and attitudes

This research examines how people can defend themselves from the threat associated with the COVID-19 pandemic by relying more on their recently generated thoughts (unrelated to the threat), thus leading those thoughts to have a greater impact on judgement through a meta-cognitive process of thought validation. Study 1 revealed that the impact of the favourability of self-related thoughts on self-esteem was greater for those feeling relatively more (vs. less) threatened by COVID-19. Study 2 manipulated (rather than measured) the favourability of thoughts and assessed the perceived COVID-19 threat. Results also showed that the impact of thoughts on subsequent self-evaluations was greater for those feeling more threatened by COVID-19. Study 3 conceptually replicated the results using a full experimental design by manipulating both thought favourability andthe perceived COVID-19 threat, moving from the self to a social perception paradigm, and providing mediational evidence for the proposed mechanism of compensatory thought validation. A final study addressed some alternative explanations by testing whether the induction of threat used in Study 3 affected perceptions of threat while not having an impact on other featuresMinisterio de Ciencia e Innovación, Gobierno de España (ES), Grant/Award Number: PID2020-116651GB-C31;PID2020- 116651GBC33/AEI/10.13039/501100011033; Consejería de Ciencia, Universidades e Innovación, Comunidad de Madrid, Grant/Award Number: SI3/PJI/2021-0047

Cation Vacancies Enable Anion Redox in Li Cathodes.

Conventional Li-ion battery intercalation cathodes leverage charge compensation that is formally associated with redox on the transition metal. Employing the anions in the charge compensation mechanism, so-called anion redox, can yield higher capacities beyond the traditional limitations of intercalation chemistry. Here, we aim to understand the structural considerations that enable anion oxidation and focus on processes that result in structural changes, such as the formation of persulfide bonds. Using a Li-rich metal sulfide as a model system, we present both first-principles simulations and experimental data that show that cation vacancies are required for anion oxidation. First-principles simulations show that the oxidation of sulfide to persulfide only occurs when a neighboring vacancy is present. To experimentally probe the role of vacancies in anion redox processes, we introduce vacancies into the Li2TiS3 phase while maintaining a high valency of Ti. When the cation sublattice is fully occupied and no vacancies can be formed through transition metal oxidation, the material is electrochemically inert. Upon introduction of vacancies, the material can support high degrees of anion redox, even in the absence of transition metal oxidation. The model system offers fundamental insights to deepen our understanding of structure-property relationships that govern reversible anion redox in sulfides and demonstrates that cation vacancies are required for anion oxidation, in which persulfides are formed

Organically Modified Silica Nanoparticles Are Biocompatible and Can Be Targeted to Neurons In Vivo

The application of nanotechnology in biological research is beginning to have a major impact leading to the development of new types of tools for human health. One focus of nanobiotechnology is the development of nanoparticle-based formulations for use in drug or gene delivery systems. However most of the nano probes currently in use have varying levels of toxicity in cells or whole organisms and therefore are not suitable for in vivo application or long-term use. Here we test the potential of a novel silica based nanoparticle (organically modified silica, ORMOSIL) in living neurons within a whole organism. We show that feeding ORMOSIL nanoparticles to Drosophila has no effect on viability. ORMOSIL nanoparticles penetrate into living brains, neuronal cell bodies and axonal projections. In the neuronal cell body, nanoparticles are present in the cytoplasm, but not in the nucleus. Strikingly, incorporation of ORMOSIL nanoparticles into the brain did not induce aberrant neuronal death or interfered with normal neuronal processes. Our results in Drosophila indicate that these novel silica based nanoparticles are biocompatible and not toxic to whole organisms, and has potential for the development of long-term applications

The Effects of Culture and Friendship on Rewarding Honesty and Punishing Deception

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