209 research outputs found

    M32+/-1

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    WFPC-2 images are used to study the central structure of M31, M32, and M33. The dimmer peak, P2, of the M31 double nucleus is centered on the bulge to 0.1", implying that it is the dynamical center of M31. P2 contains a compact source discovered by King et al. (1995) at 1700 A. This source is resolved, with r_{1/2} approx0.2 pc. It dominates the nucleus at 3000 A, and is consistent with late B-early A stars. This probable cluster may consist of young stars and be an older version of the cluster of hot stars at the center of the Milky Way, or it may consist of heavier stars built up from collisions in a possible cold disk of stars orbiting P2. In M32, the central cusp rises into the HST limit with gamma approx0.5, and the central density rho_0>10^7M_sol pc^-3. The V-I and U-V color profiles are flat, and there is no sign of an inner disk, dust, or any other structure. This total lack of features seems at variance with a nominal stellar collision time of 2 X 10^10 yr, which implies that a significant fraction of the light in the central pixel should come from blue stragglers. InM33, the nucleus has an extremely steep gamma=1.49 power-law profile for 0.05"<r<0.2" that becomes shallower as the HST resolution limit is approached. The profile for r<0.04" has either a gamma approx 0.8 cusp or a small core with r_c ~<0.13 pc. The central density is rho_0 > 2 10^6M_sol pc^-3, and the implied relaxation time is only ~3 X 10^6 yr, indicating that the nucleus is highly relaxed. The accompanying short collision time of 7 X 10^9 yr predicts a central blue straggler component quantitatively consistent with the strong V-I and B-R color gradients seen with HST and from the ground.Comment: 44 pages, 22 figures (7 as separate JPEG images), submitted to The Astronomical Journal. Full postscript image available at http://www.noao.edu/noao/staff/lauer/lauer_paper

    Thermal Behavior of Benzoic Acid/lsonicotinamide Binary Cocrystals

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    A comprehensive study of the thermal behavior of the 1:1 and 2:1 benzoic acid/isonicotinamide cocrystals is reported. The 1:1 material shows a simple unit cell expansion followed by melting upon heating. The 2:1 crystal exhibits more complex behavior. Its unit cell first expands upon heating, as a result of C–H···π interactions being lengthened. It then is converted into the 1:1 crystal, as demonstrated by significant changes in its X-ray diffraction pattern. The loss of 1 equiv of benzoic acid is confirmed by thermogravimetric analysis–mass spectrometry. Hot stage microscopy confirms that, as intuitively expected, the transformation begins at the crystal surface. The temperature at which conversion occurs is highly dependent on the sample mass and geometry, being reduced when the sample is under a gas flow or has a greater exposed surface area but increased when the heating rate is elevated

    Rapid preparation of pharmaceutical co-crystals with thermal ink-jet printing

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    Thermal ink-jet printing (TIJP) is shown to be a rapid (minutes) method with which to prepare pharmaceutical co-crystals; co-crystals were identified in all cases where the co-formers could be dissolved in water and/or water/ethanol solutions
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