Stirling material technology

The Stirling engine is an external combustion engine that offers the advantage of high fuel economy, low emissions, low noise, and low vibrations compared to current internal combustion automotive engines. The most critical component from a materials viewpoint is the heater head consisting of the cylinders, heating tubes, and regenerator housing. Materials requirements for the heater head include compatibility with hydrogen, resistance to hydrogen permeation, high temperature oxidation/corrosion resistance, and high temperature creep-rupture and fatigue properties. A materials research and technology program identified the wrought alloys CG-27 and 12RN72 and the cast alloys XF-818, NASAUT 4G-A1, and NASACC-1 as candidate replacements for the cobalt containing alloys used in current prototype engines. It is concluded that manufacture of the engine is feasible from low cost iron-base alloys rather than the cobalt alloys used in prototype engines. Results of research that lead to this conclusion are presented

A time-resolution study with a plastic scintillator read out by a Geiger-mode Avalanche Photodiode

In this work we attempt to establish the best time resolution attainable with a scintillation counter consisting of a plastic scintillator read out by a Geiger-mode Avalanche Photodiode. The measured time resolution is inversely proportional to the square root of the energy deposited in the scintillator, and scales to 18ps (sigma) at 1MeV. This result competes with the best ones reported for photomultiplier tubes.Comment: 8 pages, 8 figure

Fatigue failure of regenerator screens in a high frequency Stirling engine

Failure of Stirling Space Power Demonstrator Engine (SPDE) regenerator screens was investigated. After several hours of operation the SPDE was shut down for inspection and on removing the regenerator screens, debris of unknown origin was discovered along with considerable cracking of the screens in localized areas. Metallurgical analysis of the debris determined it to be cracked-off-deformed pieces of the 41 micron thickness Type 304 stainless steel wire screen. Scanning electron microscopy of the cracked screens revealed failures occurring at wire crossovers and fatigue striations on the fracture surface of the wires. Thus, the screen failure can be characterized as a fatigue failure of the wires. The crossovers were determined to contain a 30 percent reduction in wire thickness and a highly worked microstructure occurring from the manufacturing process of the wire screens. Later it was found that reduction in wire thickness occurred because the screen fabricator had subjected it to a light cold-roll process after weaving. Installation of this screen left a clearance in the regenerator allowing the screens to move. The combined effects of the reduction in wire thickness, stress concentration (caused by screen movement), and highly worked microstructure at the wire crossovers led to the fatigue failure of the screens

The new versatile general purpose surface-muon instrument (GPS) based on silicon photomultipliers for μ{\mu}SR measurements on a continuous-wave beam

We report on the design and commissioning of a new spectrometer for muon-spin relaxation/rotation studies installed at the Swiss Muon Source (S$\mu$S) of the Paul Scherrer Institute (PSI, Switzerland). This new instrument is essentially a new design and replaces the old general-purpose surface-muon instrument (GPS) which has been for long the workhorse of the $\mu$SR user facility at PSI. By making use of muon and positron detectors made of plastic scintillators read out by silicon photomultipliers (SiPMs), a time resolution of the complete instrument of about 160 ps (standard deviation) could be achieved. In addition, the absence of light guides, which are needed in traditionally built $\mu$SR instrument to deliver the scintillation light to photomultiplier tubes located outside magnetic fields applied, allowed us to design a compact instrument with a detector set covering an increased solid angle compared to the old GPS.Comment: 11 pages, 11 figure

Closed-loop recycling of plastics enabled by dynamic covalent diketoenamine bonds.

Recycled plastics are low-value commodities due to residual impurities and the degradation of polymer properties with each cycle of re-use. Plastics that undergo reversible polymerization allow high-value monomers to be recovered and re-manufactured into pristine materials, which should incentivize recycling in closed-loop life cycles. However, monomer recovery is often costly, incompatible with complex mixtures and energy-intensive. Here, we show that next-generation plastics-polymerized using dynamic covalent diketoenamine bonds-allow the recovery of monomers from common additives, even in mixed waste streams. Poly(diketoenamine)s 'click' together from a wide variety of triketones and aromatic or aliphatic amines, yielding only water as a by-product. Recovered monomers can be re-manufactured into the same polymer formulation, without loss of performance, as well as other polymer formulations with differentiated properties. The ease with which poly(diketoenamine)s can be manufactured, used, recycled and re-used-without losing value-points to new directions in designing sustainable polymers with minimal environmental impact

Probing the magnetic ground state of the molecular Dysprosium triangle

We present zero field muon spin lattice relaxation measurements of a Dysprosium triangle molecular magnet. The local magnetic fields sensed by the implanted muons indicate the coexistence of static and dynamic internal magnetic fields below $T^* ~35$ K. Bulk magnetization and heat capacity measurements show no indication of magnetic ordering below this temperature. We attribute the static fields to the slow relaxation of the magnetization in the ground state of Dy3. The fluctuation time of the dynamic part of the field is estimated to be ~0.55 $\mu$s at low temperaturesComment: 5 pages, 5 figures, accepted for publication in Phys. Rev.

Behaviour of a muonic atom as an acceptor centre in diamond

Polarized negative muons were used to study the behaviour of the boron acceptor centre in synthetic diamond produced by the chemical vapour deposition (CVD) method. The negative muon substitutes one of the electrons in a carbon atom, and this muonic atom imitates the boron acceptor impurity in diamond. The temperature dependence of the muon spin relaxation rate and spin precession frequency were measured in the range of 20 - 330 K in a transverse magnetic field of 14 kOe. For the first time a negative shift of the muon spin precession was observed in diamond. It is tentatively attributed to an anisotropic hyperfine interaction in the boron acceptor. The magnetic measurements showed that the magnetic susceptibility of the CVD sample was close to that of the purest natural diamond.Comment: 8 pages, 3 figure

A lens-coupled scintillation counter in cryogenic environment

In this work we present an elegant solution for a scintillation counter to be integrated into a cryogenic system. Its distinguishing feature is the absence of a continuous light guide coupling the scintillation and the photodetector parts, operating at cryogenic and room temperatures respectively. The prototype detector consists of a plastic scintillator with glued-in wavelength-shifting fiber located inside a cryostat, a Geiger-mode Avalanche Photodiode (G-APD) outside the cryostat, and a lens system guiding the scintillation light re-emitted by the fiber to the G-APD through optical windows in the cryostat shields. With a 0.8mm diameter multiclad fiber and a 1mm active area G-APD the coupling efficiency of the "lens light guide" is about 50%. A reliable performance of the detector down to 3K is demonstrated.Comment: 14 pages, 11 figure

Close proximity of FeSe to a magnetic quantum critical point as revealed by high-resolution μ\muSR measurements

A nematic transition preceding a long-range spin density wave antiferromagnetic phase is a common feature of many Fe based superconductors. However, in the FeSe system with a nematic transition at $T_{\rm s} \approx$ 90 K no evidence for long-range static magnetism down to very low temperature was found. The lack of magnetism is a challenge for the theoretical description of FeSe. Here, we investigated high-quality single crystals of FeSe using high-field (up to 9.5 Tesla) muon spin rotation ($\mu$SR) measurements. The $\mu$SR Knight shift and the bulk susceptibility linearly scale at high temperatures but deviate from this behavior around $T^{*} \sim 10$ K, where the Knight shift exhibits a kink. This behavior hints to an essential change of the electronic and/or magnetic properties crossing the region near $T^{*}$. In the temperature range $T_{\rm s} \gtrsim T \gtrsim T^{*}$ the muon spin depolarization rate follows a critical behavior $\Lambda \propto T^{-0.4}$. The observed non-Fermi liquid behavior with a cutoff at $T^{*}$ indicates that FeSe is in the vicinity to a antiferromagnetic quantum critical point. Our analysis is suggestive for $T^{*}$ triggered by the Lifshitz transition.Comment: 15 pages, 16 figure