An improved catalytic pyrolysis concept for renewable aromatics from biomass involving a recycling strategy for co-produced polycyclic aromatic hydrocarbons

Catalytic pyrolysis of crude glycerol over a shaped H-ZSM-5 zeolite catalyst with (partial) recycling of the product oil was studied with the incentive to improve benzene, toluene, and xylene (BTX) yields. Recycling of the polycyclic aromatic hydrocarbon (PAH) fraction, after separation from BTX by distillation and co-feeding with the crude glycerol feed, was shown to have a positive effect on the BTX yield. Further improvements were achieved by hydrogenation of the PAH fraction using a Ru/C catalyst and hydrogen gas prior to co-pyrolysis, and BTX yields up to 16 wt% on feed were obtained. The concept was also shown to be beneficial to other biomass feeds such as e.g., Kraft lignin, cellulose, and Jatropha oil

Longevity Around the Turn of the 20th Century: Life-Long Sustained Survival Advantage for Parents of Today’s Nonagenarians

Members of longevous families live longer than individuals from similar birth cohorts and delay/escape age related diseases. Insight into this familial component of longevity can provide important knowledge about mechanisms protecting against age-related diseases. This familial component of longevity was studied in the Leiden Longevity Study which consists of 944 longevous siblings (participants), their parents (N=842), siblings (N=2302), and spouses (N=809). Family longevity scores were estimated to explore whether human longevity is transmitted preferentially through the maternal or paternal line. Standardized mortality ratio’s (SMRs) were estimated to investigate whether longevous siblings have a survival advantage compared to longevous singletons and we investigated if parents of longevous siblings harbor a life-long sustained survival advantage compared to the general Dutch population by estimating lifetime SMRs (L-SMRs). We found that sibships with long-lived mothers and non-long-lived fathers had 0.41 (P=0.024) less observed deaths than sibships with long-lived fathers and non-long-lived mothers and 0.48 (P=0.008) less observed deaths than sibships with both parents non-long lived. Participants had 18.6% less deaths compared to matched singletons and parents had a life-long sustained survival advantage (L-SMR=0.510 and 0.688). In conclusion, genetic longevity studies may incorporate the maternal transmission pattern and genes influencing the entire life-course of individuals

Communicating uncertainty in the IPCC's greenhouse gas emissions scenarios

The issue of climate change required the development of the Special Report on Emission Scenarios (SRES) by the IPCC. The complexity of the subject and the unique science-policy relation resulted in confusion and discussions appeared in popular media like The Economist. This paper reviews scenario literature and SRES, identifies the most vulnerable elements in the communication of SRES. In the communication of GHG emission scenarios through SRES, the weaknesses that have been identified by the authors of this paper are the normative character of climate change assessment, the plausibility of the scenarios, and the risk of simplification of complex messages. The causes of these communicative issues have been identified as the intrinsic difficulties of interdisciplinary science, the uniqueness of the science-policy relation, and the need for a high degree of transparency. This paper suggests improving future communication of complex messages from scientists to their audience by means of clear reasoning when communicating with non-scientists, explicitly normative emission scenarios, and increased stakeholder participation in scenario development

The nonlinear relationship between paper recycling and primary pulp requirements:modeling paper production and recycling in Europe

Waste paper is suitable for recycling back into paper or for incineration for energy recovery. If waste paper is used for recycling, secondary pulp replaces virgin pulp. Fiber recycling is limited, however, because of physical constraints—particularly the breakage of fiber in the recycling process—and a permanent input of virgin fiber to the system is required. Therefore one can expect that the relationship between recycling rates and resource requirements is represented by a curved line rather than a straight one. In this article, we present a mathematical model which confirms that the relationship between recycling rates and primary pulp requirements can be described as nonlinear. Furthermore, we show that this nonlinear relationship leads to an optimal recycling rate with regard to energy consumption: 93% for paper produced from chemical pulp, and 81% for paper produced from mechanical pulp. Sensitivity testing additionally reveals that at low recycling rates increasing waste paper recycling is energy efficient, but it becomes less efficient at higher recycling rates. Close to the optimum recycling rates (within 10%), increasing or decreasing the rate affects the total energy requirement less than 0.3%

Wind energy, electricity, and hydrogen in the Netherlands

The curbing of greenhouse gases (GHG) is an important issue on the international political agenda. The substitution of fossil fuels by renewable energy sources is an often-advocated mitigation strategy. Wind energy is a potential renewable energy source. However, wind energy is not reliable since its electricity production depends on variable weather conditions. High wind energy penetration rates lead to losses due to power plant operation adjustments to wind energy. This research identifies the potential energetic benefits of integrated hydrogen production in electricity systems with high wind energy penetration. This research concludes that the use of system losses for hydrogen production via electrolysis is beneficial in situations with ca. 8 GW or more wind energy capacity in the Netherlands. The 2020 Dutch policy goal of 6 GW will not benefit from hydrogen production in terms of systems efficiency. An ancillary beneficial effect of coupling hydrogen production with wind energy is to relieve the high-voltage grid. (c) 2007 Elsevier Ltd. All rights reserved

Biobased Chemicals in a Carbon-Restricted World

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