454 research outputs found

    A World of Fields

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    Trope ontology is exposed and confronted with the question where one trope ends and another begins. It is argued that tropes do not have determinate boundaries, it is arbitrary how tropes are carved up. An ontology, which I call field ontology, is proposed which takes this into account. The material world consists of a certain number of fields, each of which is extended over all of space. It is shown how field ontology can also tackle the problem of determin-able properties and the problem of completeness of things

    Quasiparticle Corrections to the Electronic Properties of Anion Vacancies at GaAs(110) and InP(110)

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    We propose a new method for calculating optical defect levels and thermodynamic charge-transition levels of point defects in semiconductors, which includes quasiparticle corrections to the Kohn-Sham eigenvalues of density-functional theory. Its applicability is demonstrated for anion vacancies at the (110) surfaces of III-V semiconductors. We find the (+/0) charge-transition level to be 0.49 eV above the surface valence-band maximum for GaAs(110) and 0.82 eV for InP(110). The results show a clear improvement over the local-density approximation and agree closely with an experimental analysis.Comment: 4 pages including 1 figure, RevTe

    Low-energy electronic properties of clean CaRuO3_3: elusive Landau quasiparticles

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    We have prepared high-quality epitaxial thin films of CaRuO3_3 with residual resistivity ratios up to 55. Shubnikov-de Haas oscillations in the magnetoresistance and a T2T^2 temperature dependence in the electrical resistivity only below 1.5 K, whose coefficient is substantially suppressed in large magnetic fields, establish CaRuO3_3 as a Fermi liquid (FL) with anomalously low coherence scale. Non-Fermi liquid (NFL) T3/2T^{3/2} dependence is found between 2 and 25 K. The high sample quality allows access to the intrinsic electronic properties via THz spectroscopy. For frequencies below 0.6 THz, the conductivity is Drude-like and can be modeled by FL concepts, while for higher frequencies non-Drude behavior, inconsistent with FL predictions, is found. This establishes CaRuO3_3 as a prime example of optical NFL behavior in the THz range.Comment: 12 pages, 21 figures including supplemental materia

    Quantum Monte Carlo calculations of H2_2 dissociation on Si(001)

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    We present quantum Monte Carlo calculations for various reaction pathways of H2_2 with Si(001), using large model clusters of the surface. We obtain reaction energies and energy barriers noticeably higher than those from approximate exchange-correlation functionals. In improvement over previous studies, our adsorption barriers closely agree with experimental data. For desorption, the calculations give barriers for conventional pathways in excess of the presently accepted experimental value, and pinpoint the role of coverage effects and desorption from steps.Comment: 4 pages, 1 figur

    Energiespeicherung in Borosilikatglaesern

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    Symmetric Versus Nonsymmetric Structure of the Phosphorus Vacancy on InP(110)

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    The atomic and electronic structure of positively charged P vacancies on InP(110) surfaces is determined by combining scanning tunneling microscopy, photoelectron spectroscopy, and density-functional theory calculations. The vacancy exhibits a nonsymmetric rebonded atomic configuration with a charge transfer level 0.75+-0.1 eV above the valence band maximum. The scanning tunneling microscopy (STM) images show only a time average of two degenerate geometries, due to a thermal flip motion between the mirror configurations. This leads to an apparently symmetric STM image, although the ground state atomic structure is nonsymmetric.Comment: 5 pages including 3 figures. related publications can be found at http://www.fhi-berlin.mpg.de/th/paper.htm
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