2,872 research outputs found
The Dynamic Transition of Protein Hydration Water
Thin layers of water on biomolecular and other nanostructured surfaces can be
supercooled to temperatures not accessible with bulk water. Chen et al. [PNAS
103, 9012 (2006)] suggested that anomalies near 220 K observed by quasi-elastic
neutron scattering can be explained by a hidden critical point of bulk water.
Based on more sensitive measurements of water on perdeuterated phycocyanin,
using the new neutron backscattering spectrometer SPHERES, and an improved data
analysis, we present results that show no sign of such a fragile-to-strong
transition. The inflection of the elastic intensity at 220 K has a dynamic
origin that is compatible with a calorimetric glass transition at 170 K. The
temperature dependence of the relaxation times is highly sensitive to data
evaluation; it can be brought into perfect agreement with the results of other
techniques, without any anomaly.Comment: 4 pages, 3 figures. Phys. Rev. Lett. (in press
PHOTOCHEMICAL RING-OPENING IN meso-CHLORINATED CHLOROPHYLLS
Irradiation of 20-chloro-chlorophylls of the a-type with visible light produces long-wavelength shifted photoproducts, which transform in the dark to linear tetrapyrroles (bile pigments). The possible significance for chlorophyll degradation is discussed
Short to long-range charge-transfer excitations in the zincbacteriochlorin-bacteriochlorin complex: a Bethe-Salpeter study
We study using the Bethe-Salpeter formalism the excitation energies of the
zincbacteriochlorinbacteriochlorin dyad, a paradigmatic photosynthetic complex.
In great contrast with standard timedependent density functional theory
calculations with (semi)local kernels, charge transfer excitations are
correctly located above the intramolecular Q-bands transitions found to be in
excellent agreement with experiment. Further, the asymptotic Coulomb behavior
towards the true quasiparticle gap for charge transfer excitations at long
distance is correctly reproduced, showing that the present scheme allows to
study with the same accuracy intramolecular and charge transfer excitations at
various spatial range and screening environment without any adjustable
parameter.Comment: 5 pages, 2 figures, 1 tabl
Conduction Channels of One-Atom Zinc Contacts
We have determined the transmission coefficients of atomic-sized Zn contacts
using a new type of breakjunction which contains a whisker as a central bridge.
We find that in the last conductance plateau the transport is unexpectedly
dominated by a well-transmitting single conduction channel. We explain the
experimental findings with the help of a tight-binding model which shows that
in an one-atom Zn contact the current proceeds through the 4s and 4p orbitals
of the central atom.Comment: revtex4, 5 pages, 5 figure
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