XPS and in-situ IR investigation of Ru/Si02 catalyst

Cataloged from PDF version of article.Ru(NO)(N0&/Si02 catalyst precursors were characterized via XPS and in-situ reflectance IR spectroscopy before, during and after reduction by hydrogen over the temperature range 300-800 K. IR results indicated that the catalyst precursor lost NO3 groups first, with subsequent loss of NO both in a reducing atmosphere and during thermal annealing. XPS was used to derive information on the oxidation state of Ru in the various steps of the annealing and/or reduction processes. 0 1997 Elsevier Science B.V

XPS investigation of thin SiOx and SiOxNy overlayers

Cataloged from PDF version of article.Angle-resolved XPS is used to determine the thickness and the uniformity of the chemical composition with respect to oxygen and nitrogen of the very thin silicon oxide and oxynitride overlayers grown on silicon. (C) 1999 Elsevier Science B.V. All rights reserved

FTIR characterization of Ru/SiO2 catalyst for ammonia synthesis

Cataloged from PDF version of article.Carbon monoxide adsorption on a Ru/SiO2 catalyst was followed by IR spectroscopy to investigate the active sites. Using this catalyst, ammonia synthesis was achieved at 3508C in an N2/H2 gas mixture (N2/H2 < 3 : 1) for different reaction times. In addition to NH3 other NHx (x 1,2) species were also observed. CO adsorption after NH3 production was also performed to investigate the change in nature of the active sites. Based on the experimental evidence participation of Ru0 sites in ammonia synthesis was confirmed and a partial oxidation of the reduced Ru sites during the synthesis was observed. q 1999 Elsevier Science B.V. All rights reserved

Non-fouling flow reactors for nanomaterial synthesis

This review provides a holistic description of flow reactor fouling for wet-chemical nanomaterial syntheses. Fouling origins and consequences are discussed together with the variety of flow reactors for its prevention

Gravitational lensing in braneworld gravity: formalism and applications

In this article, we develop a formalism which is different from the standard lensing scenario and is necessary for understanding lensing by gravitational fields which arise as solutions of the effective Einstein equations on the brane. We obtain general expressions for measurable quantities such as time delay, deflection angle, Einstein ring and magnification. Subsequently, we estimate the deviations (relative to the standard lensing scenario) in the abovementioned quantities by considering the line elements for clusters and spiral galaxies obtained by solving the effective Einstein equations on the brane. Our analysis reveals that gravitational lensing can be a useful tool for testing braneworld gravity as well as the existence of extra dimensions.Comment: 20 pages, 1 figure, 2 tables. Accepted for publication in Classical and Quantum Gravit

Scalar kinks and fermion localisation in warped spacetimes

Scalar kinks propagating along the bulk in warped spacetimes provide a thick brane realisation of the braneworld. We consider here, a class of such exact solutions of the full Einstein-scalar system with a sine-Gordon potential and a negative cosmological constant. In the background of the kink and the corresponding warped geometry, we discuss the issue of localisation of spin half fermions (with emphasis on massive ones) on the brane in the presence of different types of kink-fermion Yukawa couplings. We analyse the possibility of quasi-bound states for large values of the Yukawa coupling parameter $\gamma_F$ (with $\nu$, the warp factor parameter kept fixed) using appropriate, recently developed, approximation methods. In particular, the spectrum of the low--lying states and their lifetimes are obtained, with the latter being exponentially enhanced for large $\nu \gamma_F$. Our results indicate quantitatively, within this model, that it is possible to tune the nature of warping and the strength and form of the Yukawa interaction to obtain trapped massive fermion states on the brane, which, however, do have a finite (but very small) probability of escaping into the bulk.Comment: 22 pages, 4 figures, RevTex

de Sitter branes with a bulk scalar

We propose new braneworld models arising from a scalar field in the bulk. In these examples, the induced on--brane line element is de Sitter (or anti de Sitter) and the bulk (five dimensional) Einstein equations can be exactly solved to obtain warped spacetimes. The solutions thus derived are single and two-brane models -- one with {\em thin} branes while the other one of the {\em thick} variety. The field profiles and the potentials are obtained and analysed for each case. We note that for the {\em thick} brane scenario the field profile resembles a kink, whereas for one or more {\em thin} branes, it is finite and bounded in the domain of the extra dimension. We have also addressed the localisation of gravity and other matter fields on the brane for these braneworld models.Comment: 18 pages, 5 figures. Substantial changes and new results. To appear in GR

Gene Expression Programs of Human Smooth Muscle Cells: Tissue-Specific Differentiation and Prognostic Significance in Breast Cancers

Smooth muscle is present in a wide variety of anatomical locations, such as blood vessels, various visceral organs, and hair follicles. Contraction of smooth muscle is central to functions as diverse as peristalsis, urination, respiration, and the maintenance of vascular tone. Despite the varied physiological roles of smooth muscle cells (SMCs), we possess only a limited knowledge of the heterogeneity underlying their functional and anatomic specializations. As a step toward understanding the intrinsic differences between SMCs from different anatomical locations, we used DNA microarrays to profile global gene expression patterns in 36 SMC samples from various tissues after propagation under defined conditions in cell culture. Significant variations were found between the cells isolated from blood vessels, bronchi, and visceral organs. Furthermore, pervasive differences were noted within the visceral organ subgroups that appear to reflect the distinct molecular pathways essential for organogenesis as well as those involved in organ-specific contractile and physiological properties. Finally, we sought to understand how this diversity may contribute to SMC-involving pathology. We found that a gene expression signature of the responses of vascular SMCs to serum exposure is associated with a significantly poorer prognosis in human cancers, potentially linking vascular injury response to tumor progression

Quasinormal modes for tensor and vector type perturbation of Gauss Bonnet black holes using third order WKB approach

We obtain the quasinormal modes for tensor perturbations of Gauss-Bonnet (GB) black holes in $d=5, 7, 8$ dimensions and vector perturbations in $d = 5, 6, 7$ and 8 dimensions using third order WKB formalism. The tensor perturbation for black holes in $d=6$ is not considered because of the fact that it is unstable to tensor mode perturbations. In the case of uncharged GB black hole, for both tensor and vector perturbations, the real part of the QN frequency increases as the Gauss-Bonnet coupling ($\alpha'$) increases. The imaginary part first decreases upto a certain value of $\alpha'$ and then increases with $\alpha'$ for both tensor and vector perturbations. For larger values of $\alpha'$, the QN frequencies for vector perturbation differs slightly from the QN frequencies for tensorial one. It has also been shown that as $\alpha' \to 0$, the quasinormal mode frequency for tensor and vector perturbation of the Schwarzschild black hole can be obtained. We have also calculated the quasinormal spectrum of the charged GB black hole for tensor perturbations. Here we have found that the real oscillation frequency increases, while the imaginary part of the frequency falls with the increase of the charge. We also show that the quasinormal frequencies for scalar field perturbations and the tensor gravitational perturbations do not match as was claimed in the literature. The difference in the result increases if we increase the GB coupling.Comment: 17 pages, 11 figures, change in title and abstract, new equations and results added for QN frequencies for vector perturbations, new referencees adde