1,858 research outputs found
Anisotropic Local Stress and Particle Hopping in a Deeply Supercooled Liquid
The origin of the microscopic motions that lead to stress relaxation in
deeply supercooled liquid remains unclear. We show that in such a liquid the
stress relaxation is locally anisotropic which can serve as the driving force
for the hopping of the system on its free energy surface. However, not all
hopping are equally effective in relaxing the local stress, suggesting that
diffusion can decouple from viscosity even at local level. On the other hand,
orientational relaxation is found to be always coupled to stress relaxation.Comment: 4 pages, 3 figure
Superconductivity in Ru substituted BaFe2-xRuxAs2
The occurrence of bulk superconductivity at ~22 K is reported in
polycrystalline samples of BaFe2-xRuxAs2 for nominal Ru content in the range of
x=0.75 to 1.125. A systematic suppression of the spin density wave transition
temperature (TSDW) precedes the appearance of superconductivity in the system.
A phase diagram is proposed based on the measured TSDW and superconducting
transition temperature (TC) variations as a function of Ru composition. Band
structure calculations, indicate introduction of electron carriers in the
system upon Ru substitutiom. The calculated magnetic moment on Fe shows a
minimum at x=1.0, suggesting that the suppression of the magnetic moment is
associated with the emergence of superconductivity. Results of low temperature
and high field Mossbauer measurements are presented. These indicate weakening
of magnetic interaction with Ru substitutionComment: 20 pages 10 figure
Potential Energy Landscape Equation of State
Depth, number, and shape of the basins of the potential energy landscape are
the key ingredients of the inherent structure thermodynamic formalism
introduced by Stillinger and Weber [F. H. Stillinger and T. A. Weber, Phys.
Rev. A 25, 978 (1982)]. Within this formalism, an equation of state based only
on the volume dependence of these landscape properties is derived. Vibrational
and configurational contributions to pressure are sorted out in a transparent
way. Predictions are successfully compared with data from extensive molecular
dynamics simulations of a simple model for the fragile liquid orthoterphenyl.Comment: RevTeX4, 4 pages, 5 figure
Energy landscape of a Lennard-Jones liquid: Statistics of stationary points
Molecular dynamics simulations are used to generate an ensemble of saddles of
the potential energy of a Lennard-Jones liquid. Classifying all extrema by
their potential energy u and number of unstable directions k, a well defined
relation k(u) is revealed. The degree of instability of typical stationary
points vanishes at a threshold potential energy, which lies above the energy of
the lowest glassy minima of the system. The energies of the inherent states, as
obtained by the Stillinger-Weber method, approach the threshold energy at a
temperature close to the mode-coupling transition temperature Tc.Comment: 4 RevTeX pages, 6 eps figures. Revised versio
The effect of translational and rotational relative velocity components on fluid-to-particle heat transfer coefficients in continuous tube flow
A liquid crystal technique was used to determine average fluid-to-particle heat transfer coefficients (hfp) for single spherical hollow aluminium particles heating in carboxymethylcellulose solutions in continuous tube flow. The particles' linear and rotational velocities were also measured by videotaping the particle motion at a bottom position. Particles with different diameter and density were used in solutions with different viscosities and at different flow rates (7 < Reynolds < 284; 144 < Prandtl < 1755). The values of the average heat transfer coefficient were between 334 and 1497 W/m2C. The results showed that both the relative fluid-to-particle velocity and the particle rotational velocity influence the heat transfer coefficients, although it is not possible to individualize their effects. However, the addition of the individual effects, predicted by using published dimensionless correlations, yielded a good fit with the experimental values
Liquid Limits: The Glass Transition and Liquid-Gas Spinodal Boundaries of Metastable Liquids
The liquid-gas spinodal and the glass transition define ultimate boundaries
beyond which substances cannot exist as (stable or metastable) liquids. The
relation between these limits is analyzed {\it via} computer simulations of a
model liquid. The results obtained indicate that the liquid - gas spinodal and
the glass transition lines intersect at a finite temperature, implying a glass
- gas mechanical instability locus at low temperatures. The glass transition
lines obtained by thermodynamic and dynamic criteria agree very well with each
other.Comment: 5 pages, 4 figures, to appear in Phys. Rev. Let
Stability, Gain, and Robustness in Quantum Feedback Networks
This paper concerns the problem of stability for quantum feedback networks.
We demonstrate in the context of quantum optics how stability of quantum
feedback networks can be guaranteed using only simple gain inequalities for
network components and algebraic relationships determined by the network.
Quantum feedback networks are shown to be stable if the loop gain is less than
one-this is an extension of the famous small gain theorem of classical control
theory. We illustrate the simplicity and power of the small gain approach with
applications to important problems of robust stability and robust
stabilization.Comment: 16 page
Blue luminescence of Au nanoclusters embedded in silica matrix
Photoluminescence study using the 325 nm He-Cd excitation is reported for the
Au nanoclusters embedded in SiO2 matrix. Au clusters are grown by ion beam
mixing with 100 KeV Ar+ irradiation on Au [40 nm]/SiO2 at various fluences and
subsequent annealing at high temperature. The blue bands above ~3 eV match
closely with reported values for colloidal Au nanoclusters and supported Au
nanoislands. Radiative recombination of sp electrons above Fermi level to
occupied d-band holes are assigned for observed luminescence peaks. Peaks at
3.1 eV and 3.4 eV are correlated to energy gaps at the X- and L-symmetry
points, respectively, with possible involvement of relaxation mechanism. The
blue shift of peak positions at 3.4 eV with decreasing cluster size is reported
to be due to the compressive strain in small clusters. A first principle
calculation based on density functional theory using the full potential linear
augmented plane wave plus local orbitals (FP-LAPW+LO) formalism with
generalized gradient approximation (GGA) for the exchange correlation energy is
used to estimate the band gaps at the X- and L-symmetry points by calculating
the band structures and joint density of states (JDOS) for different strain
values in order to explain the blueshift of ~0.1 eV with decreasing cluster
size around L-symmetry point.Comment: 13 pages, 7 Figures Only in PDF format; To be published in J. of
Chem. Phys. (Tentative issue of publication 8th December 2004
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