Fuel characteristics of rehabilitated bauxite mines in Western Australia

This investigation assessed the fuel characteristics of Alcoa of Australia\u27s rehabilitated bauxite mines in the south-west of Western Australia. The study determined the fuel loads, their composition and structure. The characteristics of fuel were determined, their relationship with time ascertained, and the similarity of these characteristics to the jarrah forest ecosystems that they have replaced was discussed. Pits aged from four to twenty years since rehabilitation were assessed. Predictive models were developed to allow the rapid assessment of fuel. The fuel characteristics in two controlled bum areas were also assessed to how much fuel would burn in a fire and what factors were effecting this consumption. Fuel quantities increased with age since rehabilitation from 7.19t/ha in a 5 year-old pit to 68.23t/ha in a 17 year-old pit. This is up 6 times higher than the maximum levels suggested for the surrounding jarrah forest. The distribution of fuels was very heterogeneous in nearly all sites. It was much more variable than in the surrounding jarrah forest. For example, fuel loads sampled in a 15 year old site, ranged from approximately 20t/ha to 120t/ha. This uneven fuel distribution will influence fire behaviour and intensity during controlled bums. Measurement of fuel consumption showed that a spring burn of moderate to high intensity consumed more fuel than an autumn burn of lower intensity. The higher moisture content of the autumn burn area contributed to the lower consumption of fuel as moisture inhibits combustion. More than 88% of standing fuel was consumed in the bums. Research data suggests that fire is carried in this standing fuel component. This differs from the jarrah forest where fire is carried in the litter layer. This implies that measurements of moisture content in soils and litter, which are used in other models to predict fire behaviour, would be of limited use in the rehabilitation areas under 15 years of age which have a significant proportion of standing fuel. Although many other factors need to be considered in relation to the controlled burning of rehabilitated areas, the findings of this study have important implications. The fuel characteristics in 4 to 20 year-old rehabilitated areas are different to the jarrah forest ecosystem that they have replaced. At this stage the areas need to be treated differently in the development of a fire management programme

Chemical underpinning of the tea bag index: An examination of the decomposition of tea leaves

Decomposition is a key flux of terrestrial carbon to the atmosphere. Therefore, gaining a better understanding of how plant litter decomposes in soil, and what governs this process, is vital for global climate models. The Tea Bag Index (TBI) was introduced by Keuskamp et al. (2013) as a novel method for measuring litter decomposition rate and stabilisation. The TBI uses two types of tea bags representing fast (green tea) and slow (rooibos tea) decomposition substrates as standardised litter bags. To date, the TBI method has been used in over 2000 locations across the globe. However, before now, there has been no information on how the composition of the tea leaves change during incubation. These data are crucial in determining the validity of the use of the TBI method globally, to ensure the tea leaves decompose in a way that is representative of so-called “native” litters. To provide chemical underpinning of the TBI method, a laboratory incubation of the tea bags was conducted with destructive sampling at 0, 7, 14, 21, 28, 35, 42, 49, 56, 63, 70, 77, 84, and 91 d. The incubated tea was analysed for total C and N. In addition, C was characterised as alkyl, O-alkyl, aromatic, or carbonyl C using solid-state 13C nuclear magnetic resonance spectroscopy with cross-polarization and magic angle spinning (CPMAS NMR). The results suggest that changes in carbon in both tea types are comparable to other litter studies, with a net decrease in total C and relative proportion of O-alkyl C fraction, which contains carbohydrates and cellulose. We conclude that the decomposition of tea leaves in the bags used in the TBI is representative of other litters

Horizontal and radial collector wells: simple tools for a complex problem

The capture of groundwater by horizontal wells (HWs) is an old but often overlooked technique. Practically all modeling techniques available in groundwater hydrology have been applied to HWs. This work compares analytical models with field data and investigates the influence of nonuniform screen inflow. The usefulness of a vertical well approximation is studied. A new MATLAB application, HORI, is presented for common analytical models. Analytical methods are found to reproduce drawdown around two radial collector wells (RCWs). Beyond the direct vicinity of the caisson, in particular, drawdown around an RCW can be approximated with a vertical well model

The Properties of Brightest Cluster Galaxies in X-Ray Selected Clusters

We present the K-band Hubble diagram for 162 brightest cluster galaxies (BCGs) in X-ray selected clusters, 0.01<z<0.83. The sample incorporates that of Burke, Collins, & Mann (2000) and includes additional infrared data from the 2MASS extended source catalogue. We show that below z=0.1 the BCGs show no correlation with their environment, however, above z=0.1 BCGs in more X-ray luminous clusters are more uniform in their photometric properties. This suggests that there may be two populations of BCGs which have different evolutionary histories.Comment: 2 pages, to appear in the proceedings of the Sesto 2001 conference on tracing cosmic evolution with galaxy cluster

Conditional expression in corticothalamic efferents reveals a developmental role for nicotinic acetylcholine receptors in modulation of passive avoidance behavior

Prenatal nicotine exposure has been linked to attention deficit hyperactivity disorder and cognitive impairment, but the sites of action for these effects of nicotine are still under investigation. High-affinity nicotinic acetylcholine receptors (nAChRs) contain the .2 subunit and modulate passive avoidance (PA) learning in mice. Using an inducible, tetracycline-regulated transgenic system, we generated lines of mice with expression of high-affinity nicotinic receptors restored in specific neuronal populations. One line of mice shows functional .2 subunit-containing nAChRs localized exclusively in corticothalamic efferents. Functional, presynaptic nAChRs are present in the thalamus of these mice as detected by nicotine-elicited rubidium efflux assays from synaptosomes. Knock-out mice lacking high-affinity nAChRs show elevated baseline PA learning, whereas normal baseline PA behavior is restored in mice with corticothalamic expression of these nAChRs. In contrast, nicotine can enhance PA learning in adult wild-type animals but not in corticothalamic-expressing transgenic mice. When these transgenic mice are treated with doxycycline in adulthood to switch off nAChR expression, baseline PA is maintained even after transgene expression is abolished. These data suggest that high-affinity nAChRs expressed on corticothalamic neurons during development are critical for baseline PA performance and provide a potential neuroanatomical substrate for changes induced by prenatal nicotine exposure leading to long-term behavioral and cognitive deficits

A comparison of physical soil organic matter fractionation methods for amended soils

Selecting a suitable physical fractionation method, to investigate soil organic matter dynamics, from the plethora that are available is a difficult task. Using five different physical fractionation methods, on soils either nontreated or with a history of amendment with a range of exogenous organic matter inputs (Irish moss peat; composted horse manure; garden compost) and a resulting range of carbon contents (6.8 to 22.2%), we show that method selection had a significant impact on both the total C recovered and the distribution of the recovered C between unprotected, physically protected, or chemically protected conceptual pools. These between-method differences most likely resulted from the following: (i) variation in the methodological fractions obtained (i.e., distinguishing between aggregate size classes); (ii) their subsequent designation to conceptual pools (e.g., protected versus unprotected); and (iii) the procedures used in sample pretreatment and subsequent aggregate dispersion and fractionation steps. The performance of each method also varied depending on the amendment in question. The findings emphasise the need for an understanding of the nature of the soil samples under investigation, and the stabilisation mechanism of interest, both prior to method selection and when comparing and interpreting findings from literature studies using different fractionation methods

Scratching the surface: the use of sheepskin parchment to deter textual erasure in early modern legal deeds.

UNLABELLED: Historic legal deeds are one of the most abundant resources in British archives, but also one of the most neglected. Despite the millions that survive, we know remarkably little about their manufacture, including the species of animal on which they were written. Here we present the species identification of 645 sixteenth-twentieth century skins via peptide mass fingerprinting (ZooMS), demonstrating the preferential use of sheepskin parchment. We argue that alongside their abundance and low cost, the use of sheepskins over those of other species was motivated by the increased visibility of fraudulent text erasure and modification afforded by the unique structure of their skin. SUPPLEMENTARY INFORMATION: The online version contains supplementary material available at 10.1186/s40494-021-00503-6

Girding the loins? Direct evidence of the use of a medieval English parchment birthing girdle from biomolecular analysis

In this paper, we describe palaeoproteomic evidence obtained from a stained medieval birth girdle using a previously developed dry non-invasive sampling technique. The parchment birth girdle studied (Wellcome Collection Western MS. 632) was made in England in the late fifteenth century and was thought to be used by pregnant women while giving birth. We were able to extract both human and non-human peptides from the manuscript, including evidence for the use of honey, cereals, ovicaprine milk and legumes. In addition, a large number of human peptides were detected on the birth roll, many of which are found in cervico-vaginal fluid. This suggests that the birth roll was actively used during childbirth. This study is, to our knowledge, the first to extract and analyse non-collagenous peptides from a birth girdle using this sampling method and demonstrates the potential of this type of analysis for stained manuscripts, providing direct biomolecular evidence for active use

Application of a Hybrid Statistical–Dynamical System to Seasonal Prediction of North American Temperature and Precipitation

Recent research demonstrates that dynamical models sometimes fail to represent observed teleconnection patterns associated with predictable modes of climate variability. As a result, model forecast skill may be reduced. We address this gap in skill through the application of a Bayesian postprocessing technique—the calibration, bridging, and merging (CBaM) method—which previously has been shown to improve probabilistic seasonal forecast skill over Australia. Calibration models developed from dynamical model reforecasts and observations are employed to statistically correct dynamical model forecasts. Bridging models use dynamical model forecasts of relevant climate modes (e.g., ENSO) as predictors of remote temperature and precipitation. Bridging and calibration models are first developed separately using Bayesian joint probability modeling and then merged using Bayesian model averaging to yield an optimal forecast. We apply CBaM to seasonal forecasts of North American 2-m temperature and precipitation from the North American Multimodel Ensemble (NMME) hindcast. Bridging is done using the model-predicted Niño-3.4 index. Overall, the fully merged CBaM forecasts achieve higher Brier skill scores and better reliability compared to raw NMME forecasts. Bridging enhances forecast skill for individual NMME member model forecasts of temperature, but does not result in significant improvements in precipitation forecast skill, possibly because the models of the NMME better represent the ENSO–precipitation teleconnection pattern compared to the ENSO– temperature pattern. These results demonstrate the potential utility of the CBaM method to improve seasonal forecast skill over North America

Metallogenic Setting and Temporal Evolution of Porphyry Cu-Mo Mineralization and Alteration in the Delamerian Orogen, South Australia: Insights From Zircon U-Pb, Molybdenite Re-Os, and In Situ White Mica Rb-Sr Geochronology

Paleozoic porphyry-style hydrothermal alteration and mineralization has previously been recognized within the Delamerian orogen, South Australia, where porphyry prospects include Anabama Hill, Netley Hill, and Bendigo. However, limited exploration due in part to thick postmineralization cover hinders the understanding of the temporal context, metallogenic setting, and mineral potential of the porphyry systems along the Proterozoic continental margin of Australia. In this study, we have characterized the hydrothermal alteration and mineralization of these porphyry occurrences. Zircon U-Pb, molybdenite Re-Os, and white mica Rb-Sr ages have been determined to constrain the timing for emplacement of magmatic intrusions, precipitation of metal-bearing sulfides, and duration of hydrothermal alteration in the Delamerian orogenic belt. Zircon U-Pb laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) analyses of nine granitoids reveal that the intrusive rocks were emplaced mostly between 485 and 465 Ma, whereas three intrusions at Bendigo have zircon U-Pb ages of 490 to 480 Ma. Molybdenite isotope dilution-negative thermal ion mass spectrometry (ID-NTIMS) Re-Os dating of the four prospects identifies two porphyry Cu-Mo mineralization events at 480 and 470 to 460 Ma, respectively. Nineteen white mica Rb-Sr LA-ICP-MS/MS (tandem mass spectrometers) analyses return an age range between 455 and 435 Ma for phyllic alteration at the Anabama Hill and Netley Hill prospects, whereas intense white mica-quartz-pyrite alteration at Bendigo prospect appears to have developed between 470 and 460 Ma. These geochronologic results indicate that the Delamerian porphyry systems postdated subduction-related magmatism in the region (514–490 Ma) but instead formed within an inverted back-arc regime, where mineralized magmas and fluids ascended along favorable lithospheric-scale structures, probably due to asthenospheric upwelling triggered by mafic delamination. Porphyritic stocks, dikes, and aplites with ages of 470 to 460 Ma are the most likely hosts to porphyry-style mineralization in the Delamerian orogen that appears to have formed simultaneously with the oldest known porphyry systems in the intraoceanic Macquarie arc (e.g., Marsden, E43, and Milly Milly; 467–455 Ma). These results emphasize the significance and potential of Early-Middle Ordovician intrusive systems to host such a type of magmatic-hydrothermal mineralization in the Delamerian orogen