Diversité De La Macrofaune Du Sol Dans Les Parcelles De Reboisement De La Grande Muraille Verte Au Sénégal

Objective: To assess the effect of vegetation cover on soil macrofauna, a study focused on the diversity of soil macrofauna inside and outside reforestation plots of the Great Green Wall in Senegal was carried out. Methodology: The sampling of macrofauna was performed according to the method recommended by the TSBF network (Tropical Soil Biology and Fertility). It involves isolating 10 ground plots along a transect of 50 meters chosen at random in each plot and outside of each plot. The macrofauna was sampled between February and July 2016 during the dry season Results: The results show, in order of importance Hymenoptera, Isoptera, Coleoptera, the Spiders, the isopods and springtails are the taxonomic groups of the study area. The density of each of these taxa is larger inside and outside of the plots. The vertical distribution of macrofauna shows that the 0-10 cm layer is more densely populated than the deeper layers. Conclusion: This study showed a low diversity of soil macrofauna in the area. It also shows that the vegetation cover affects the density of the macrofauna

Gestational diabetes and endothelial function: impact of gestational insulin resistance on reactive hyperhemia index

Our aim was to characterize endothelial function in gestational diabetes by evaluating the reactive hyperemia index (RHI, LnRHI). A prospective, descriptive and comparative study was conducted on a population of pregnant women aged over 20 and under 36, located in the gestational age group 24-38th week of amenorrhea. They were divided into two groups. Group 1 (G1): group of pregnancies without diabetes, consists of pregnant women with no risk factor for gestational diabetes and with normal fasting blood glucose. Group 2 (G2): group of pregnancies with diabetes, includes pregnancies whose oral glucose tolerance tests (OGTT) came back positive. Anthropo-physiological parameters (age, weight, height, blood pressure (PA) and biochemical parameters (glycemia, insulinemia, HOMA-IR, cholesterol, triglycerides) were measured. RHI and LnRHI were determined at Endopat 2000. The two groups were matched for age, weight, heart rate (HR) and blood pressure (BP). Levels of glucose (G1:0.76±0.11; G2:1.11±0.11; p˂0.0001), insulin (G1:7.67±4.35; G2:22.9±3.75; p˂0.0001), HOMA-IR (G1:1.51±0.97; G2:6.29±1.23; p˂0.0001), total cholesterol (G1:1±0.81; G2:2.49±0.74; p=0.002), HDL cholesterol (G1:0.45±0.23; G2: 0.8±0.19; p=0.004, LDL cholesterol (G1:0.42±0.54; G2:1.39±0.6; p=0.004), triglycerides (G1:0.65±0.49; G2:1.48±0.27; p=0.0018), were significantly higher in the diabetic group. Both RHI and LnRHI were negatively correlated with HOMA-IR (respectively, r=-0.8931, p<0.0001; r=-0.8938; p<0.0001). HOMA-IR index was independently associated with levels of RHI and LnRHI (respectively r²=0.797; p<0.0001); (r²=0.804; p<0.0001)). Thus, gestational insulin resistance would be associated with a change in endothelial function such as a decrease in endothelium-dependent vasodilatation reflecting endothelial dysfunction, hence an increase in cardiovascular risk

NEW TRANSITION METAL OXALATO COMPLEXES WITH DABCOH22+ AS ADVERSE CATION: SYNTHESIS AND INFRARED STUDY

On allowing DABCOH2(HC2O4)2 to react with transition metal dihalides in ethanol, a new series of complexes of general formula M(oxalate)2 DABCOH22+. nDABCOH22+.2X- (n=1/2;1) have been obtained. When (n=1) a dimeric structure is suggested, the two monomeric species being hold together by biprotonated DABCO through N-H…O hydrogen bonds. In the case of the complex M(oxalate)2DABCOH22+ .1/2 DABCOH22+.2X- -M = Ni, Cu- the structure is an infinite chain. The environment around the metallic centers is octahedral or square pyramidal. The oxalate behaves as a monochelating and hydrogen bonds involved ligand or is only concerned by hydrogen bonds

NEW TRANSITION METAL OXALATO COMPLEXES WITH DABCOH22+ AS ADVERSE CATION: SYNTHESIS AND INFRARED STUDY

On allowing DABCOH2(HC2O4)2 to react with transition metal dihalides in ethanol, a new series of complexes of general formula M(oxalate)2 DABCOH22+. nDABCOH22+.2X- (n=1/2;1) have been obtained. When (n=1) a dimeric structure is suggested, the two monomeric species being hold together by biprotonated DABCO through N-H…O hydrogen bonds. In the case of the complex M(oxalate)2DABCOH22+ .1/2 DABCOH22+.2X- -M = Ni, Cu- the structure is an infinite chain. The environment around the metallic centers is octahedral or square pyramidal. The oxalate behaves as a monochelating and hydrogen bonds involved ligand or is only concerned by hydrogen bonds

Cardiopulmonary Response to Exercise in COPD and Overweight Patients: Relationship between Unloaded Cycling and Maximal Oxygen Uptake Profiles

Cardiopulmonary response to unloaded cycling may be related to higher workloads. This was assessed in male subjects: 18 healthy sedentary subjects (controls), 14 hypoxemic patients with chronic obstructive pulmonary disease (COPD), and 31 overweight individuals (twelve were hypoxemic). They underwent an incremental exercise up to the maximal oxygen uptake (VO 2 max), preceded by a 2 min unloaded cycling period. Oxygen uptake (VO 2 ), heart rate (HR), minute ventilation (VE), and respiratory frequency (fR) were averaged every 10 s. At the end of unloaded cycling period, HR increase was significantly accentuated in COPD and hypoxemic overweight subjects (resp., +14 ± 2 and +13 ± 1.5 min −1 , compared to +7.5 ± 1.5 min −1 in normoxemic overweight subjects and +8 ± 1.8 min −1 in controls). The fR increase was accentuated in all overweight subjects (hypoxemic: +4.5 ± 0.8; normoxemic: +3.9 ± 0.7 min −1 ) compared to controls (+2.5 ± 0.8 min −1 ) and COPDs (+2.0 ± 0.7 min −1 ). The plateau VE increase during unloaded cycling was positively correlated with VE values measured at the ventilatory threshold and VO 2 max. Measurement of ventilation during unloaded cycling may serve to predict the ventilatory performance of COPD patients and overweight subjects during an exercise rehabilitation program

The synthesis and the reactivity of arene ruthenium oxalato complexes

This article outlines the reactions of the well known [RuCl(&#951;6-p-cymene)]2(&#956;-&#951;4-C2O4) and [RuCl(&#951;6-p-cymene)(&#951;2-dppm)][PF6] ruthenium complexes with C2O4(Me4N)2 in the mol ratios 1:1 and 2:1. While the 2:1 ratio reaction led to the sole and expected binuclear product {[Ru(&#951;6-p-cymene)(&#951;2-dppm)]2(&#956;-&#951;2-C2O4)}[PF6]2, the reaction also afforded the unexpected mononuclear complex [RuCl(&#951;2-C2O4)(&#951;6-p-cymene)][Me4N]. This can also be obtained in improved yield by reacting [RuCl2(p-cymene)]2 with C2O4[Me4N]2 in a 1:1 mol ratio. Surprisingly, when [RuCl(&#951;6-p-cymene)]2(&#956;-&#951;4-C2O4) was reacted with an equimolar amount of the ligand dppm, the expected complex {[Ru(&#951;6-p-cymene)]2(&#956;-&#951;4-C2O4)(&#956;-dppm)}[PF6]2 was accompanied by [RuCl(&#951;6-p-cymene)(&#951;2-dppm)][PF6] in an inseparable solid mixture.&#160;KEY WORDS: Ruthenium, Arene, p-cymene, Mesitylene, Oxalate, bis-(Dipenylphosphino)methane&#160;&#160;Bull. Chem. Soc. Ethiop. 2008, 22(2), 207-217

Insulin resistance and arterial stiffness: impact of gestational diabetes on pulse wave velocity

Background: Gestational diabetes is an intolerance of glucose with the first appearance during the pregnancy. This hyperglycaemia status, because of the pre-existing insulin-resistance, constitute a favourable land of arterial stiffness. The aim of this study is to determine the impact of non obese gestational diabetes on arterial stiffness by measuring the pulse wave velocity (PWV).Methods: We recruited 60 pregnant women aged from 20 to 35 years old. They were between twentieth four and thirtieth five weeks of gestational age. Subjects were divided into two groups: the first group (G1), considered as control group, included 25 normoglycemic pregnant subjects without any history of illness or risk factors of gestational diabetes; the second group (G2) included 35 women with Gestational Diabetes Mellitus (GDM). All pregnant women had not history of smoking, were not taking decoction or medicine, which could disturb pregnancy evolution. Anthropo-physiological and biochemical parameters studied, were: age, body mass index (BMI), blood pressure (BP), triglyceride, cholesterol and HOMA-IR index. The PWV between finger and toe (PWVft) was measured by pOpmètre®.Results: The two groups are matched by age (G1:28±4ans; G2:29±3ans) and BMI (G1:25.6±1.27; G2:26.9±1.3). Blood pressure (BP) values are in normal interval (systolic BP: [110-132mmHg]; diastolic BP: [63-87mmHg]; mean BP: [79-103mmHg]). Total cholesterol (G1:0.95±0.08;G2:2.4±0.7; p˂0.0001), HDL cholesterol (G1:0.44±0.02; G2:0.76±0.2; p˂0.0001, LDL cholesterol (G1:0.40±0.05; G2:1.3±0.5; p˂0.0001), triglyceride (G1:0.57±0.45; G2:1.6±0.4;p˂0.0001), HOMA.IR (G1:1.31±1.05; G2:7.4±1.07; p˂0.01), PWVft (G1:5.99±1.23; G2:10.3±1.9; p˂0.0001) are significantly higher in diabetic group. PWVft is positively correlate to HOMA-IR index, total cholesterol, LDL cholesterol and triglycerides (r=0.3348, p=0.032; r=0.5275, p˂0.0001; r=0.4855,p˂0.0001; r=0.5581, p˂0.0001respectively).Conclusions: Gestational diabetes might induce an increase of pulse wave velocity expressing increment of arterial stiffness. This last constitute an early underlying cardiovascular risk.

High blood viscosity is associated with high pulse wave velocity in African sickle cell trait carriers

Background: Sickle cell trait (SCT) is the benign condition of sickle cell disease. Often asymptomatic, the SCT carriers have hemorheological disturbances such as blood hyper-viscosity compared to healthy subjects. These disturbances could lead to structural and functional changes in large vessels. The aim of the study was to evaluate the association between blood viscosity (ηb) and pulse wave velocity (PWV) in SCT carriers.Methods: Thirteen SCT with high blood viscosity (SCT_hηb) aged 34±12 years (4 men) were compared to 13 SCT with low blood viscosity (SCT_lηb) aged 32±9 years (5 men) recruited from the National Blood Transfusion Center (CNTS) in Dakar (Senegal). Pulse wave velocity finger-toe (PWVft) was assessed using pOpmètre® (Axelife SAS-France). Cardiovascular risk (CVR) was assessed according to the Framingham Laurier score.Results: SCT_hηb had higher PWVft (m/s) than SCT_lηb respectively 8.98±1.98 and 7.11±1.18 (p = 0.004). CVR score (%) was higher in SCT_hηb than SCT_lηb, but this difference was not statistically significant (5.96±7.45 vs 2.09±2.15; p=0.31). Multivariate linear regression showed a positive correlation between PWVft and ηb and CVR score (r2=0.74, F=21.19, p˂0.001).Conclusions: Present results indicate that the SCT_hηb carriers have arteries stiffer than SCT_lηb and ηb and CVR could remain independent determinants of arterial stiffness in SCT carriers

Etude De La Diversite Des Termites (Isoptera) Dans Quelques Localites De La Region De Kolda (Haute Casamance, Senegal)

Termites (Isoptera) are invertebrates that play many ecological functions in terrestrial ecosystems, especially in tropical areas. Their impacts on the quality and the fertility of the soil are well known. However, in Senegal termite fauna is still poorly known. Thus, to contribute to the knowledge of termites of Senegal we have conducted a study on their diversity in the region of Kolda (Casamance). Termites were sampled in transects of 100 m long and 20 m wide. Termite workers, soldiers and some time reproductives are collected in vials filled with ethanol 70°. Thirty (30) termite species have been identified. Five of them are new records for Senegal. The four trophic groups xylophagous, fungus-growing termites, harvester or foraging termites and soil-feeding were represented. The fungusgrowing termites are more diversified. According to the types of nests, termites encountered are divided into 3 groups. The more diversified are those that build ground-nest without fungus