1,824 research outputs found
Optical constants of silicon carbide for astrophysical applications. II. Extending optical functions from IR to UV using single-crystal absorption spectra
Laboratory measurements of unpolarized and polarized absorption spectra of
various samples and crystal stuctures of silicon carbide (SiC) are presented
from 1200--35,000 cm ( 8--0.28 m) and used to improve
the accuracy of optical functions ( and ) from the infrared (IR) to the
ultraviolet (UV). Comparison with previous 6--20 m
thin-film spectra constrains the thickness of the films and verifies that
recent IR reflectivity data provide correct values for in the IR region. We
extract and needed for radiative transfer models using a new
``difference method'', which utilizes transmission spectra measured from two
SiC single-crystals with different thicknesses. This method is ideal for
near-IR to visible regions where absorbance and reflectance are low and can be
applied to any material. Comparing our results with previous UV measurements of
SiC, we distinguish between chemical and structural effects at high frequency.
We find that for all spectral regions, 3C (-SiC) and the polarization of 6H (a type of -SiC) have almost identical
optical functions that can be substituted for each other in modeling
astronomical environments. Optical functions for of 6H SiC
have peaks shifted to lower frequency, permitting identification of this
structure below m. The onset of strong UV absorption for pure
SiC occurs near 0.2 m, but the presence of impurities redshifts the rise
to 0.33 m. Optical functions are similarly impacted. Such large
differences in spectral characteristics due to structural and chemical effects
should be observable and provide a means to distinguish chemical variation of
SiC dust in space.Comment: 46 pages inc. 8 figures and 2 full tables. Also 6 electronic-only
data files. Accepted by Ap
Optical properties of silicon carbide for astrophysical applications I. New laboratory infrared reflectance spectra and optical constants
Silicon Carbide (SiC) optical constants are fundamental inputs for radiative
transfer models of astrophysical dust environments. However, previously
published values contain errors and do not adequately represent the bulk
physical properties of the cubic (beta) SiC polytype usually found around
carbon stars. We provide new, uncompromised optical constants for beta- and
alpha-SiC derived from single-crystal reflectance spectra and investigate
quantitatively whether there is any difference between alpha- and beta-SiC that
can be seen in infrared spectra and optical functions.
Previous optical constants for SiC do not reflect the true bulk properties,
and they are only valid for a narrow grain size range. The new optical
constants presented here will allow narrow constraints to be placed on the
grain size and shape distribution that dominate in astrophysical environments.
In addition, our calculated absorption coefficients are much higher than
laboratory measurements, which has an impact on the use of previous data to
constrain abundances of these dust grains.Comment: 12 pages; 10 figures; laboratory optical constants available from
CDS. Accepted by Astronomy & Astrophysic
The SiC problem: astronomical and meteoritic evidence
Pre-solar grains of silicon carbide found in meteorites and interpreted as
having had an origin around carbon stars from their isotopic composition, have
all been found to be of the beta-SiC polytype. Yet to date fits to the 11.3
microns SiC emission band of carbon stars had been obtained only for alpha-SiC
grains. We present thin film infrared (IR) absorption spectra measured in a
diamond anvil cell for both the alpha- and beta- polymorphs of synthetic SiC
and compare the results with previously published spectra taken using the KBr
matrix method. We find that our thin film spectra have positions nearly
identical to those obtained previously from finely ground samples in KBr.
Hence, we show that this discrepancy has arisen from inappropriate `KBr
corrections' having been made to laboratory spectra of SiC particles dispersed
in KBr matrices. We re-fit a sample of carbon star mid-IR spectra, using
laboratory data with no KBr correction applied, and show that beta-SiC grains
fit the observations, while alpha-SiC grains do not. The discrepancy between
meteoritic and astronomical identifications of the SiC-type is therefore
removed. This work shows that the diamond anvil cell thin film method can be
used to produce mineral spectra applicable to cosmic environments without
further manipulation.Comment: to be published in Astrophysical Journal Letter 4 pages, 3 figure
Processing of Presolar Grains around Post-Asymptotic Giant Branch Stars: Silicon Carbide as the Carrier of the 21 Micron Feature
doi: 10.1086/379973Some proto-planetary nebulae (PPNs) exhibit an enigmatic feature in their infrared spectra at ~21 μm. This feature is not seen in the spectra of either the precursors to PPNs, the asymptotic giant branch (AGB) stars, or the successors of PPNs, "normal" planetary nebulae (PNs). However, the 21 μm feature has been seen in the spectra of PNs with Wolf-Rayet central stars. Therefore, the carrier of this feature is unlikely to be a transient species that only exists in the PPN phase. This feature has been attributed to various molecular and solid-state species, none of which satisfy all constraints, although titanium carbide (TiC) and polycyclic aromatic hydrocarbons (PAHs) have seemed the most viable. We present new laboratory data for silicon carbide (SiC) and show that it has a spectral feature that is a good candidate for the carrier of the 21 μm feature. The SiC spectral feature appears at approximately the same wavelength (depending on the polytype/grain size) and has the same asymmetric profile as the observed astronomical feature. We suggest that processing and cooling of the SiC grains known to exist around carbon-rich AGB stars are responsible for the emergence of the enigmatic 21 μm feature. The emergence of this feature in the spectra of post-AGB stars demonstrates the processing of dust due to the changing physical environments around evolving stars.A. M. H. was supported by NSF AST 98-05924
Current-Induced Spin Polarization in Gallium Nitride
Electrically generated spin polarization is probed directly in bulk GaN using
Kerr rotation spectroscopy. A series of n-type GaN epilayers are grown in the
wurtzite phase both by molecular beam epitaxy (MBE) and metalorganic chemical
vapor deposition (MOCVD) with a variety of doping densities chosen to broadly
modulate the transverse spin lifetime, T2*. The spin polarization is
characterized as a function of electrical excitation energy over a range of
temperatures. Despite weak spin-orbit interactions in GaN, a current-induced
spin polarization (CISP) is observed in the material at temperatures of up to
200 K.Comment: 16 pages, 3 figure
Effective Confinement as Origin of the Equivalence of Kinetic Temperature and Fluctuation-Dissipation Ratio in a Dense Shear Driven Suspension
We study response and velocity autocorrelation functions for a tagged
particle in a shear driven suspension governed by underdamped stochastic
dynamics. We follow the idea of an effective confinement in dense suspensions
and exploit a time-scale separation between particle reorganization and
vibrational motion. This allows us to approximately derive the
fluctuation-dissipation theorem in a "hybrid" form involving the kinetic
temperature as an effective temperature and an additive correction term. We
show numerically that even in a moderately dense suspension the latter is
negligible. We discuss similarities and differences with a simple toy model, a
single trapped particle in shear flow
Modified Fluctuation-dissipation theorem for non-equilibrium steady-states and applications to molecular motors
We present a theoretical framework to understand a modified
fluctuation-dissipation theorem valid for systems close to non-equilibrium
steady-states and obeying markovian dynamics. We discuss the interpretation of
this result in terms of trajectory entropy excess. The framework is illustrated
on a simple pedagogical example of a molecular motor. We also derive in this
context generalized Green-Kubo relations similar to the ones derived recently
by Seifert., Phys. Rev. Lett., 104, 138101 (2010) for more general networks of
biomolecular states.Comment: 6 pages, 2 figures, submitted in EP
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