Photochemical studies of cis-[Ru(bpy)2(4-bzpy)(CO)](PF6)2 and cis-[Ru(bpy)2(4-bzpy)(Cl)](PF6): Blue light-induced nucleobase binding.

The ruthenium(II) compounds cis-[Ru(bpy)2(4-bzpy)(CO)](PF6)2 (I) and cis-[Ru(bpy)2(4-bzpy)(Cl)](PF6) (II) (4-bzpy=4-benzoylpyridine, bpy=2,2'-bipyridine) were synthesized and characterized by spectroscopic and electrochemical techniques. The crystal structure of II was determined by X-ray diffraction. The photochemical behavior of I in aqueous solution shows that irradiation with ultraviolet light (365nm) releases both CO and 4-bzpy leading to the formation of the cis-[Ru(bpy)2(H2O)2]2+ ion as identified by NMR and electronic spectroscopy. Carbon monoxide release was confirmed with the myoglobin method and by gas chromatographic analysis of the headspace. CO release was not observed when aqueous I was irradiated with blue light (453nm). Changes in the electronic and 1H NMR spectra indicate that I undergoes photoaquation of 4-bzpy to form cis-[Ru(bpy)2(CO)(H2O)]2+. Blue light irradiation of aqueous II released the coordinated 4-bzpy to give the cis-[Ru(bpy)2(H2O)(Cl)]2+ ion. When the latter reaction was carried out in the presence of the nucleobase guanine, Ru-guanine adducts were formed, indicating that the metal containing photoproduct may also participate in biologically relevant reactions. The photochemical behavior of I indicates that it can release either CO or 4-bzpy depending on the wavelength chosen, a feature that may have therapeutic application

Desenho preliminar de uma coleção nuclear de mandioca dentro do banco ativo de germoplasma da Embrapa Amazônia Ocidental.

A mandioca (Manihot esculenta Crantz) destaca-se como um dos cultivos mais importantes na Amazônia, tanto para a segurança alimentar regional como no comércio. A Embrapa Amazônia Ocidental organizou um Banco Ativo de Germoplasma (BAG) para fins de melhoramento e conservação in vivo da variabilidade genética da mandioca, por meio da coleta de germoplasma em diferentes localidades no Estado do Amazonas, visando reunir a diversidade encontrada na região amazônica. O objetivo deste trabalho foi desenhar uma coleção nuclear de mandioca com base em dados geográficos, morfo-agronômicos e genético-moleculares. Decidiu-se que a Coleção Nuclear deveria conter 50 amostras, representando 15% do BAG e serão representadas por acessos coletados nas calhas dos principais rios Negro, Solimões, Purus, Amazonas e Madeira. As localidades super-representadas no BAG serão alocadas à CN logaritmicamente, enquanto que as localidades sub-representadas serão alocadas proporcionalmente. As amostras selecionadas para a Coleção devem possuir boa produtividade (>13,3 t/há), raízes com polpa de coloração amarelada, teores de HCN acima de 100 mg/kg e divergência genético-moleculares satisfatórias

Standard map in magnetized relativistic systems: fixed points and regular acceleration

We investigate the concept of a standard map for the interaction of relativistic particles and electrostatic waves of arbitrary amplitudes, under the action of external magnetic fields. The map is adequate for physical settings where waves and particles interact impulsively, and allows for a series of analytical result to be exactly obtained. Unlike the traditional form of the standard map, the present map is nonlinear in the wave amplitude and displays a series of peculiar properties. Among these properties we discuss the relation involving fixed points of the maps and accelerator regimes.Comment: Work to appear in Phys. Rev. E. 2 figure

Alternate islands of multiple isochronous chains in wave-particle interactions

We analyze the dynamics of a relativistic particle moving in a uniform magnetic field and perturbed by a standing electrostatic wave. We show that a pulsed wave produces an infinite number of perturbative terms with the same winding number, which may generate islands in the same region of phase space. As a consequence, the number of isochronous island chains varies as a function of the wave parameters. We observe that in all the resonances, the number of chains is related to the amplitude of the various resonant terms. We determine analytically the position of the periodic points and the number of island chains as a function of the wave number and wave period. Such information is very important when one is concerned with regular particle acceleration, since it is necessary to adjust the initial conditions of the particle to obtain the maximum acceleration.Comment: Submitte

Produção de uvas sem sementes "BRS CLARA"

bitstream/item/58249/1/3-uvas-Jair-2011.pd