Sporopollenin, a natural copolymer, is robust under high hydrostatic pressure

Lycopodium sporopollenin, a natural copolymer, shows exceptional stability under high hydrostatic pressures (10 GPa) as determined by in situ high pressure synchrotron source FTIR spectroscopy. This stability is evaluated in terms of the component compounds of the sporopollenin: p-coumaric acid, phloretic acid, ferulic acid, and palmitic and sebacic acids, which represent the additional n-acid and ndiacid components. This high stability is attributed to interactions between these components, rather than the exceptional stability of any one molecular component. We propose a biomimetic solution for the creation of polymer materials that can withstand high pressures for a multitude of uses in aeronautics, vascular autografts, ballistics and light-weight protective materials

Reducing Model Complexity by Means of the Optimal Scaling: Population Balance Model for Latex Particles Morphology Formation.

Rational computer-aided design of multiphase polymer materials is vital for rapid progress in many important applications, such as: diagnostic tests, drug delivery, coatings , additives for constructing materials, cosmetics, etc. Several property predictive models, including the prospective Population Balance Model for Latex Particles Morphology Formation (LPMF PBM), have already been developed for such materials. However, they lack computational efficiency, and the accurate prediction of materials’ properties still remains a great challenge . To enhance performance of the LPMF PBM, we explore the feasibility of reducing its complexity through disregard of the aggregation terms of the model. The introduced nondimensionalization approach, which we call Optimal Scaling with Constraints, suggests a quantitative criterion for locating regions of slow and fast aggregation and helps to derive a family of dimensionless LPMF PBM of reduced complexity. The mathematical analysis of this new family is also provided. When compared with the original LPMF PBM, the resulting models demonstrate several orders of magnitude better computational efficiency.The BERC 2018e2021 grant and the following ELKARTEK projects were also acknowledged: KK-2021/0 0 022, KK-2021/0 0 064 and KK-2022/0 0 0 06K

3-Dimensional Core-Collapse

In this paper, we present the results of 3-dimensional collapse simulations of rotating stars for a range of stellar progenitors. We find that for the fastest spinning stars, rotation does indeed modify the convection above the proto-neutron star, but it is not fast enough to cause core fragmentation. Similarly, although strong magnetic fields can be produced once the proto-neutron star cools and contracts, the proto-neutron star is not spinning fast enough to generate strong magnetic fields quickly after collapse and, for our simulations, magnetic fields will not dominate the supernova explosion mechanism. Even so, the resulting pulsars for our fastest rotating models may emit enough energy to dominate the total explosion energy of the supernova. However, more recent stellar models predict rotation rates that are much too slow to affect the explosion, but these models are not sophisticated enough to determine whether the most recent, or past, stellar rotation rates are most likely. Thus, we must rely upon observational constraints to determine the true rotation rates of stellar cores just before collapse. We conclude with a discussion of the possible constraints on stellar rotation which we can derive from core-collapse supernovae.Comment: 34 pages (5 of 17 figures missing), For full paper, goto http://qso.lanl.gov/~clf/papers/rot.ps.gz accepted by Ap

Epidemiologia do Boophilus microplus nas condições de cerrado.

O carrapato Boophilus microplus (Canestrini 1887), e um parasita temporário e obrigatório dos bovinos. Distribui-se geograficamente entre os paralelos 32 Norte e Sul, tendo ampla distribuição no México, América Central, América do Sul e Austrália.bitstream/item/137546/1/PESQ-EM-ANDAMENTO-23.pd

Tasas de dispersión y supervivencia de adultos y juveniles del rabijunco colirrojo (Phaethon rubricauda) expuestas a contaminantes potenciales

Annual survival and dispersal rates of adult and juvenile red–tailed tropicbirds were examined in connection with exposure to heavy metals. From 1990–2000 the incineration of a U.S. stockpile of chemical weapons stored at Johnston Atoll exposed nesting tropicbirds to increased levels of human disturbance, smoke stack emissions and potential leaks. Using a multi–state mark–recapture modeling approach, birds nesting in this site (downwind of the plant) were compared to those nesting in a reference site (upwind of the plant) with less human disturbance, no exposure to smoke stack emissions or other potential incineration emissions. We did not find any difference in survival of adults or juveniles when comparing the two sites. Adult breeding dispersal rates did not differ between the sites but we did find differences in the age–specific natal dispersal rates. Birds fledged from downwind areas were less likely to return to their natal area to nest and more likely to immigrate to the upwind area than vice–versa. This asymmetry in emigration rates is believed to be due to differing vegetation densities and has implications for vegetation management in relation to tropicbird nest success and population size.Se examinaron las tasas de dispersión y de supervivencia anual de adultos y jóvenes de los rabijuncos colirrojos en relación a la exposición a metales pesados. Entre los años 1990 y 2000, la incineración de un arsenal de armas químicas del ejército de Estados Unidos almacenadas en Johnston Atoll expuso a las aves del trópico que anidaban en la zona a niveles más elevados de perturbaciones antrópicas/contaminación humana, emisiones procedentes de chimeneas y fugas potenciales. Se comparó las aves nidificantes en este lugar (a favor del viento de la planta) mediante modelos de captura–recaptura de multiestados, con las que anidaban en un emplazamiento de referencia (en cuyo caso la planta quedaba situada en contra del viento), caracterizado por menos perturbaciones antrópicas y ninguna exposición a emisiones procedentes de chimeneas ni a ningún otro tipo de emisiones potenciales de incineración. Al comparar ambos emplazamientos, no se halló ninguna diferencia en cuanto a la supervivencia de las aves adultas o jóvenes. Las tasas de dispersión reproductiva de los adultos no difirieron entre los emplazamientos; en cambio, sí que se observaron diferencias en las tasas de dispersión natal por edades. Las aves jóvenes que abandonaron las áreas situadas a favor del viento era menos probable que regresaran a su área natal para anidar y más probable que inmigraran al área situada en contra del viento. Se considera que esta asimetría en las tasas de emigración obedece a las diferentes densidades de vegetación, repercutiendo en la gestión de la vegetación con respecto al éxito de los nidos de las aves del trópico y el tamaño poblacional

Tuning the superconducting and magnetic properties in Fe_ySe_0.25Te_0.75 by varying the Fe-content

The superconducting and magnetic properties of Fe$_{y}$Se$_{0.25}$Te$_{0.75}$ single crystals ($0.9\leq y \leq1.1$) were studied by means of x-ray diffraction, SQUID magnetometry, muon spin rotation, and elastic neutron diffraction. The samples with $y<1$ exhibit coexistence of bulk superconductivity and incommensurate magnetism. The magnetic order remains incommensurate for $y\geq 1$, but with increasing Fe content superconductivity is suppressed and the magnetic correlation length increases. The results show that the superconducting and the magnetic properties of the Fe$_{y}$Se$_{1-x}$Te$_{x}$ can be tuned not only by varying the Se/Te ratio but also by changing the Fe content

Attosecond control of electrons emitted from a nanoscale metal tip

Attosecond science is based on steering of electrons with the electric field of well-controlled femtosecond laser pulses. It has led to, for example, the generation of XUV light pulses with a duration in the sub-100-attosecond regime, to the measurement of intra-molecular dynamics by diffraction of an electron taken from the molecule under scrutiny, and to novel ultrafast electron holography. All these effects have been observed with atoms or molecules in the gas phase. Although predicted to occur, a strong light-phase sensitivity of electrons liberated by few-cycle laser pulses from solids has hitherto been elusive. Here we show a carrier-envelope (C-E) phase-dependent current modulation of up to 100% recorded in spectra of electrons laser-emitted from a nanometric tungsten tip. Controlled by the C-E phase, electrons originate from either one or two sub-500as long instances within the 6-fs laser pulse, leading to the presence or absence of spectral interference. We also show that coherent elastic re-scattering of liberated electrons takes place at the metal surface. Due to field enhancement at the tip, a simple laser oscillator suffices to reach the required peak electric field strengths, allowing attosecond science experiments to be performed at the 100-Megahertz repetition rate level and rendering complex amplified laser systems dispensable. Practically, this work represents a simple, exquisitely sensitive C-E phase sensor device, which can be shrunk in volume down to ~ 1cm3. The results indicate that the above-mentioned novel attosecond science techniques developed with and for atoms and molecules can also be employed with solids. In particular, we foresee sub-femtosecond (sub-) nanometre probing of (collective) electron dynamics, such as plasmon polaritons, in solid-state systems ranging in size from mesoscopic solids via clusters to single protruding atoms.Comment: Final manuscript version submitted to Natur

Competitiveness and communication for effective inoculation byRhizobium, Bradyrhizobium and vesicular-arbuscular mycorrhiza fungi

After a short summary on the ecology and rhizosphere biology of symbiotic bacteria and vesicular-arbuscular (VA) mycorrhiza fungi and their application as microbial inocula, results on competitiveness and communication are summarized. Stress factors such as high temperature, low soil pH, aluminium concentrations and phytoalexins produced by the host plants were studied withRhizobium leguminosarum bv.phaseoli andRhizobium tropici onPhaseolus beans. Quantitative data for competitiveness were obtained by usinggus + (glucoronidase) labelled strains, which produce blue-coloured nodules. ForPhaseolus-nodulating rhizobia, a group specific DNA probe was also developed, which did not hybridize with more than 20 other common soil and rhizosphere bacteria. Results from several laboratories contributing to knowledge of signal exchange and communication in theRhizobium/Bradyrhizobium legume system are summarized in a new scheme, including also defense reactions at the early stages of legume nodule initiation. Stimulating effects of flavonoids on germination and growth of VA mycorrhiza fungi were also found. A constitutive antifungal compound in pea roots, -isoxazolinonyl-alanine, was characterized

Field Analysis of Microbial Contamination Using Three Molecular Methods in Parallel

Advanced technologies with the capability of detecting microbial contamination remain an integral tool for the next stage of space agency proposed exploration missions. To maintain a clean, operational spacecraft environment with minimal potential for forward contamination, such technology is a necessity, particularly, the ability to analyze samples near the point of collection and in real-time both for conducting biological scientific experiments and for performing routine monitoring operations. Multiple molecular methods for detecting microbial contamination are available, but many are either too large or not validated for use on spacecraft. Two methods, the adenosine- triphosphate (ATP) and Limulus Amebocyte Lysate (LAL) assays have been approved by the NASA Planetary Protection Office for the assessment of microbial contamination on spacecraft surfaces. We present the first parallel field analysis of microbial contamination pre- and post-cleaning using these two methods as well as universal primer-based polymerase chain reaction (PCR)