Modelling of a standard gas mixtures generator with computational fluid dynamics

Monitoring VOC for climate change and for indoor and outdoor air quality at trace level concentrations need reference standard materials at high metrological performance. To improve this performance, the description of phenomena involved in mixtures generation by rigorous models is mandatory. A model to describe diffusion cells of a primary generator was developed and validated with experimental data. A good agreement was found between the uncertainties of measurements and calculations

Natural sealed fractures in mudrocks: A case study tied to burial history from the Barnett Shale, Fort Worth Basin, Texas, USA

The Mississippian Barnett Shale (Texas, USA), consisting of organic-rich shales and limestones, hosts the largest gas fields of North America. This study examines sealed fractures from core and outcrop samples of the Barnett Shale of the Fort Worth Basin and aims to: 1) characterize the phases occurring in the fractures from samples having experienced different burial histories; 2) establish a paragenetic sequence to relate the timing of fracture origin and sealing with the burial history of the basin; and 3) contribute to the understanding of the mechanisms of fracture formation in shales, including overpressure origin. Four fracture generations were distinguished in the most deeply buried core samples by characterizing the sealing minerals petrographically and geochemically. The generations were inserted into the framework of a reconstructed burial history for the Fort Worth Basin, which allowed a time sequence for fracture development to be established. This in turn allowed inference of conditions of fracture development, and consideration of fracture mechanisms as well as the origin of the parent fluids of sealing minerals.Type 1 fractures formed during early mechanical compaction (at a few 10s to 100m of depth) of still not fully cemented sediments. Type 2 fractures formed during moderate burial (~2km), from slightly modified seawater. Their timing is consistent with overpressure generated during rapid deposition and differential compaction of Pennsylvanian lithologies during the onset of the Ouachita compressional event. Type 3 fractures formed during deep burial (>3km) from silica-rich basinal brines possibly derived from clay diagenesis. Type 4 fractures formed at very deep burial (>4km), from hot and 18O-rich fluids, carrying light oil (20-30 API) and record the opening of the fluid system after hydrocarbon migration.Differences are highlighted between the timing and thermal regimes under which fractures formed in Barnett lithologies from different areas of the basin, this suggesting that extrapolation of outcrop observations to subsurface must be used with due care

Simulation of boron rejection by seawater reverse osmosis desalination

yesBoron is a vital element for growth of creations, but excessive exposure can cause detrimental effects to plants, animals, and possibly humans. Reverse Osmosis (RO) technique is widely used for seawater desalination as well as for waste water treatment. The aim of this study is to identify how different operating parameters such as pH, temperature and pressure can affect boron concentrations at the end of RO processes. For this purpose, a mathematical model for boron rejection is developed based on solution-diffusion model which can describe solvent and solute transport mechanism through the membranes. After a wide and thorough research, empirical correlations developed in the past are filtered, adopted and calibrated in order to faction with reliability as part of the solution-diffusion model of this work. The model is validated against a number of experimental results from the literature and is used in further simulations to get a deeper insight of the RO process. The general findings of the boron rejection model are supporting the case that with increasing pH and operating pressure of the feed water, the boron rejection increases and with increasing feed water temperature the boron rejection decreases

Exceptional cause of bowel obstruction: rectal endometriosis mimicking carcinoma of Rectum - A case report

Endometriosis with intestinal serosal involvement is not uncommon in women of childbearing age. However, endometriosis presenting as colon obstruction is rare and occurs in less than 1% of cases. The Lack of pathognomonic signs makes the diagnosis difficult, mostly because the main differential diagnosis is with neoplasm, even during the intervention. Reported here is a case of a 35-year –old woman presenting with bowel obstruction due to rectal endometriosis. The patient presented signs and symptoms of bowel obstruction. Colonoscopy and radiological findings were suggestive of rectal carcinoma. Surgeons performed an anterior resection with right salpingectomy. Histopathology diagnosed bowel endometriosis. This case demonstrates the difficulty of establishing an accurate pre- and intra-operative diagnosis and the ability of intestinal endometriosis to mimic colon cancer

Exploring the relationship between education and obesity

An epidemic of obesity has been developing in virtually all OECD countries over the last 30 years. Existing evidence provides a strong suggestion that such an epidemic has affected certain social groups more than others. In particular, a better education appears to be associated with a lower likelihood of obesity, especially among women. This paper sheds light on the nature and the strength of the correlation between education and obesity. Analyses of health survey data from Australia, Canada, England, and Korea were undertaken with the aim of exploring this relationship. Social gradients in obesity were assessed across the entire education spectrum, overall and in different population sub-groups. Furthermore, investigations testing for mediation effects and for the causal nature of the links observed were undertaken to better understand the underlying mechanisms of the relationship between education and obesity. © OECD 2011

Self-reported knee symptoms assessed by KOOS questionnaire in downhill runners (skyrunners)

Background: The knee is the weight-bearing joint most commonly associated with sports injuries, and therefore is most at risk of developing degenerative changes, including osteoarthritis. Skyrunners can be considered to be at risk of developing symptoms of post-traumatic osteoarthritis due to downhill running. Aim: The aim of this study was to analyze the health of the knee joints of a large group of these athletes via a specific self-report questionnaire. Methods: This study was carried out by asking the participants of seven official Skyraces (22.4±3.1 km length; 1596±393 m elevation) to fill out a questionnaire. Information regarding age, sex, downhill elevation (m) during training and competitions over the last month, and history of previous knee injury was also collected before the participants filled out the Knee injury and Osteoarthritis Outcome Score (KOOS), which is a reliable and validated instrument designed to assess patients' opinions about their knees and associated problems that can result in post-traumatic osteoarthritis. Athletes were divided into six age groups (from 17 to 70 years) and 12 groups based on the downhill gradient they had covered over the last month (from 1,000 to 40,000 m). Results: Six hundred twenty-one questionnaires were collected from 45% of the participants in the seven races. Multivariate analysis revealed that self-reported KOOS scores were unrelated to age, sex and monthly downhill gradient. Only 74 (12%) of the participants reported previous knee injuries. Significant differences in the five subscales of the KOOS were found between skyrunners with and without previous knee injuries (P<0.01). Conclusions: In the studied population, regular training for downhill running and participation in Skyraces could not be considered risk factors for subjective knee symptoms. Skyrunners with selfreported histories of knee injuries scored worse on all five subscales of the KOO