Chromium recovery by membranes for process reuse in the tannery industry

Leather tanning is a wide common industry all over the world. In leather processing, water is one of the most important medium, almost 40-45 L water kg-1 raw-hide or skin is used by tanneries for processing finished leathers. The composition of tannery wastewater presents considerable dissimilarities in the concentration range of pollutants both of inorganic (chlorides, with concentration ranging from several hundred to over 10,000 mg L-1 Cl–; sulphate (VI), ammonium ions and sulphide ions, exhibiting concentration that ranges from tens to several hundred mg L-1) and organic (the COD value is usually several thousand mg L-1 O2). Throughout the years, many conventional processes have been carried out to treat wastewater from tannery industry: unfortunately, in this case, biological treatment methods give rise to an excessive production of sludge, whereas physical and chemical methods are too expensive in terms of energy and reagent costs. In this work, a membrane process based on NF membrane modules was adopted to treat the tannery feedstock after primary conventional treatment. In a first step, the determination of all boundary flux parameters, in order to inhibit severe fouling formation during operation, were performed. After this, experimental work was carried out to validate the approach. The target of water purification was reached, that is the legal discharge to municipal sewer system in Italy of 90% of the initial wastewater stream volume. This allows having an immediate cost saving of 21%. Moreover, the developed process leads to a second benefit, that is the production of 5% of the initial volume as a highly chromium-rich concentrate at no cost suitable to tannery process recycle and reuse. In this case, cost saving rates exceeds 40%. At the end, scale-up of the investigated process will be discussed from technical and economic point of view

An Unbiased 1.3 mm Emission Line Survey of the Protoplanetary Disk Orbiting LkCa 15

The outer (>30 AU) regions of the dusty circumstellar disk orbiting the ~2-5 Myr-old, actively accreting solar analog LkCa 15 are known to be chemically rich, and the inner disk may host a young protoplanet within its central cavity. To obtain a complete census of the brightest molecular line emission emanating from the LkCa 15 disk over the 210-270 GHz (1.4 - 1.1 mm) range, we have conducted an unbiased radio spectroscopic survey with the Institute de Radioastronomie Millimetrique (IRAM) 30 meter telescope. The survey demonstrates that, in this spectral region, the most readily detectable lines are those of CO and its isotopologues 13CO and C18O, as well as HCO+, HCN, CN, C2H, CS, and H2CO. All of these species had been previously detected in the LkCa 15 disk; however, the present survey includes the first complete coverage of the CN (2-1) and C2H (3-2) hyperfine complexes. Modeling of these emission complexes indicates that the CN and C2H either reside in the coldest regions of the disk or are subthermally excited, and that their abundances are enhanced relative to molecular clouds and young stellar object environments. These results highlight the value of unbiased single-dish line surveys in guiding future high resolution interferometric imaging of disks.Comment: 35 pages, 9 figures, accepted for publication in The Astrophysical Journa

A ring in a shell: the large-scale 6D structure of the Vela OB2 complex

The Vela OB2 association is a group of 10 Myr stars exhibiting a complex spatial and kinematic substructure. The all-sky Gaia DR2 catalogue contains proper motions, parallaxes (a proxy for distance) and photometry that allow us to separate the various components of Vela OB2. We characterise the distribution of the Vela OB2 stars on a large spatial scale, and study its internal kinematics and dynamic history. We make use of Gaia DR2 astrometry and published Gaia-ESO Survey data. We apply an unsupervised classification algorithm to determine groups of stars with common proper motions and parallaxes. We find that the association is made up of a number of small groups, with a total current mass over 2330 Msun. The three-dimensional distribution of these young stars trace the edge of the gas and dust structure known as the IRAS Vela Shell across 180 pc and shows clear signs of expansion. We propose a common history for Vela OB2 and the IRAS Vela Shell. The event that caused the expansion of the shell happened before the Vela OB2 stars formed, imprinted the expansion in the gas the stars formed from, and most likely triggered star formation.Comment: Accepted by A&A (02 November 2018), 13 pages, 9+2 figure

Age-dependence of electromagnetic power and heat deposition in near-surface tissues in emerging 5G bands

With the development of 5th generation (5G) mobile networks people of different ages will be exposed in the upper part of the microwave spectrum. From the perspective of non-ionizing radiation dosimetry, an accurate analysis of age-dependent electromagnetic power deposition and resulting heating is required. In this study, we evaluate the effect of age on exposure at 26 GHz and 60 GHz. A near-surface tissue model illuminated by a plane wave is used to asses the exposure considering both frequency-independent and frequency-dependent limits. The age-related variation of the skin thickness and tissue electromagnetic properties has been considered. Moreover, the blood flow decrease rate has been taken into account to assess the age-dependent heating. Our results demonstrate that the overall variations of the power density, specific absorption rate (SAR) and heating in the near-surface tissues are limited to about 10–15%. These variations are mainly due to the tissue permittivity and blood flow change with age. In contrast to the transmitted power density that increases with age, the peak SAR decreases at both frequencies. The peak steady-state heating increases from 5 to 70 years old by roughly 11% at 26 GHz and 13% at 60 GHz

Toward a precision, complexity-informed cultural policy design: Structural bottlenecks to culture-led development in Skaraborg, Sweden

We analyze the spatial-temporal dynamics of cultural vibrancy in the Swedish sub-region of Skaraborg. Our database consists of 4170 geo-localized cultural activities and facilities, mapped between October 2013 and March 2014. We make use of the TWC methodology for the dynamic simulation of the evolution of geo-localized activity starting from an observed distribution of events, and of the AutoCM ANN architecture to understand how cultural variables are related to the rest of the Skaraborg socio-economy. We find that cultural vibrancy in Skaraborg is likely characterized by a 'flaring' pattern of initial, widespread activity followed by a re-concentration into the main local urban hubs. The deep reason behind this unsuccessful developmental trajectory is the lack of centrality of cultural production in the local socio-economy, and of integration across cultural production sectors. This is in turn due also to structural bottlenecks of a non-cultural nature such as insufficient access of women to higher education. We make a case for the necessity to develop a new precision cultural policy design approach founded upon the science of complexity for both policy design and assessment, and we provide and illustrate a first technical toolkit to this purpose.(c) 2022 Elsevier B.V. All rights reserved

A nonlinear, data-driven, ANNs-based approach to culture-led development policies in rural areas: The case of Gjakove and Pee districts, Western Kosovo

We develop a computational approach to the analysis of cultural vibrancy and to the role of the cultural and cre-ative sectors in the socio-economic organization of two districts of Western Kosovo, Gjakove and Pee. Our anal-ysis is built on a geolocalized mapping of the cultural activities and facilities, and on the main socio-economic variables for the two districts, and makes use of innovative data analysis techniques: Theory of Impossible Words (TIW), the Topological Weighted Centroid (TWC), and the AutoCM ANN. We find that the dynamics of cul-tural vibrancy of the territory is mainly driven by the competing attraction pulls of the nearby countries of Serbia and Albania, that also form the region's main and often conflicting ethnicities, and that such dynamics are likely to further polarize in the future. We also find that the cultural system plays a marginal role in the territory's socio-economic organization. This situation makes a case for a more active role of cultural policy in shaping future local developmental models in rural areas and in acting as an agent of social cohesion.(c) 2022 Elsevier Ltd. All rights reserved

Método para classificar bovinos resistentes à infecção por Babesia bovis.

Descreve a metodologia de desafio para a identificação de bovinos resistentes ou suscetíveis à primo-infecção por B. bovis para fins experimentais.bitstream/item/55805/1/CO65.pdfDsiponível no formato online