On the Role of Penning Ionization in Photoassociation Spectroscopy

We study the role of Penning ionization on the photoassociation spectra of He(^3S)-He(^3S). The experimental setup is discussed and experimental results for different intensities of the probe laser are shown. For modelling the experimental results we consider coupled-channel calculations of the crossing of the ground state with the excited state at the Condon point. The coupled-channel calculations are first applied to model systems, where we consider two coupled channels without ionization, two coupled channels with ionization, and three coupled channels, for which only one of the excited states is ionizing. Finally, coupled-channel calculations are applied to photoassociation of He(^3S)-He(^3S) and good agreement is obtained between the model and the experimental results.Comment: 14 pages, 18 figures, submitted to the special issue on Cold Molecules of J. Phys.

Optimal inverse estimation of ecosystem parameters from observations of carbon and energy fluxes

Canopy structural and leaf photosynthesis parameterizations such as maximum carboxylation capacity (V_(cmax)), slope of the Ball–Berry stomatal conductance model (BB_(slope)) and leaf area index (LAI) are crucial for modeling plant physiological processes and canopy radiative transfer. These parameters are large sources of uncertainty in predictions of carbon and water fluxes. In this study, we develop an optimal moving window nonlinear Bayesian inversion framework to use the Soil Canopy Observation Photochemistry and Energy fluxes (SCOPE) model for constraining V_(cmax), BB_(slope) and LAI with observations of coupled carbon and energy fluxes and spectral reflectance from satellites. We adapted SCOPE to follow the biochemical implementation of the Community Land Model and applied the inversion framework for parameter retrievals of plant species that have both the C₃ and C₄ photosynthetic pathways across three ecosystems. We present comparative analysis of parameter retrievals using observations of (i) gross primary productivity (GPP) and latent energy (LE) fluxes and (ii) improvement in results when using flux observations along with reflectance. Our results demonstrate the applicability of the approach in terms of capturing the seasonal variability and posterior error reduction (40 %–90 %) of key ecosystem parameters. The optimized parameters capture the diurnal and seasonal variability in the GPP and LE fluxes well when compared to flux tower observations (0.95>R²>0.79). This study thus demonstrates the feasibility of parameter inversions using SCOPE, which can be easily adapted to incorporate additional data sources such as spectrally resolved reflectance and fluorescence and thermal emissions

Genetic background of methane emission by Dutch Holstein Friesian cows measured with infrared sensors in automatic milking systems

International environmental agreements have led to the need to reduce methane emission by dairy cows. Reduction could be achieved through selective breeding. The aim of this study was to quantify the genetic variation of methane emission by Dutch Holstein Friesian cows measured using infrared sensors installed in automatic milking systems (AMS). Measurements of CH4 and CO2 on 1508 Dutch Holstein Friesian cows located on 11 commercial dairy farms were available. Phenotypes per AMS visit were the mean of CH4, mean of CO2, mean of CH4 divided by mean of CO2, and their log10-transformations. The repeatabilities of the log10-transformated methane phenotypes were 0.27 for CH4, 0.31 for CO2, and 0.14 for the ratio. The log10-transformated heritabilities of these phenotypes were 0.11 for CH4, 0.12 for CO2, and 0.03 for the ratio. These results indicate that measurements taken using infrared sensors in AMS are repeatable and heritable and, thus, could be used for selection for lower CH4 emission. Furthermore, it is important to account for farm, AMS, day of measurement, time of day, and lactation stage when estimating genetic parameters for methane phenotypes. Selection based on log10-transformated CH4 instead of the ratio would be expected to give a greater reduction of CH4 emission by dairy cows

Ionospheric Calibration of Low Frequency Radio Interferometric Observations using the Peeling Scheme: I. Method Description and First Results

Calibration of radio interferometric observations becomes increasingly difficult towards lower frequencies. Below ~300 MHz, spatially variant refractions and propagation delays of radio waves traveling through the ionosphere cause phase rotations that can vary significantly with time, viewing direction and antenna location. In this article we present a description and first results of SPAM (Source Peeling and Atmospheric Modeling), a new calibration method that attempts to iteratively solve and correct for ionospheric phase errors. To model the ionosphere, we construct a time-variant, 2-dimensional phase screen at fixed height above the Earth's surface. Spatial variations are described by a truncated set of discrete Karhunen-Loeve base functions, optimized for an assumed power-law spectral density of free electrons density fluctuations, and a given configuration of calibrator sources and antenna locations. The model is constrained using antenna-based gain phases from individual self-calibrations on the available bright sources in the field-of-view. Application of SPAM on three test cases, a simulated visibility data set and two selected 74 MHz VLA data sets, yields significant improvements in image background noise (5-75 percent reduction) and source peak fluxes (up to 25 percent increase) as compared to the existing self-calibration and field-based calibration methods, which indicates a significant improvement in ionospheric phase calibration accuracy.Comment: 23 pages, 14 figures, 2 tables. Accepted for publication in A&A. Changes in v2: Corrected minor error in Equations A.3 and A.12. Extended acknowledgment

Development of a practical guideline for person centred goal setting in geriatric rehabilitation:A participatory action research

PurposeTo improve goal setting in Geriatric Rehabilitation (GR), by developing an evidence-based practical guideline for patient-centred goal setting.MethodsParticipatory action research (PAR) in a cyclical process, with GR professionals as co-researchers. Each cycle consisted of five phases: problem analysis, literature review, development, practical experience, feedback & evaluation. The evaluation was based on video recordings of goal setting conversations, and on oral and written feedback of the GR professionals who tested the guideline.ResultsIn two PAR-cycles the guideline was developed, consisting of eight recommendations for setting and using goals, and of practical advices elaborating three of the recommendations, concerning conversational skills specific for goal setting conversations. After the second cycle the research team concluded that the guideline was feasible in daily practice and effective when used consciously.ConclusionIn this study, a practical guideline for setting and using goals in GR was developed. GR teams can improve their patient centred working with goals by discussing the recommendations in their team and choosing the recommendations to work on. This can be supported by the development of an interdisciplinary training. The effect on quality of care should be subject to further investigation

Chalcogenides applied to microring switching

We show that switching a phase-change material between its two bonding states can be used to shift the resonant wavelength of a ring resonator and change its Q-factor and extinction ratio, in a reversible and non-volatile way

A 5-year follow-up study of Alfredson's heel-drop exercise programme in chronic midportion Achilles tendinopathy

Background: Eccentric exercises have the most evidence in conservative treatment of midportion Achilles tendinopathy. Although short-term studies show significant improvement, little is known of the long-term (>3 years) results. Aim: To evaluate the 5-year outcome of patients with chronic midportion Achilles tendinopathy treated with the classical Alfredson's heel-drop exercise programme. Study design: Part of a 5-year follow-up of a previously conducted randomised controlled trial. Methods: 58 patients (70 tendons) were approached 5 years after the start of the heel-drop exercise programme according to Alfredson. At baseline and at 5-year follow-up, the validated Victorian Institute of Sports Assessment-Achilles (VISA-A) questionnaire score, pain status, alternative treatments received and ultrasonographic neovascularisation score were recorded. Results: In 46 patients (58 tendons), the VISA-A score significantly increased from 49.2 at baseline to 83.6 after 5 years (p<0.001) and from the 1-year to 5-year follow-up from 75.0 to 83.4 (p<0.01). 39.7% of the patients were completely pain-free at follow-up and 48.3% had received one or more alternative treatments. The sagittal tendon thickness decreased from 8.05 mm (SD 2.1) at baseline to 7.50 mm (SD 1.6) at the 5-year follow-up (p=0.051). Conclusion: At 5-year follow-up, a significant increase of VISA-A score can be expected. After the 3-month Alfredson's heel-drop exercise programme, almost half of the patients had received other therapies. Although improvement of symptoms can be expected at long term, mild pain may remain

Global column‐averaged methane mixing ratios from 2003 to 2009 as derived from SCIAMACHY: Trends and variability

After a decade of stable or slightly decreasing global methane concentrations, ground-based in situ data show that CH_4 began increasing again in 2007 and that this increase continued through 2009. So far, space-based retrievals sensitive to the lower troposphere in the time period under consideration have not been available. Here we report a long-term data set of column-averaged methane mixing ratios retrieved from spectra of the Scanning Imaging Absorption Spectrometer for Atmospheric Cartography (SCIAMACHY) instrument onboard Envisat. The retrieval quality after 2005 was severely affected by degrading detector pixels within the methane 2ν_3 absorption band. We identified the most crucial problems in SCIAMACHY detector degradation and overcame the problem by applying a strict pixel mask as well as a new dark current characterization. Even though retrieval precision after the end of 2005 is invariably degraded, consistent methane retrievals from 2003 through 2009 are now possible. Regional time series in the Sahara, Australia, tropical Africa, South America, and Asia show the methane increase in 2007–2009, but we cannot yet draw a firm conclusion concerning the origin of the increase. Tropical Africa even seems to exhibit a negative anomaly in 2006, but an impact from changes in SCIAMACHY detector degradation cannot be excluded yet. Over Assakrem, Algeria, we observed strong similarities between SCIAMACHY measurements and ground-based data in deseasonalized time series. We further show long-term SCIAMACHY xCH_4 averages at high spatial resolution that provide further insight into methane variations on regional scales. The Red Basin in China exhibits, on average, the highest methane abundance worldwide, while other localized features such as the Sudd wetlands in southern Sudan can also be identified in SCIAMACHY xCH_4 averages