The role of electron-hole recombination in organic magnetoresistance

Magneto-electrical measurements were performed on diodes and bulk heterojunction solar cells (BHSCs) to clarify the role of formation of coulombically bound electron-hole (e-h) pairs on the magnetoresistance (MR) response in organic thin film devices. BHSCs are suitable model systems because they effectively quench excitons but the probability of forming e-h pairs in them can be tuned over orders of magnitude by the choice of material and solvent in the blend. We have systematically varied the e-h recombination coefficients, which are directly proportional to the probability for the charge carriers to meet in space, and found that a reduced probability of electrons and holes meeting in space lead to disappearance of the MR. Our results clearly show that MR is a direct consequence of e-h pair formation. We also found that the MR line shape follows a power law-dependence of B0.5 at higher fields

A scale-free network hidden in the collapsing polymer

We show that the collapsed globular phase of a polymer accommodates a scale-free incompatibility graph of its contacts. The degree distribution of this network is found to decay with the exponent $\gamma = 1/(2-c)$ up to a cut-off degree $d_c \propto L^{2-c}$, where $c$ is the loop exponent for dense polymers ($c=11/8$ in two dimensions) and $L$ is the length of the polymer. Our results exemplify how a scale-free network (SFN) can emerge from standard criticality.Comment: 4 pages, 3 figures, address correcte

Polymer desorption under pulling: a novel dichotomic phase transition

We show that the structural properties and phase behavior of a self-avoiding polymer chain on adhesive substrate, subject to pulling at the chain end, can be obtained by means of a Grand Canonical Ensemble (GCE) approach. We derive analytical expressions for the mean length of the basic structural units of adsorbed polymer, such as loops and tails, in terms of the adhesive potential and detachment force, and determine values of the universal exponents which govern their probability distributions. Most notably, the hitherto controversial value of the critical adsorption exponent $\phi$ is found to depend essentially on the interaction between different loops. The chain detachment transition turns out to be of the first order, albeit dichotomic, i.e., no coexistence of different phase states exists. These novel theoretical predictions and the suggested phase diagram of the adsorption-desorption transformation under external pulling force are verified by means of extensive Monte Carlo simulations.Comment: 10 pages, 4 figure

Trading interactions for topology in scale-free networks

Scale-free networks with topology-dependent interactions are studied. It is shown that the universality classes of critical behavior, which conventionally depend only on topology, can also be explored by tuning the interactions. A mapping, $\gamma' = (\gamma - \mu)/(1-\mu)$, describes how a shift of the standard exponent $\gamma$ of the degree distribution $P(q)$ can absorb the effect of degree-dependent pair interactions $J_{ij} \propto (q_iq_j)^{-\mu}$. Replica technique, cavity method and Monte Carlo simulation support the physical picture suggested by Landau theory for the critical exponents and by the Bethe-Peierls approximation for the critical temperature. The equivalence of topology and interaction holds for equilibrium and non-equilibrium systems, and is illustrated with interdisciplinary applications.Comment: 4 pages, 5 figure

Universality of collapsing two-dimensional self-avoiding trails

Results of a numerically exact transfer matrix calculation for the model of Interacting Self-Avoiding Trails are presented. The results lead to the conclusion that, at the collapse transition, Self-Avoiding Trails are in the same universality class as the O(n=0) model of Blote and Nienhuis (or vertex-interacting self-avoiding walk), which has thermal exponent $\nu=12/23$, contrary to previous conjectures.Comment: Final version, accepted for publication in Journal of Physics A; 9 pages; 3 figure

On the number of contacts of a floating polymer chain cross-linked with a surface adsorbed chain on fractal structures

We study the interaction problem of a linear polymer chain, floating in fractal containers that belong to the three-dimensional Sierpinski gasket (3D SG) family of fractals, with a surface-adsorbed linear polymer chain. Each member of the 3D SG fractal family has a fractal impenetrable 2D adsorbing surface, which appears to be 2D SG fractal. The two-polymer system is modelled by two mutually crossing self-avoiding walks. By applying the Monte Carlo Renormalization Group (MCRG) method, we calculate the critical exponents $\phi$, associated with the number of contacts of the 3D SG floating polymer chain, and the 2D SG adsorbed polymer chain, for a sequence of SG fractals with $2\le b\le 40$. Besides, we propose the codimension additivity (CA) argument formula for $\phi$, and compare its predictions with our reliable set of the MCRG data. We find that $\phi$ monotonically decreases with increasing $b$, that is, with increase of the container fractal dimension. Finally, we discuss the relations between different contact exponents, and analyze their possible behaviour in the fractal-to-Euclidean crossover region $b\to\infty$.Comment: 15 pages, 3 figure

Sequence randomness and polymer collapse transitions

Contrary to expectations based on Harris' criterion, chain disorder with frustration can modify the universality class of scaling at the theta transition of heteropolymers. This is shown for a model with random two-body potentials in 2D on the basis of exact enumeration and accurate Monte Carlo results. When frustration grows beyond a certain finite threshold, the temperature below which disorder becomes relevant coincides with the theta one and scaling exponents definitely start deviating from those valid for homopolymers.Comment: 4 pages, 4 eps figure

Vertex Models and Random Labyrinths: Phase Diagrams for Ice-type Vertex Models

We propose a simple geometric recipe for constructing phase diagrams for a general class of vertex models obeying the ice rule. The disordered phase maps onto the intersecting loop model which is interesting in its own right and is related to several other statistical mechanical models. This mapping is also useful in understanding some ordered phases of these vertex models as they correspond to the polymer loop models with cross-links in their vulcanised phase.Comment: 8 pages, 6 figure

Bethe approximation for self-interacting lattice trees

In this paper we develop a Bethe approximation, based on the cluster variation method, which is apt to study lattice models of branched polymers. We show that the method is extremely accurate in cases where exact results are known as, for instance, in the enumeration of spanning trees. Moreover, the expressions we obtain for the asymptotic number of spanning trees and lattice trees on a graph coincide with analogous expressions derived through different approaches. We study the phase diagram of lattice trees with nearest-neighbour attraction and branching energies. We find a collapse transition at a tricritical theta point, which separates an expanded phase from a compact phase. We compare our results for the theta transition in two and three dimensions with available numerical estimates.Comment: 10 pages, 3 figures, to be published in Europhysics Letter

Adsorption-like Collapse of Diblock Copolymers

A linear copolymer made of two reciprocally attracting N-monomer blocks collapses to a compact phase through a novel transition, whose exponents are determined with extensive MC simulations in two and three dimensions. In the former case, an identification with the statistical geometry of suitable percolation paths allows to predict that the number of contacts between the blocks grows like $N^{9/16}$. In the compact phase the blocks are mixed and, in two dimensions, also zipped, in such a way to form a spiral, double chain structure.Comment: 4 pages, 5 Postscript figure